SDS - Nufarm Sempra Herbicide - 230127

SAFETY DATA SHEET NUFARM SEMPRA HERBICIDE Infosafe No.: 3NU0L ISSUED Date : 27/01/2023 ISSUED by: NUFARM AUSTRALIA LIMITED.

Section 1 - Identification

Product Identifier NUFARM SEMPRA HERBICIDE

Product Code 0727

Product Type Group 2 Herbicide

Company Name NUFARM AUSTRALIA LIMITED. ()

Address 103-105 Pipe Road Laverton North Victoria 3026 AUSTRALIA

Telephone/Fax Number

Emergency Phone Number (24hr Australia)

Emergency Contact Name

E-mail Address

Recommended use of the chemical and restrictions on use For selective post-emergence control of Nutgrass in Sugarcane, Corn/Maize and Sorghum; for the selective post-emergence control of Nutgrass and Mullumbimby couch in Turf; and for the selective post-emergence control of Navua sedge in Pasture. Also for the control of Nutgrass in Cotton using shielded sprayers as per the Directions for Use table on the Label. READ COMPLETE DIRECTIONS FOR USE BEFORE USING THIS PRODUCT.

Section 2 - Hazard(s) Identification

GHS classification of the substance/mixture Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia. Complies with the requirements of Special Provision AU01 and therefore exempted from being classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) Classified as Dangerous Goods according to International Maritime Dangerous Goods Code (IMDG) and International Air Transport Association (IATA). Reproductive toxicity: Category 1B Hazardous to the Aquatic Environment - Acute Hazard: Category 1 Hazardous to the Aquatic Environment - Long-Term Hazard: Category 1

Signal Word (s) DANGER

Hazard Statement (s) H360D May damage the unborn child. H410 Very toxic to aquatic life with long lasting effects.

Pictogram (s) [Image of Health hazard and Environment pictograms]

Precautionary Statement – Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary Statement – Response P308+P313 IF exposed or concerned: Get medical advice/attention. P391 Collect spillage.

Precautionary Statement – Storage P405 Store locked up.

Precautionary Statement – Disposal P501 Dispose of contents/container to an approved waste disposal plant.

Section 3 - Composition and Information on Ingredients

Ingredients

Section 4 - First Aid Measures

Inhalation If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seek medical attention.

Ingestion Do not induce vomiting. Wash out mouth thoroughly with water. Seek medical attention.

Skin Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention.

Eye If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing for several minutes until all contaminants are washed out completely. If symptoms develop and/or persist seek medical attention.

First Aid Facilities Eyewash and normal washroom facilities.

Advice to Doctor Treat symptomatically.

Other Information For advice in an emergency, contact a Poisons Information Centre (Phone Australia 131 126) or a doctor at once.

Section 5 - Firefighting Measures

Suitable Extinguishing Media Use appropriate fire extinguisher for surrounding environment.

Unsuitable Extinguishing Media Do not use water jet.

Hazards from Combustion Products Non combustible material. If involved in a major fire, could evolve oxides of nitrogen, sulphur or hydrogen chloride.

Specific hazards arising from the chemical This product is non combustible. However heating can cause expansion or decomposition leading to violent rupture of containers.

Special Protective Equipment and Precautions for Firefighters Fire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode. Fight fire from safe location.

Hazchem Code 2Z

Decomposition Temperature Not available

Section 6 - Accidental Release Measures

Emergency Procedures Increase ventilation. Evacuate all unprotected personnel. Wear sufficient respiratory protection and full protective clothing to prevent exposure. Sweep up material avoiding dust generation or dampen spilled material with water to avoid airborne dust, then transfer material to a suitable container. Wash surfaces well with soap and water. Seal all wastes in labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations.

Environmental Precautions This product is a herbicide and spills can damage crops, pastures and desirable vegetation.

Section 7 - Handling and Storage

Precautions for Safe Handling Always read the label and any attached leaflet before use. Avoid inhalation of dust, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up of dust in the work atmosphere. Maintain high standards of personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities. Avoid exposure. Do not handle until all safety precautions have been read and understood. It is recommended that pregnant or breastfeeding women should not handle this product unless adequate exposure protection can be assured at all times. Female personnel planning pregnancy should be made aware of the potential risks.

Conditions for safe storage, including any incompatibilities Store in a cool, dry, well-ventilated area, out of direct sunlight and moisture. Store in suitable, labelled containers. Keep containers tightly closed. Store away from incompatible materials. Ensure that storage conditions comply with applicable local and national regulations.

