Safety Data Sheet

SDS - Scotts Osmocote CRF Tomato, Vegetable & Herb - 220608

English 494 KB PDF Valid until 2027-06-08

Applies to Osmocote Tomato, Vegetable & Herb Controlled Release Fertiliser

Document contents

Text extracted from the source document for accessibility and reference. Always consult the original safety data sheet above for the authoritative version.

6/20/22, 1:37 PM SDS 1/7 SAFETY DATA SHEET SCOTTS OSMOCOTE TOMATO, VEGETABLE & HERB CONTROLLED RELEASE FERTILISER Infosafe No.: LQ9SA ISSUED Date : 08/06/2022 ISSUED by: Evergreen Garden Care Australia Pty. Ltd.

Section 1 - Identification

Product Identifier SCOTTS OSMOCOTE TOMATO, VEGETABLE & HERB CONTROLLED RELEASE FERTILISER

Product Code 118145, 118245, 118545, 118645, 118745, 118586

Company Name Evergreen Garden Care Australia Pty. Ltd.

Address Building E, Level 2 24-32 Lexington Drive, Bella Vista NSW AUSTRALIA

Telephone/Fax Number

Emergency Phone Number

Recommended use of the chemical and restrictions on use Fertiliser

Section 2 - Hazard(s) Identification

GHS classification of the substance/mixture Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia. Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) Oxidising solids: Category 3 Eye damage/irritation: Category 2A

Signal Word (s) WARNING

Hazard Statement (s) H272 May intensify fire; oxidiser. H319 Causes serious eye irritation.

Pictogram (s) Flame over circle, Exclamation mark [Image of Flame over circle and Exclamation mark pictograms]

Precautionary Statement – Prevention P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep away from clothing and other combustible materials. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection.

6/20/22, 1:37 PM SDS 2/7

Precautionary Statement – Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P370+P378 In case of fire: Use dry chemical, CO2, water spray or "alcohol" foam to extinguish.

Precautionary Statement – Disposal P501 Dispose of contents/container to an approved waste disposal plant.

Section 3 - Composition and Information on Ingredients

Ingredients

Name CAS Proportion
Ammonium nitrate 6484- 52- 2 10- 20 %
Gypsum 13397- 24- 5 1- 10 %
POTASSIUM SULPHATE 7778- 80- 5 1- 10 %
iron (II) sulfate 7720- 78- 7 1- 10 %
sulfur 7704- 34- 9 1- 10 %
manganese sulfate 7785- 87- 7 0. 1- 1 %
Sodium borate anhydrous (Na2B4O7) 1330- 43- 4 0. 1- 1 %
Calcium Fluoride 7789- 75- 5 <0. 1 %
Other ingredients determined not to be hazardous Not Required Balance

Section 4 - First Aid Measures

Inhalation If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seek medical attention.

Ingestion Do not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention.

Skin Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention.

Eye If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing for several minutes until all contaminants are washed out completely. Seek medical attention.

First Aid Facilities Eyewash, safety shower and normal washroom facilities.

Advice to Doctor Treat symptomatically.

Other Information For advice in an emergency, contact a Poisons Information Centre (Phone Australia 131 126) or a doctor at once.

Section 5 - Firefighting Measures

Suitable Extinguishing Media Carbon dioxide, dry chemical, foam, water mist or water spray.

Unsuitable Extinguishing Media Do not use water jet.

Hazards from Combustion Products Non combustible material. Decomposes on heating. Thermal decomposition may produce toxic oxides of carbon, nitrogen.

Specific hazards arising from the chemical

6/20/22, 1:37 PM SDS 3/7 Oxidising. Contact with combustible material may cause fire. Non-combustible, but may support the combustion of other materials. High airborne dust concentrations have the potential for explosions.

Hazchem Code 1Z

Decomposition Temperature Not available

Precautions in connection with Fire Fire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode. In case of fire the product may be violently or explosively reactive. Use water spray to disperse vapours. This product should be prevented from entering drains and watercourses.

Section 6 - Accidental Release Measures

Emergency Procedures Increase ventilation. Evacuate all unprotected personnel. Wear sufficient respiratory protection and full protective clothing to prevent exposure. Sweep up material avoiding dust generation or dampen spilled material with water to avoid airborne dust, then transfer material to a suitable container. Wash surfaces well with soap and water. Seal all wastes in labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations.

