SDS - Envu Reserve Stressgard Turf Fungicide - 230410

SAFETY DATA SHEET

Reserve Stressgard® Turf Fungicide

Version 1.0 Revision Date: 10.04.2023 SDS Number: 11192642-00001 Date of last issue: - Date of first issue: 10.04.2023 1 / 16

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Reserve Stressgard® Turf Fungicide Product code : Article/SKU: 84984671 UVP: 84999792 Specification: 102000031645

Manufacturer or supplier's details

Company : 2022 Environmental Science AU Pty Ltd

Address : Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123 Emergency telephone number :

Recommended use of the chemical and restrictions on use

Recommended use : Fungicide Restrictions on use : Not applicable

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Acute toxicity (Inhalation) : Category 2 Serious eye damage/eye irritation : Category 1 Skin sensitisation : Category 1 Carcinogenicity : Category 2 Specific target organ toxicity - single exposure : Category 3

GHS label elements

Hazard pictograms : [Skull and crossbones, Corrosion, Exclamation mark] Signal word : Danger

Hazard statements : H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer.

Precautionary statements :

Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe mist or vapours. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection.

Response: P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P320 Specific treatment is urgent (see supplemental first aid instructions on this label). P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.

Storage: P405 Store locked up.

Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Components

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.

If inhaled : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

In case of skin contact : In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention immediately.

If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention. Rinse mouth thoroughly with water.

Most important symptoms and effects, both acute and delayed : Allergic reactions Prolonged and repeated contact with skin, eyes or mucous membranes may cause irritation. May cause an allergic skin reaction. Causes serious eye damage. Fatal if inhaled. May cause respiratory irritation. Suspected of causing cancer.

Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8).

Notes to physician : Treat symptomatically and supportively.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing media : None known.

Specific hazards during firefighting : Exposure to combustion products may be a hazard to health.

Hazardous combustion products : Nitrogen oxides (NOx) Chlorine compounds Carbon oxides

Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.

Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Hazchem Code : 2X

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures : Evacuate personnel to safe areas. Only trained personnel should re-enter the area. Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8).

Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up : Soak up with inert absorbent material. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation : If sufficient ventilation is unavailable, use with local exhaust ventilation.

Advice on safe handling : Do not get on skin or clothing. Do not breathe mist or vapours. Do not swallow. Do not get in eyes. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment Keep container tightly closed. Already sensitised individuals, and those susceptible to asthma, allergies, chronic or recurrent respiratory disease, should consult their physician regarding working with respiratory irritants or sensitisers. Take care to prevent spills, waste and minimize release to the environment.

Hygiene measures : If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before re-use.

Conditions for safe storage : Keep in properly labelled containers. Store locked up. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations.

Materials to avoid : Do not store with the following product types: Explosives

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Engineering measures : Minimize workplace exposure concentrations. If sufficient ventilation is unavailable, use with local exhaust ventilation.

Personal protective equipment

Respiratory protection : If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection.

Filter type : Combined particulates and organic vapour type

Hand protection Material : Chemical-resistant gloves

Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.

Eye protection : Wear the following personal protective equipment: Chemical resistant goggles must be worn. If splashes are likely to occur, wear: Face-shield

Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : suspension Colour : green Odour : No data available Odour Threshold : No data available pH : 6 - 8 Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : No data available Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available Upper explosion limit / Upper flammability limit : No data available Lower explosion limit / Lower flammability limit : No data available Vapour pressure : No data available Relative vapour density : No data available Relative density : No data available Solubility(ies) Water solubility : No data available Partition coefficient: n-octanol/water : Not applicable Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : 700 - 1,000 mPa.s Method: Brookfield Viscosity, kinematic : No data available Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. Particle size : Not applicable

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Can react with strong oxidizing agents. Conditions to avoid : None known. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Exposure routes : Inhalation Skin contact Ingestion Eye contact

Acute toxicity Fatal if inhaled.

Product: Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate: 0.1861 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Components:

Chlorothalonil: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC50 (Rat): 0.1 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 402

Ethylene glycol: Acute oral toxicity : Acute toxicity estimate: 500 mg/kg Method: Expert judgement Acute inhalation toxicity : LC50 (Rat): > 2.5 mg/l Exposure time: 6 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Mouse): > 3,500 mg/kg

Skin corrosion/irritation Not classified based on available information.

Components: Chlorothalonil: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation

Ethylene glycol: Species : Rabbit Result : No skin irritation

Serious eye damage/eye irritation Causes serious eye damage.

Components: Chlorothalonil: Species : Rabbit Result : Irreversible effects on the eye

Ethylene glycol: Species : Rabbit Result : No eye irritation

Respiratory or skin sensitisation Skin sensitisation May cause an allergic skin reaction.

Respiratory sensitisation Not classified based on available information.

Components: Chlorothalonil: Test Type : Maximisation Test Exposure routes : Skin contact Species : Guinea pig Result : positive Assessment : Probability or evidence of skin sensitisation in humans

Ethylene glycol: Test Type : Maximisation Test Exposure routes : Skin contact Species : Guinea pig Result : negative

Chronic toxicity Germ cell mutagenicity Not classified based on available information.

