SDS - BASF Versys Insecticide - 240808

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Safety Data Sheet

Page: 1/13 BASF Safety data sheet Date / Revised: 08.08.2024 Product: Versys® Insecticide Version: 3.0 (30694767/SDS_CPA_AU/EN) Date of print: 09.08.2024

1. Substance/preparation and Manufacturer/supplier Identification

Product name: Versys® Insecticide

Use: crop protection product, insecticide

Manufacturer/supplier: BASF Australia Limited () Level 12, 28 Freshwater Place Southbank Victoria 3006, AUSTRALIA Telefax number:

Emergency information: BASF Emergency Advice Number: (24h) [within Australia] BASF Emergency Advice Number: + 61 3 8855 6666 [outside Australia]

2. Hazard Identification

Classification of the substance and mixture: Acute toxicity: Cat.3 (Inhalation - mist) Skin corrosion/irritation: Cat.2 Hazardous to the aquatic environment - acute: Cat.2 Hazardous to the aquatic environment - chronic: Cat.1

Label elements and precautionary statement: Pictogram: [Pictogram: Skull and crossbones, Environment]

Signal Word: Danger

Hazard Statement: H315 Causes skin irritation. H331 Toxic if inhaled. H401 Toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statement: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read carefully and follow all instructions.

Precautionary Statements (Prevention): P261 Avoid breathing mist. P264 Wash contaminated body parts thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves.

Precautionary Statements (Response): P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P311 Call a POISON CENTER or physician. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Precautionary Statements (Storage): P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary Statements (Disposal): P501 Dispose of contents and container to hazardous or special waste collection point.

Other hazards which do not result in classification: See section 12 - Results of PBT and vPvB assessment. If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/information on Ingredients

Chemical nature Substance nature: mixture Dispersible Concentration (DC), insecticide

Hazardous ingredients

Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Content (W/W): 9.8 % CAS Number: 915972-17-7 Aquatic Acute: Cat. 2 Aquatic Chronic: Cat. 1 M-factor chronic: 10000

Alcohols, C12-18, ethoxylated propoxylated Content (W/W): < 70 % CAS Number: 69227-21-0 Aquatic Acute: Cat. 2

Poly(oxy-1,2-ethanediyl), .alpha.-[tris(1-phenylethyl)phenyl]-.omega.-hydroxy Content (W/W): < 10 % CAS Number: 99734-09-5 Acute Tox.: Cat. 5 (oral) Aquatic Acute: Cat. 3 Aquatic Chronic: Cat. 3

4. First-aid Measures

General advice: First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.

If inhaled: Keep patient calm, remove to fresh air, seek medical attention.

On skin contact: Immediately wash thoroughly with soap and water, seek medical attention.

On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion: Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Note to physician: Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11., (Further) symptoms and / or effects are not known so far Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

5. Fire-fighting Measures

Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide

Unsuitable extinguishing media for safety reasons: water jet

Specific hazards: carbon monoxide, carbon dioxide, nitrogen oxides The substances/groups of substances mentioned can be released in case of fire.

Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing.

Further information: Keep containers cool by spraying with water if exposed to fire. In case of fire and/or explosion do not breathe fumes. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release Measures

Personal precautions: Do not breathe vapour/spray.Use personal protective clothing.Avoid contact with the skin, eyes and clothing.

Environmental precautions: Do not discharge into the subsoil/soil.Do not discharge into drains/surface waters/groundwater.

Methods for cleaning up or taking up: For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). For large amounts: Dike spillage. Pump off product. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Wear suitable protective equipment.

7. Handling and Storage

Handling No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Remove contaminated clothing and protective equipment before entering eating areas.

Protection against fire and explosion: Vapours may form ignitable mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Storage Segregate from foods and animal feeds. Further information on storage conditions: Keep away from heat. Protect from direct sunlight.

8. Exposure Controls and Personal Protection

Components with occupational exposure limits propane-1,2-diol, 57-55-6; TWA value 474 mg/m3 ; 150 ppm (AU NOEL), Total vapour and particulates TWA value 10 mg/m3 (AU NOEL), Particulate TWA value 474 mg/m3 ; 150 ppm (OEL (AU)), Total vapour and particulates TWA value 10 mg/m3 (OEL (AU)), Particulate

Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester, 915972-17-7; TWA value 0.2 mg/m3 (BASF recomm. occupational exposure limit)

Personal protective equipment Respiratory protection: Respiratory protection not required.

Hand protection: Chemical resistant protective gloves

Eye protection: Safety glasses with side-shields.

Body protection: Standard work clothes and shoes.

General safety and hygiene measures: Avoid contact with the skin, eyes and clothing. In order to prevent contamination while handling, closed working clothes and working gloves should be used. Wash contaminated clothing before reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Before eating, drinking, or smoking, wash face and hands with soap and water.

9. Physical and Chemical Properties

Form: liquid Colour: golden yellow Odour: odourless Odour threshold: Not determined since toxic by inhalation. pH value: approx. 5 - 7 (CIPAC standard water D, 1 %(m), 20 °C) (pH Meter) Melting temperature: The product has not been tested. boiling temperature: > 189 °C Flash point: 96 °C (Regulation 440/2008/EC, A.9) Evaporation rate: not applicable Flammability (solid/gas): not applicable Lower explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Upper explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Ignition temperature: 385 °C (Regulation 440/2008/EC, A.15) Thermal decomposition: 350 °C , 270 kJ/kg (onset temperature) (DSC (OECD 113)) Not a substance liable to self-decomposition according to UN transport regulations, class 4.1. Explosion hazard: not explosive (Regulation 440/2008/EC, A.14) Fire promoting properties: not fire-propagating (Regulation 440/2008/EC, A.21) Vapour pressure: approx. < 0.000009 Pa (25 °C) The data given are those of the active ingredient. Density: approx. 1.02 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not applicable Solubility in water: dispersible Partitioning coefficient n-octanol/water (log Pow): not applicable Viscosity, dynamic: approx. 334 mPa.s (20 °C) (OECD Guideline 114)

Other Information: If necessary, information on other physical and chemical parameters is indicated in this section.

