SDS - David Grays Crab Grass & Clover Killer - 220101
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Product Name: David Grays Crab Grass & Clover Killer Selective Weed Killer Page: 1 of 6
SAFETY DATA SHEET
Issued by: David Gray & Co. Pty Ltd Phone: (office hours) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Section 1 - Identification of the Material and Supplier
Chemical nature: An organoarsenic compound. Trade Name: David Grays Crab Grass & Clover Killer APVMA Code: 50739 Product Use: Selective herbicide for use as described on the product label. David Gray & Co O’Connor, WA 6163 Phone: (office hours)
This version issued: January 2022 and is valid for 5 years from this date. Poisons Information Centre: Phone 13 1126 from anywhere in Australia
Section 2 - Hazards Identification
Statement of Hazardous Nature This product is classified as: Xn, Harmful. Hazardous according to the criteria of SWA. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria. SUSMP Classification: S6 ADG Classification: None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria. UN Number: None allocated
[Diagram: GHS Exclamation mark pictogram] [Diagram: GHS Health hazard pictogram]
GHS Signal word: WARNING Acute Toxicity Oral Category 4 Acute Toxicity Dermal Category 4 Acute Toxicity Inhalation Category 4 Specific Target Organ toxicity - repeated exposure Category 2
HAZARD STATEMENT: H302: Harmful if swallowed. H312: Harmful in contact with skin. H332: Harmful if inhaled. H373: May cause damage to organs through prolonged or repeated exposure.
PREVENTION P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P103: Read label before use. P201: Obtain special instruction before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE P314: Get medical advice or attention if you feel unwell. P363: Wash contaminated clothing before reuse. P301+P312: IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell.
Product Name: David Grays Crab Grass & Clover Killer Selective Weed Killer Page: 2 of 6
SAFETY DATA SHEET
Issued by: David Gray & Co. Pty Ltd Phone: (office hours) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P302+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P370+P378: Not combustible. Use extinguishing media suited to burning materials.
STORAGE P405: Store locked up. P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.
DISPOSAL P501: Dispose of contents and containers as specified on the registered label.
Emergency Overview Physical Description & Colour: Clear to slightly hazy colourless liquid. Odour: No data re odour. Major Health Hazards: danger of cumulative effects, harmful by inhalation, in contact with skin, and if swallowed.
Section 3 - Composition/information on Ingredients
| Ingredients | CAS No | Conc,% | TWA (mg/m³) | STEL (mg/m³) |
|---|---|---|---|---|
| DSMA (Disodium methyl arsonate) | 144-21-8 | 74g/L | 0.05* | not set |
| MCPA | 203-46-5 | 24g/L | not set | not set |
| Other ingredients non-hazardous |
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible. The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information: You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.
Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g. watchbands and belts) and completely decontaminate them before reuse or discard.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information Centre, or call a doctor.
First Aid Facilities: Ensure eye wash and safety shower are available.
Medical Attention: Symptoms may be delayed. The first aid procedure should be established in consultation with a doctor responsible for industrial medicine.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen deficient (or both), fire gases. There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. This product is likely to decompose only after heating to dryness, followed by further strong heating.
Product Name: David Grays Crab Grass & Clover Killer Selective Weed Killer Page: 3 of 6
SAFETY DATA SHEET
Issued by: David Gray & Co. Pty Ltd Phone: (office hours) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures. Extinguishing Media: Not combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. Flash point: Does not burn. Upper Flammability Limit: Does not burn. Lower Flammability Limit: Does not burn. Autoignition temperature: Not applicable - does not burn. Flammability Class: Does not burn.
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full protective clothing including eye/face protection. All skin areas should be covered. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include rubber. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned below (section 8). Otherwise, not normally necessary. Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10. Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this schedule of poison. Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715/1716, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
| SWA Exposure Limits | TWA (mg/m³) | STEL (mg/m³) |
|---|---|---|
| DSMA | 0.05 | not set |
The ADI for DSMA is set at 0.0005mg/kg/day. The corresponding NOEL is set at 0.5mg/kg/day. ADI means Acceptable Daily Intake; NOEL means No-observable-effect-level. Data from Australian ADI List, June 2014. Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a fan is suggested. Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used. Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin areas are covered. See below for suitable material types.