Components: Chlorothalonil: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Result: negative Test Type: Chromosome aberration test in vitro Result: positive Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Rat Application Route: Ingestion Result: negative

Ethylene glycol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative

Carcinogenicity Suspected of causing cancer.

Components: Chlorothalonil: Species : Rat Application Route : Ingestion Exposure time : 2 Years Result : positive Carcinogenicity - Assessment : Limited evidence of carcinogenicity in animal studies

Ethylene glycol: Species : Mouse Application Route : Ingestion Exposure time : 2 Years Result : negative

Reproductive toxicity Not classified based on available information.

Components: Chlorothalonil: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Effects on foetal development : Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative

STOT - single exposure May cause respiratory irritation.

Components: Chlorothalonil: Assessment : May cause respiratory irritation.

STOT - repeated exposure Not classified based on available information.

Components: Chlorothalonil: Assessment : No significant health effects observed in animals at concentrations of 100 mg/kg bw or less.

Ethylene glycol: Exposure routes : Ingestion Target Organs : Kidney Assessment : Shown to produce significant health effects in animals at concentrations of >10 to 100 mg/kg bw.

Repeated dose toxicity

Components: Chlorothalonil: Species : Rat NOAEL : 10 mg/kg Application Route : Ingestion

Ethylene glycol: Species : Rat NOAEL : 150 mg/kg Application Route : Ingestion Exposure time : 2 yr Species : Dog NOAEL : 2,200 - 4,400 mg/kg Application Route : Skin contact Exposure time : 4 Weeks Method : OECD Test Guideline 410

Aspiration toxicity Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components: Chlorothalonil: Toxicity to fish : LC50 (Cyprinodon variegatus (sheepshead minnow)): 28 µg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Crassostrea virginica (eastern oyster)): 7.5 µg/l Exposure time: 96 h Toxicity to algae/aquatic plants : ErC50 (Navicula pelliculosa (Freshwater diatom)): 13 µg/l Exposure time: 72 h Method: OECD Test Guideline 201 NOEC (Navicula pelliculosa (Freshwater diatom)): 3.5 µg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) : NOEC (Pimephales promelas (fathead minnow)): 1.4 µg/l Exposure time: 297 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Mysidopsis bahia (opossum shrimp)): 0.4 µg/l Exposure time: 28 d Method: OPPTS 850.1350 Toxicity to microorganisms : NOEC (activated sludge): 10 mg/l Exposure time: 3 h Test substance: Neutralised product Method: OECD Test Guideline 209

Ethylene glycol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 72,860 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : EC50 (Pseudokirchneriella subcapitata (green algae)): 6,500 - 13,000 mg/l Exposure time: 96 h Toxicity to fish (Chronic toxicity) : NOEC (Pimephales promelas (fathead minnow)): 15,380 mg/l Exposure time: 7 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Ceriodaphnia dubia (water flea)): 8,590 mg/l Exposure time: 7 d

Persistence and degradability

Components: Ethylene glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: 90 - 100 % Exposure time: 10 d Method: OECD Test Guideline 301A

Bioaccumulative potential

Components: Chlorothalonil: Bioaccumulation : Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): 264 Partition coefficient: n-octanol/water : log Pow: 2.94

Ethylene glycol: Bioaccumulation : Species: Leuciscus idus (Golden orfe) Bioconcentration factor (BCF): 10 Partition coefficient: n-octanol/water : log Pow: -1.93

Mobility in soil No data available

Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues : It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer.

Contaminated packaging : Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG UN number : UN 2810 Proper shipping name : TOXIC LIQUID, ORGANIC, N.O.S. (Chlorothalonil) Class : 6.1 Packing group : II Labels : 6.1

IATA-DGR UN/ID No. : UN 2810 Proper shipping name : Toxic liquid, organic, n.o.s. (Chlorothalonil) Class : 6.1 Packing group : II Labels : Toxic Packing instruction (cargo aircraft) : 662 Packing instruction (passenger aircraft) : 654

IMDG-Code UN number : UN 2810 Proper shipping name : TOXIC LIQUID, ORGANIC, N.O.S. (Chlorothalonil) Class : 6.1 Packing group : II Labels : 6.1 EmS Code : F-A, S-A Marine pollutant : yes

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations

ADG UN number : UN 2810 Proper shipping name : TOXIC LIQUID, ORGANIC, N.O.S. (Chlorothalonil) Class : 6.1 Packing group : II Labels : 6.1 Hazchem Code : 2X

Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

Standard for the Uniform Scheduling of Medicines and Poisons : Schedule 6

Prohibition/Licensing Requirements : There is no applicable prohibition, authorisation and restricted use requirements, including for carcinogens referred to in Schedule 10 of the model WHS Act and Regulations.

Regulation (EU) No 528/2012 of the European Parliament and of the Council of 22 May 2012 concerning the making available on the market and use of biocidal products Authorisation number : 81269 Active substance : 720 g/l Chlorothalonil

SECTION 16. OTHER INFORMATION

Further information Revision Date : 10.04.2023 Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency, Date format : dd.mm.yyyy

Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) AU OEL : Australia. Workplace Exposure Standards for Airborne Contaminants. ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit AU OEL / TWA : Exposure standard - time weighted average AU OEL / STEL : Exposure standard - short term exposure limit

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.

AU / EN