SDS - ICL Banrot 400WP Fungicide - 241001

Safety Data Sheet Revision date: October 2024

1. PRODUCT AND COMPANY IDENTIFICATION Product Name: BANROT 400WP Recommended Use: Soil Fungicide Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. - (CONTAINS ETRIDIAZOLE) Supplier: Everris Australia Pty Ltd, 211/33 Lexington Drive, Bella Vista, NSW 2153, Australia. Telephone: Australian Business Number: 31 003 123 162 Emergency Telephone: Australia: New Zealand: 0800 446 881 (toll-free, New Zealand only) HSNO Approval number (NZ): HSR007632

2. HAZARDS IDENTIFICATION Australia Classified as Hazardous according to criteria of National Occupational Health & Safety Commission (NOHSC), Australia. Classified as not Dangerous goods for transport by road or rail (ADG Code 7). Exempt from classification as a Dangerous Good as per ADG7, SP no. AU01. For bulk shipments as Class 9, use UN 3077, Hazchem code 2Z.

New Zealand Classified as Hazardous according to the New Zealand Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001. Classified as Dangerous Goods for transport, according to the New Zealand Standard NZS 5433:1999 Transport of Dangerous Goods on Land.

GHS Classification:

[Diagram: Three hazard pictograms: Exclamation mark, Health hazard, Environment]

Signal Word: Warning/ Caution

Hazard Statements: H317 May cause an allergic skin reaction H319 Causes serious eye irritation H341 Suspected of causing genetic defects H351 Suspected of causing cancer H361 Suspected of damaging fertility or the unborn child H373 May cause damage to organs (lungs) through prolonged or repeated exposure H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long-lasting effects

Prevention: P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P260 Do not breath dust/mist/spray P261 Avoid breathing dust P264 Wash hands and face thoroughly after handling P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves, protective clothing, eye protection

Response: P302+P352 IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice. P314 Get medical advice if you feel unwell. P321 Specific treatment (see First Aid measures on label). P333+P313 If skin irritation or rash occurs: Get medical advice. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage

Storage: P405 Store locked up

Disposal: P501 Dispose of according to instructions on the product label.

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3. COMPOSITION/INFORMATION ON INGREDIENTS

   Ingredients Name	CAS	Proportion Ingredients
   Thiophanate-methyl	23564-05-8	25 %
   Etridiazole	2593-15-9	15 %
   Silicon dioxide	7631-86-9	7.5%
   Sodium dodecyl sulphate	151-21-3	2.5%
   Ingredients determined not to be hazardous:		50 %

4. FIRST AID MEASURES Inhalation: May be harmful if inhaled. Do not breath dust/mist/vapour/spray. IF INHALED: Call a POISON CENTRE or doctor if you feel unwell. Ingestion: May be harmful is swallowed. IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell. Rinse mouth Skin: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice. Remove contaminated clothing and wash before reuse. Contaminated work clothing should not be allowed out of the workplace. Eye: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation develops or persists: get medical advice/ attention. First Aid Facilities: Normal wash-room facilities. Advice to Doctor: Treat symptomatically. Other information: For advice, contact a Poisons Information Centre (Phone Australia 13 11 26; New Zealand 0800 764 766) or a doctor (at once).

5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use carbon dioxide, dry chemical, and foam or water mist. Hazards from Combustion Products: Under fire conditions this product may emit toxic and/or irritating fumes. Special Protective Equipment for fire Fighters: Fire-fighters should wear full protective clothing and self contained breathing apparatus (SCBA). Hazchem Code: 2Z

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6. ACCIDENTAL RELEASE MEASURES Emergency Procedures Sweep up material avoiding dust generation or dampen spilled material with water to avoid airborne dust, and then transfer material to a suitable container. Use absorbent paper dampened with water to pick up remaining material. Wash surfaces well, with soap and water. Seal all wastes in vapour tight labelled plastic containers for eventual disposal. Dispose of waste according to federal, Environmental Protection Authority and state regulations. Avoid release to the environment. If the spillage enters waterways contact the Environmental Protection Authority, or your local Waste Management Authority.

7. HANDLING AND STORAGE Precautions for Safe Handling: Read label before use. Do not handle until all safety precautions have been read and understood. Avoid generating and breathing dust. Wash hands thoroughly after handling. Wear protective gloves and clothing. Contaminated work clothing should not be allowed out of the workplace. Use personal protective equipment as specified on the label and in section 8 of this Safety Data Sheet. Conditions for Safe Storage: Store locked up. Keep out of reach of children. Store in a cool, dry place. Keep container tightly closed when not in use.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION National Exposure Standards: The exposure standard for dust not otherwise specified is 10 mg/m³ (for inspirable dust) and 3 mg/m³ (for respirable dust). The limit applies to both Australia and New Zealand. Biological Limit Values: No biological limit allocated. Engineering Controls: Avoid breathing dusts. If dusts are produced local exhaust ventilation should be used. Respiratory Protection: If engineering controls are not effective in controlling airborne exposure then respiratory protective equipment should be used suitable for protecting against airborne contaminants. Final choice of appropriate breathing protection is dependent upon actual airborne concentrations and the type of breathing protection required and will vary according to individual circumstances. Expert advice may be required to make this decision. Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices.