Product Name: David Grays Crab Grass & Clover Killer Selective Weed Killer Page: 4 of 6
SAFETY DATA SHEET
Issued by: David Gray & Co. Pty Ltd Phone: (office hours) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber. Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above. Otherwise, not normally necessary. Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Clear to hazy colourless liquid Odour: No data re odour. Boiling Point: Approximately 100°C at 100kPa. Freezing/Melting Point: Below 0°C. Volatiles: Water component. Vapour Pressure: 2.37 kPa at 20°C (water vapour pressure). Vapour Density: As for water. Specific Gravity: No data. Water Solubility: Completely soluble in water. pH: 7.0 – 9.5 Volatility: No data. Odour Threshold: No data. Evaporation Rate: As for water. Coeff Oil/water Distribution: No data Autoignition temp: Not applicable - does not burn.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Incompatibilities: strong acids, strong bases, strong oxidising agents. Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong heating. Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also formed. Sodium and arsenic compounds. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Local Effects: Target Organs: There is no data to hand indicating any particular target organs.
Classification of Hazardous Ingredients
| Ingredient | Risk Phrases |
|---|---|
| No ingredient mentioned in the HSIS Database is present in this product at hazardous concentrations. |
The following refers to DSMA –the active ingredient: Acute oral LD50: > 1800 mg/kg in rats Acute dermal LD50: > 10,000 mg/kg in rabbits CARCINOGENICITY: Based on a 90 day rat feeding study the no effect level was found to be 186 ppm for methanearsonic acid (100%). TERATOGENIC EFFECTS: No data
Potential Health Effects Inhalation: Short Term Exposure: Available data shows that this product is harmful, but symptoms are not available. In addition product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term inhalation.
Product Name: David Grays Crab Grass & Clover Killer Selective Weed Killer Page: 5 of 6
SAFETY DATA SHEET
Issued by: David Gray & Co. Pty Ltd Phone: (office hours) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Skin Contact: Short Term Exposure: Available data shows that this product is harmful, but symptoms are not available. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short Term Exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product is harmful, but symptoms are not available. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 12 - Ecological Information
This product is biodegradable. It will not accumulate in the soil or water or cause long term problems. The following refers to DSMA & MCPA–the active ingredient: ECOTOXICOLOGY: Birds: No data. Fish: Slightly toxic to fish. Bees: Acutely Toxic to slightly toxic ENVIRONMENTAL BREAKDOWN: DSMA is metabolised by soil bacteria to methylarsine, arsenate and methylarsonate (half life in soil is 55 days). Do not contaminate dams, waterways or sewers with this product.
Section 13 - Disposal Considerations
Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. Dispose of empty container by wrapping in paper, placing in a plastic bag and putting in garbage.
Section 14 - Transport Information
UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special transport conditions are necessary unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations. The following ingredient: DSMA, is mentioned in the SUSMP.
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature.
Acronyms: ADG Code: Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition) AICS: Australian Inventory of Chemical Substances SWA: Safe Work Australia, formerly ASCC and NOHSC CAS number: Chemical Abstracts Service Registry Number IARC: International Agency for Research on Cancer
Product Name: David Grays Crab Grass & Clover Killer Selective Weed Killer Page: 6 of 6
SAFETY DATA SHEET
Issued by: David Gray & Co. Pty Ltd Phone: (office hours) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
NOS: Not otherwise specified NTP: National Toxicology Program (USA) R-Phrase: Risk Phrase SUSMP: Standard for the Uniform Scheduling of Medicines & Poisons UN Number: United Nations Number
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product. This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous Chemicals - Code of Practice” (December 2011) Copyright © David Gray & Co. Pty Ltd, January 2022.