Section 8 - Exposure Controls and Personal Protection

Occupational exposure limit values No exposure standards have been established for the mixture. However, over-exposure to some chemicals may result in enhancement of pre-existing adverse medical conditions and/or allergic reactions and should be kept to the least possible levels.

Biological Monitoring No biological limits allocated.

Control Banding Not available

Engineering Controls This substance is hazardous and should be used with a local exhaust ventilation system, drawing solid/dust away from workers' breathing zone. If the engineering controls are not sufficient to maintain concentrations of particulates below the exposure standards, suitable respiratory protection must be worn.

Respiratory Protection If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable P1 dust/particulate filter should be used. Refer to relevant regulations for further information concerning respiratory protective requirements. Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances.

Eye and Face Protection Safety glasses with side shields, chemical goggles or full-face shield as appropriate should be used. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform to relevant regulations. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 (series) - Eye Protectors for Industrial Applications.

Hand Protection Wear gloves of impervious material such as PVC. Final choice of appropriate gloves will vary according to individual circumstances. i.e. methods of handling or according to risk assessments undertaken. Occupational protective gloves should conform to relevant regulations. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.

Thermal Hazards No further relevant information available.

Body Protection Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled.

Section 9 - Physical and Chemical Properties

Section 10 - Stability and Reactivity

Reactivity Reacts with incompatible materials.

Chemical Stability Stable under normal conditions of storage and handling.

Possibility of hazardous reactions Reacts with incompatible materials.

Conditions to Avoid Extremes of temperature and direct sunlight.

Incompatible Materials Not available.

Hazardous Decomposition Products Thermal decomposition may result in the release of toxic and/or irritating fumes such as oxides of nitrogen, sulphur or hydrogen chloride.

Hazardous Polymerization Will not occur.

Section 11 - Toxicological Information

Acute Toxicity Toxicity data for material given below.

Acute Toxicity - Oral LD50 (rat, M/F): 2825/1947 mg/kg

Acute Toxicity - Dermal LD50 (rabbit): >2000 mg/kg

Acute Toxicity - Inhalation LC50 (rat): >5.7 mg/l/4h

Ingestion Ingestion of this product may irritate the gastric tract causing nausea and vomiting.

Inhalation Inhalation of dusts may irritate the respiratory system.

Skin May be irritating to skin. The symptoms may include redness, itching and swelling.

Eye May be irritating to eyes. The symptoms may include redness, itching and tearing.

Respiratory Sensitisation Not expected to be a respiratory sensitiser.

Skin Sensitisation Not expected to be a skin sensitiser.

Germ Cell Mutagenicity Not considered to be a mutagenic hazard.

Carcinogenicity Not considered to be a carcinogenic hazard.

Reproductive Toxicity May damage the unborn child. Classified as a Known or presumed human developmental toxicant.

STOT - Single Exposure Not expected to cause toxicity to a specific target organ.

STOT - Repeated Exposure Not expected to cause toxicity to a specific target organ.

Aspiration Hazard Not expected to be an aspiration hazard.

Other Information The Australian Acceptable Daily Intake (ADI) for halosulfuron-methyl for a human is 0.01 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the NOEL of 1 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. (Ref: Australian Pesticides and Veterinary Medicines Authority (APVMA) December 2022.)

Section 12 - Ecological Information

Ecotoxicity Very toxic to aquatic life with long lasting effects. No ecological data available for this material. The available ecological data for the ingredients is given below:

Persistence and degradability Not readily biodegradable.

Mobility Not available

Bioaccumulative Potential Not available

Other Precautions Do not graze any treated turf or feed turf clippings from any treated area to poultry or livestock.

Environmental Protection After spraying, the first flush irrigation tailwater or stormwater run-off from land treated with Sempra should be prevented from entering waterways. Where farms do not have the capacity to retain run-off, DO NOT irrigate to the point of run-off for at least 6 days after application. Do not discharge this material into waterways, drains and sewers.

Acute Toxicity - Fish Halosulfuron-methyl LC50 (trout): >120 mg/l/96h LC50 (carp): 340 ppm/96h

Acute Toxicity - Daphnia Halosulfuron-methyl LC50 (daphnia): 170 ppm/48h

Acute Toxicity - Algae Halosulfuron-methyl EC50 (pseudokirchneriella subcapitata): 0.0053 mg/l/72h

Acute Toxicity - Other Organisms Birds: Not toxic to birds. LD50 (bobwhite quail): 2250 mg/kg Bees: Not toxic to bees. LD50: >100 µg/bee. Sempra is very highly toxic to duckweed.