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Hand Protection: Wear gloves of impervious material. Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance. Eye Protection: Safety glasses with side shields, goggles or full-face shield as appropriate recommended. Final choice of appropriate eye/face protection will vary according to individual circumstances i.e. methods of handling or engineering controls and according to risk assessments undertaken. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications. Body Protection: Suitable work wear should be worn to protect personal clothing, e.g. cotton overalls buttoned at neck and wrist. When large quantities are handled the use of plastic aprons and rubber boots is recommended. Industrial clothing should conform to the specifications detailed in AS/NZS 2919: Industrial clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Tan powder Odour: Not available Melting Point: Not available Boiling Point: Not applicable Solubility in Water: Not available pH Value: Not available Vapour Pressure: Not applicable Vapour Density: Not applicable Bulk density: 640.74kg/m 3 Flashpoint: Not applicable Auto-Ignition Temperature: Not available Flammable Limits-Lower: Not applicable Flammable Limits-Upper: Not applicable

10. STABILITY AND REACTIVITY Chemical Stability: Stable under normal conditions of use. Conditions to Avoid: Heat, direct sunlight, open flames or other sources of ignition.

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Incompatible Materials: Strong oxidising agents, alkalis and reducing agents. Hazardous Decomposition Products: Thermal decomposition and combustion produce noxious fumes containing oxides of carbon. Hazardous polymerization: Will not occur.

11. TOXICOLOGICAL INFORMATION Inhalation: May be harmful if inhaled. Inhalation of product dusts will cause irritation of the nose, throat and respiratory system. May cause damage to lungs through prolonged or repeated exposure. Ingestion: May be harmful if swallowed. Ingestion of this product may irritate the gastric tract causing nausea and vomiting. Ingestion of large quantities may depress the central nervous system. Skin: May be harmful in contact with skin. May cause an allergic skin reaction. May cause mild skin irritation. This product may cause sensitisation in some individuals. Eye: Causes serious eye irritation. Mutagenicity: It is important to recognise that this material is classified as H341 Suspected of causing genetic defects. There is evidence from appropriate mutagenicity studies, of concern that human exposure may result in the development of heritable genetic damage, but this evidence is insufficient to classify the substance as 6.6A. Carcinogenicity: It is important to recognise that this product is classified as H351 Suspected of causing cancer. That is, there is some evidence from appropriate animal studies that human exposure may result in the development of cancer, but this evidence is insufficient to classify the substance as 6.7A.

12. ECOLOGICAL INFORMATION Ecotoxicity: Very toxic to the aquatic environment with long lasting effects. Hazardous to soil organisms. Persistence/ Degradability: Inherently biodegradable. Non-persistent. Mobility: Water contaminating Bioaccumulative: Does not bioaccumulate Environmental Protection: Avoid contaminating waterways with product or empty container.

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13. Disposal Considerations Disposal Considerations: Do not allow into drains or watercourses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with all federal, E.P.A., state and local regulations. Assure conformity with all applicable regulations.

14. TRANSPORT INFORMATION UN Number: 3077 [Diagram: Class 9 placard, Environmentally hazardous substance mark]

ADR/RID: Australia: Classified as not Dangerous Goods for transport by road or rail. Exempt from classification as a Dangerous Good as per ADG7, SP no. AU01. For bulk shipments classified as Class 9, UN 3077, Hazchem code 2Z. New Zealand: Classified as Dangerous Goods for the purpose of transport by road and rail. Refer to relevant regulations for storage and transport requirements. Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS ETRIDIAZOLE). Class: 9 Packing group: III

IMDG/IMO: Classified as Dangerous Goods for the purpose of transport by sea. Refer to relevant regulations for storage and transport requirements. Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS ETRIDIAZOLE). Class: 9 Packing group: III

ICAO: Classified as Dangerous Goods for the purpose of transport by sea. Refer to relevant regulations for storage and transport requirements. Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS ETRIDIAZOLE). Class: 9 Packing group: III

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General Information: Hazchem code: 2Z

15. REGULATORY INFORMATION Australia: Classified as hazardous according to criteria of Safe Work Australia. APVMA Approval Number: 52741 New Zealand: Classified as Hazardous according to the New Zealand Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001. Group Standard: HSNO Approval Number: HSR007632 Poisons Schedule: S5

16. OTHER INFORMATION Date of preparation: Safety Data Sheet Created: September 2019. MSDS Contact Person/Point: Everris Australia Pty Ltd. Suite 211, 33 Lexington Drive, Bella Vista Australia, Phone . Emergency Telephone: Australia: End of Safety Data Sheet

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