10. Stability and Reactivity

Conditions to avoid: See SDS section 7 - Handling and storage.

Thermal decomposition: 350 °C, 270 kJ/kg (DSC (OECD 113)) (onset temperature) Thermal decomposition: Not a substance liable to self-decomposition according to UN transport regulations, class 4.1.

Substances to avoid: strong acids, strong bases, strong oxidizing agents

Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated.

Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated.

Chemical stability: The product is stable if stored and handled as prescribed/indicated.

Reactivity: No hazardous reactions if stored and handled as prescribed/indicated.

11. Toxicological Information

Routes of exposure Acute oral toxicity Experimental/calculated data: LD50rat (oral): > 2,000 mg/kg (OECD Guideline 423) No mortality was observed.

Acute inhalation toxicity LC50 rat (by inhalation): > 0.55 - < 1.22 mg/l 4 h (OECD Guideline 403) An aerosol with respirable particles was tested.

Acute dermal toxicity LD50 rat (dermal): > 5,000 mg/kg (OECD Guideline 402) No mortality was observed.

Assessment of acute toxicity Of pronounced toxicity after short-term inhalation. Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact.

Symptoms Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11. (Further) symptoms and / or effects are not known so far

Irritation Assessment of irritating effects: Skin contact causes slight irritation. Not irritating to the eyes.

Experimental/calculated data: Skin corrosion/irritation rabbit: Slightly irritating. (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)

Respiratory/Skin sensitization Assessment of sensitization: No sensitizing effect.

Experimental/calculated data: Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)

Germ cell mutagenicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Assessment of carcinogenicity: In long-term animal studies in which the substance was given in high doses by feed, a carcinogenic effect was observed. The effect is caused by an animal specific mechanism that has no human counter part.

Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.

Specific target organ toxicity (single exposure) Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Remarks: The product has not been tested. The statement has been derived from the properties of the individual components.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Assessment of repeated dose toxicity: Repeated exposure to large quantities may affect certain organs. Based on available data, the classification criteria are not met.

Aspiration hazard not applicable

Other relevant toxicity information Misuse can be harmful to health.

12. Ecological Information

Ecotoxicity Assessment of aquatic toxicity: Toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Toxicity to fish: LC50 (96 h) 1.08 mg/l, Oncorhynchus mykiss (OECD 203; ISO 7346; 84/449/EWG, C.1)

Aquatic invertebrates: EC50 (48 h) 1.17 mg/l, Daphnia magna (OECD Guideline 202, part 1)

Aquatic plants: EC50 (72 h) > 100 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201) No observed effect concentration (72 h) 0.31 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201) EC10 (72 h) 0.65 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201)

Chronic toxicity to fish: No observed effect concentration (96 h) 0.33 mg/l, Oncorhynchus mykiss

Chronic toxicity to aquatic invertebrates: No observed effect concentration (48 h), 0.16 mg/l, Daphnia magna

Information on: Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Toxicity to fish: LC50 (96 h) 18 mg/l, Cyprinus carpio No observed effect concentration (34 d) 0.082 mg/l, Cyprinodon variegatus

Information on: Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Chronic toxicity to aquatic invertebrates: No observed effect concentration (28 d), 0.000004 mg/l, Mysidopsis bahia

Mobility Assessment transport between environmental compartments: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Assessment transport between environmental compartments: Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.

Persistence and degradability Assessment biodegradation and elimination (H2O): The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).

Bioaccumulation potential Assessment bioaccumulation potential: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: Cyclopropanecarboxylic acid, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11H-naphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl ester Bioaccumulation potential: Bioconcentration factor: 0.06 Does not accumulate in organisms.

Additional information Other ecotoxicological advice: Do not discharge product into the environment without control.

13. Disposal Considerations

Must be sent to a suitable incineration plant, observing local regulations.

Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

14. Transport Information

Domestic transport: UN number or ID number: UN 3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (AFIDOPYROPEN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known

Further information Hazchem Code:3Z IERG Number:47

Sea transport IMDG UN number or ID number: UN 3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (AFIDOPYROPEN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Marine pollutant: YES Special precautions for user: EmS: F-A; S-F

Air transport IATA/ICAO UN number or ID number: UN 3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (AFIDOPYROPEN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known

Further information Environmentally Hazardous Substances meeting the description of UN 3077 or UN 3082 are not subjected to the Australian Dangerous Goods Code when transported by road or rail in packagings not exceeding 500 kg(L) or IBCs.

Further information Product may be shipped as non-hazardous in suitable packages containing a net quantity of 5 L or less under the provisions of various regulatory agencies: ADR, RID, ADN: Special Provision 375; IMDG: 2.10.2.7; IATA: A197; TDG: Special Provision 99(2); 49CFR: §171.4 (c) (2) and also the Special Provision 375 in Appendix B which is regulated in China "Regulations Concerning Road Transportation of Dangerous Goods Part 3: Index of dangerous goods name and transportation requirements" (JT/T 617.3)

15. Regulatory Information

Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection.

Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP): Not Scheduled

APVMA Approval No: 82738

Registration status: AICIS, AU Contains non-registered, non-listed substance., Individual registration may be required., Please contact your BASF representative.

16. Other Information

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.