Section 7 - Handling and Storage

Precautions for Safe Handling Avoid inhalation of dust, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up of dust in the work atmosphere. Maintain high standards of personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities.

Conditions for safe storage, including any incompatibilities Store in a cool, dry, well-ventilated area, out of direct sunlight and moisture. Store in suitable, labelled containers. Keep containers tightly closed. Store away from incompatible materials. Ensure that storage conditions comply with applicable local and national regulations. For information on the design of the storeroom reference should be made to Australian Standard AS 4326 - The storage and handling of oxidizing agents.

Section 8 - Exposure Controls and Personal Protection

Occupational exposure limit values No exposure standards have been established for this material. However, the available exposure limits for ingredients are listed below: Substance: Magnesium Oxide (fume) TWA: 10 mg/m³ Substance: Manganese (dust and compounds as Mn) TWA: 1 mg/m³ Substance: Fluorides TWA: 2.5 mg/m³ TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight- hour working day, for a five-day week. Source: Safe Work Australia

Biological Monitoring Name: Fluorides Determinant: Fluoride in urine Value: 2 mg/L Sampling time: Prior to shift Value: 3 mg/L

6/20/22, 1:37 PM SDS 4/7 Sampling time: End of shift Source: American Conference of Industrial Hygienists (ACGIH).

Control Banding Not available

Engineering Controls This substance is hazardous and should be used with a local exhaust ventilation system, drawing solid/dust away from workers' breathing zone. If the engineering controls are not sufficient to maintain concentrations of particulates below the exposure standards, suitable respiratory protection must be worn.

Respiratory Protection If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable dust/particulate filter should be used. Refer to relevant regulations for further information concerning respiratory protective requirements. Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances.

Eye and Face Protection Safety glasses with side shields, chemical goggles or full-face shield as appropriate should be used. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform to relevant regulations. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 (series) - Eye Protectors for Industrial Applications.

Hand Protection Wear gloves of impervious material. Final choice of appropriate gloves will vary according to individual circumstances. i.e. methods of handling or according to risk assessments undertaken. Occupational protective gloves should conform to relevant regulations. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.

Thermal Hazards No further relevant information available.

Body Protection Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled.

Section 9 - Physical and Chemical Properties

Properties Description Properties Description
Form Solid - Granules Appearance Brown, black and blue granules
Colour Brown, black and blue Odour Slightly sweet to sweet odour
Melting Point Not available Boiling Point Not available
Decomposition Temperature Not available Solubility in Water Partially soluble
Specific Gravity Not available pH Not available
Vapour Pressure Not available Relative Vapour Density (Air=1) Not available
Evaporation Rate Not available Odour Threshold Not available
Viscosity Not available Volatile Component Not available
Partition Coefficient: n-octanol/water (log value) Not available Flash Point Decomposes on heating.
Flammability Oxidizing Solids Auto-Ignition Temperature Not available
Explosion Limit - Upper Not available Explosion Limit - Lower Not available
Explosion Properties Not available Oxidising Properties Not available
Particle Characteristics Not available

Section 10 - Stability and Reactivity

Reactivity Reacts with incompatible materials.

Chemical Stability Stable under normal conditions of storage and handling.

Possibility of hazardous reactions Not available.

Conditions to Avoid

6/20/22, 1:37 PM SDS 5/7 For quality reasons: Keep out of reach of direct sunlight, store under dry conditions, partly used bags should be closed well.

Incompatible Materials Strong oxidising agents.

Hazardous Decomposition Products Thermal decomposition may produce toxic oxides of carbon, nitrogen.

Hazardous Polymerization Will not occur.

Section 11 - Toxicological Information

Toxicology Information No toxicity data available for this material.

Ingestion Ingestion of this product may irritate the gastric tract causing nausea and vomiting.

Inhalation Inhalation of dusts may irritate the respiratory system.

Skin Skin contact may cause mechanical irritation resulting in redness and itching.

Eye Causes serious eye irritation. On eye contact this product will cause tearing, stinging, blurred vision, and redness.

Respiratory Sensitisation Not expected to be a respiratory sensitiser.