Hazardous to the Ozone Layer This product is not expected to deplete the ozone layer.

Section 13 - Disposal Considerations

Disposal Considerations Dispose of waste according to applicable local and national regulations. Do not allow into drains or watercourses or dispose of where ground or surface waters may be affected. Wastes including emptied containers are controlled wastes and should be disposed of in accordance with all applicable local and national regulations. To minimise personal exposure, refer to Section 8 - Exposure Controls and Personal Protection.

Product Disposal On site disposal of the concentrated product is not acceptable. Ideally, the product should be used for its intended purpose. If there is a need to dispose of the product, approach local authorities who hold periodic collections of unwanted chemicals (ChemClear®).

Container Disposal and Methods If recycling, replace cap and return clean containers to recycler or designated collection point. Triple rinse containers before disposal. Add rinsings to the spray tank. If not recycling, break, crush or puncture and deliver empty packaging for appropriate disposal at an approved waste management facility. If an approved waste management facility is not available, bury the empty packaging 500mm below the surface in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots, in compliance with relevant local, state or territory government regulations. DO NOT burn empty containers or product. Do not dispose of product on site.

Section 14 - Transport Information

Transport Information Road and Rail Transport (ADG Code): This product complies with the requirements of Special Provision AU01 and is therefore exempted from being classified as Dangerous Goods according to the ADG Code. Note: Special Provision AU01: Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to this Code when transported by road or rail in: packagings that do not incorporate a receptacle exceeding 500 kg(L); or IBCs.

Marine Transport (IMO/IMDG): Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Class/Division: 9 UN No: 3077 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Contains Halosulfuron - methyl) MARINE POLLUTANT Packing Group: III EMS: F-A, S-F Special Provisions: 274, 335, 966, 967, 969

Air Transport (ICAO/IATA): Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. Class/Division: 9 UN No: 3077 Proper Shipping Name: Environmentally hazardous substance, solid, n.o.s.(Contains Halosulfuron - methyl) Packing Group: III Label: Miscellaneous Packaging Instructions (passenger & cargo): 956 Packaging Instructions (cargo only): 956 Special provisions: A97, A158, A179, A197, A215

UN Number None Allocated

Proper Shipping Name None Allocated

Transport Hazard Class None Allocated

Hazchem Code 2Z

Special Precautions for User Not available

IMDG Marine pollutant Yes

Transport in Bulk For bulk shipments as Class 9, use UN 3077, HazChem code 2Z.

Section 15 - Regulatory Information

Regulatory Information Classified as Hazardous according to the Globally Harmonised System of Classification and Labelling of Chemicals (GHS) including Work, Health and Safety Regulations, Australia. Classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Australia: WHS regulations (2011) - Schedule 11: classification not listed.

Poisons Schedule S5

Montreal Protocol Not listed

Stockholm Convention Not listed

Rotterdam Convention Not listed

International Convention for the Prevention of Pollution from Ships (MARPOL) Not available

APVMA product number: 56620. This product is registered with the Australian Pesticides and Veterinary Medicines Authority (APVMA).

Basel Convention Not listed

Section 16 - Any Other Relevant Information

Date of Preparation SDS Amended: January 2024, Product Identifier and Product Type updated. SDS Reviewed: January 2023 Supersedes: May 2020

Version Number 4.1

Literature References Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice. Standard for the Uniform Scheduling of Medicines and Poisons. Australian Code for the Transport of Dangerous Goods by Road & Rail. Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals. Code of Practice for Supply Diversion into Illicit Drug Manufacture. National Code of Practice for Chemicals of Security Concern. Agricultural Compounds and Veterinary Chemicals Act. International Agency for Research on Cancer (IARC) Monographs. Montreal Protocol on Substances that Deplete the Ozone Layer. Stockholm Convention on Persistent Organic Pollutants (POPs). Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade. Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal. International Air Transport Association (IATA) Dangerous Goods Regulations. International Maritime Dangerous Goods (IMDG) Code. Workplace exposure standards for airborne contaminants. Adopted biological exposure determinants, American Conference of Industrial Hygienists (ACGIH). Globally Harmonised System of Classification and Labelling of Chemicals (7th revised edition). Code of Practice: Managing Noise and Preventing Hearing Loss at Work.

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