SDS - Adama Magellan 800WG Fungicide - 2203

Product Name: Magellan 800 WG Systemic Fungicide Page: 1 of 5 This version issued: March, 2022

SAFETY DATA SHEET Issued by: Adama Australia Pty Ltd Phone: (office hours) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Section 1 - Identification of the Material and Supplier Adama Australia Pty Ltd, Level 1, Building B 207 Pacific Highway St Leonards, NSW 2065

Telephone (office hours) Emergency (24 hours)

Chemical nature: Water dispersible granules containing fosetyl-aluminium Trade Name: Magellan 800 WG Systemic Fungicide Product Use: Agricultural fungicide for use as described on the product label. Creation Date: March, 2017 This version issued: March, 2022 and is valid for 5 years from this date. Poisons Information Centre: Phone 13 1126 from anywhere in Australia

Section 2 - Hazards Identification Statement of Hazardous Nature This product is classified as: Hazardous according to the criteria of SWA. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria. SUSMP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria. UN Number: None allocated

GHS Signal word: WARNING Serious eye damage/eye irritation Category 2/2A Hazardous to aquatic environment Short term/Acute Category 2

HAZARD STATEMENT: H319: Causes serious eye irritation. H401: Toxic to aquatic life.

PREVENTION P261: Avoid breathing dusts. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

RESPONSE P335: Brush off loose particles from skin. P362: Take off contaminated clothing and wash before reuse. P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam.

STORAGE P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

DISPOSAL P501: Dispose of contents and containers as specified on the registered label.

Emergency Overview Physical Description & Colour: White to off-white extruded granule [Diagram: GHS Exclamation Mark pictogram]

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Product Name: Magellan 800 WG Systemic Fungicide Page: 2 of 5 This version issued: March, 2022

Odour: No data. Major Health Hazards: may cause serious irritation to eyes.

Section 3 - Composition/Information on Ingredients

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible. The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak" is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Section 4 - First Aid Measures General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.

Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about 30 minutes, seek medical advice. Skin Contact: Gently brush away excess particles. Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until chemical is removed. Eye Contact: Quickly and gently brush particles from eyes. Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 15 minutes or until the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.

Section 5 - Fire Fighting Measures Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen deficient (or both), fire gases. There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures. Extinguishing Media: In case of fire, use carbon dioxide, dry chemical or foam. Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. Flammability Class: No data.

Section 6 - Accidental Release Measures Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full protective chemically resistant clothing including eye/face protection, gauntlets and self contained breathing apparatus. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include no specific manufacturer recommendations. Use impermeable gloves with care. Eye/face protective equipment should comprise, as a minimum, protective glasses and, preferably, goggles. If there is a significant chance that dusts are likely to build up in cleanup area, we recommend that you use a suitable dust mask. Otherwise, not normally necessary. Stop leak if safe to do so, and contain spill. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Consider vacuuming if appropriate. Recycle containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

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Product Name: Magellan 800 WG Systemic Fungicide Page: 3 of 5 This version issued: March, 2022

Section 7 - Handling and Storage Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Storage: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Check packaging - there may be further storage instructions on the label.

Section 8 - Exposure Controls and Personal Protection The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

The ADI for Fosetyl aluminium is set at 1mg/kg/day. The corresponding NOEL is set at 103mg/kg/day. ADI means Acceptable Daily Intake; NOEL means No-observable-effect-level. Data from Australian ADI List, June 2014. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. If necessary, use a fan. Eye Protection: Protective glasses or goggles must be worn when this product is being used. Failure to protect your eyes may lead to severe harm to them or to general health. Emergency eye wash facilities must also be available in an area close to where this product is being used. Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable impervious elbow-length gloves and facial protection when handling this product. See below for suitable material types. Protective Material Types: There is no data that enables us to recommend any type except that it should be impermeable. Respirator: If there is a significant chance that dusts are likely to build up in the area where this product is being used, we recommend that you use a suitable dust mask. Otherwise, not normally necessary. Eyebaths or eyewash stations and safety deluge showers should, if practical, be provided near to where this product is being handled commercially.

Section 9 - Physical and Chemical Properties: Physical Description & colour: White to off-white extruded granule Odour: No data. Boiling Point: Not available. Flash point: Not flammable. Upper Flammability Limit: No data. Lower Flammability Limit: No data. Freezing/Melting Point: No specific data. Solid at normal temperatures. Volatiles: No data. Vapour Pressure: No data. Vapour Density: Not applicable. Specific Gravity: No data. Water Solubility: No data. pH: 3.0-5.0 (1% aqueous suspension) Volatility: No data. Odour Threshold: No data. Evaporation Rate: Not applicable. Coeff Oil/water Distribution: No data Particle Characteristics: Granules Autoignition temp: No data.

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Product Name: Magellan 800 WG Systemic Fungicide Page: 4 of 5 This version issued: March, 2022

Section 10 - Stability and Reactivity Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also formed. Aluminium compounds. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: Polymerisation reactions are unlikely; they are not expected to occur.

Section 11 - Toxicological Information Local Effects: Target Organs: There is no data to hand indicating any particular target organs.

Classification of Hazardous Ingredients

Potential Health Effects Inhalation: Short Term Exposure: Available data indicates that this product is not harmful. However product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term inhalation. Skin Contact: Short Term Exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short Term Exposure: This product is a severe eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms such as swelling of eyelids and blurred vision may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment is likely to cause permanent damage. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.

Section 12 - Ecological Information This product is toxic to aquatic organisms. Insufficient data to be sure of status.

Section 13 - Disposal Considerations Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear and for help with the disposal of empty drums, contact DrumMuster where you will find contact details for your area.

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Product Name: Magellan 800 WG Systemic Fungicide Page: 5 of 5 This version issued: March, 2022

Section 14 - Transport Information UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special transport conditions are necessary unless required by other regulations.

Section 15 - Regulatory Information AIIC: All of the significant ingredients in this formulation are compliant with AICIS regulations.

Section 16 - Other Information This SDS contains only safety-related information. For other data see product literature.

Acronyms: ADG Code: Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition AIIC: Australian Inventory of Industrial Chemicals CAS number: Chemical Abstracts Service Registry Number Hazchem Code: Emergency action code of numbers and letters that provide information to emergency services especially firefighters IARC: International Agency for Research on Cancer SWA: Safe Work Australia, formerly ASCC and NOHSC NOS: Not otherwise specified NTP: National Toxicology Program (USA) SUSMP: Standard for the Uniform Scheduling of Medicines & Poisons UN Number: United Nations Number

Contact Points: Call Adama on and ask for the technical manager. Fax: Police and Fire Brigade: Dial 000 Emergency contact: (24 hours) If ineffective: Dial Poisons Information Centre (13 1126 from anywhere in Australia)

THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST. Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous Chemicals - Code of Practice” (July 2020) and GHS Revision 7 Copyright © Kilford & Kilford Pty Ltd, March, 2022.