Skin Sensitisation Not expected to be a skin sensitiser.

Germ Cell Mutagenicity Not considered to be a mutagenic hazard.

Carcinogenicity Not considered to be a carcinogenic hazard. Nitrates are listed as a Group 2A: Probably carcinogenic to humans according to International Agency for Research on Cancer (IARC).

Reproductive Toxicity Not considered to be toxic to reproduction.

STOT - Single Exposure Not expected to cause toxicity to a specific target organ.

STOT - Repeated Exposure Not expected to cause toxicity to a specific target organ.

Aspiration Hazard Not expected to be an aspiration hazard.

Section 12 - Ecological Information

Ecotoxicity No ecological data available for this material. Keep out of lakes, streams, or ponds.

Persistence and degradability Not available

Mobility Not available

Bioaccumulative Potential Not available

Other Adverse Effects Not available

Environmental Protection Do not discharge this material into waterways, drains and sewers.

Hazardous to the Ozone Layer This product is not expected to deplete the ozone layer.

Section 13 - Disposal Considerations

6/20/22, 1:37 PM SDS 6/7 Disposal Considerations The disposal of the spilled or waste material must be done in accordance with applicable local and national regulations. To minimise personal exposure to the chemical, refer to Section 8—Exposure controls and personal protection.

Section 14 - Transport Information

Transport Information This material is classified as Dangerous Goods Class 9 Miscellaneous Dangerous Goods Class 9: Miscellaneous substances Dangerous Goods are incompatible in a placard load with any of the following: Class 1: Explosives (when the class 9 substance is a fire risk substance) Division 5.1: Oxidising substances (when the class 9 substance is a fire risk substance) and Division 5.2: Organic peroxides (when the class 9 substance is a fire risk substance)

Marine Transport (IMO/IMDG): Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Class/Division: 9 UN No: 2071 Proper Shipping Name: AMMONIUM NITRATE BASED FERTILIZER Packing Group: III EMS : F-H, S-Q Special Provisions: 193

Air Transport (ICAO/IATA): Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. Class/Division: 9 UN No: 2071 Proper Shipping Name: Ammonium nitrate based fertilizer Packing Group: III Packaging Instructions (passenger & cargo): 958 Packaging Instructions (cargo only): 958 Hazard Label: Miscellaneous Special Provisions: A90

ADG U.N. Number 2071

ADG Proper Shipping Name AMMONIUM NITRATE BASED FERTILIZER

ADG Transport Hazard Class 9

ADG Packing Group III

Hazchem Code 1Z

IERG Number 50

Special Precautions for User Not available

IMDG Marine pollutant No

Transport in Bulk Not available

Section 15 - Regulatory Information

Regulatory Information Classified as Hazardous according to the Globally Harmonised System of Classification and Labelling of Chemicals (GHS) including Work, Health and Safety Regulations, Australia. Classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).

Poisons Schedule

6/20/22, 1:37 PM SDS 7/7 S5

Montreal Protocol Not listed

Stockholm Convention Not listed

Rotterdam Convention Not listed

International Convention for the Prevention of Pollution from Ships (MARPOL) Not available

Not available

Basel Convention Not available

Section 16 - Any Other Relevant Information

Date of Preparation SDS Reviewed: June 2022 Supersedes: October 2019

Version Number Version 2.0

Literature References Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice. Standard for the Uniform Scheduling of Medicines and Poisons. Australian Code for the Transport of Dangerous Goods by Road & Rail. Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals. Code of Practice for Supply Diversion into Illicit Drug Manufacture. National Code of Practice for Chemicals of Security Concern. Agricultural Compounds and Veterinary Chemicals Act. International Agency for Research on Cancer (IARC) Monographs. Montreal Protocol on Substances that Deplete the Ozone Layer. Stockholm Convention on Persistent Organic Pollutants (POPs). Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade. Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal. International Air Transport Association (IATA) Dangerous Goods Regulations. International Maritime Dangerous Goods (IMDG) Code. Workplace exposure standards for airborne contaminants. Adopted biological exposure determinants, American Conference of Industrial Hygienists (ACGIH). Globally Harmonised System of Classification and Labelling of Chemicals (7th revised edition). Code of Practice: Managing Noise and Preventing Hearing Loss at Work.

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