SDS - Envu Exteris StressGard Turf Fungicide - 240906
Applies to Exteris Stressgard | Turf Fungicide
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SAFETY DATA SHEET Exteris StressGard Turf Fungicide
Version 2.0 Revision Date: 12.11.2024 SDS Number: 11436144-00002 Date of last issue: 06.09.2024 Date of first issue: 06.09.2024 1 / 21
SECTION 1: IDENTIFICATION Product name : Exteris StressGard Turf Fungicide Product code : Article/SKU: 85767097 UVP: 81753938 Specification: 102000028296
Manufacturer or supplier's details Company : 2022 Environmental Science AU Pty Ltd
Address : Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123 Emergency telephone number :
Recommended use of the chemical and restrictions on use Recommended use : Fungicide Plant protection agent Restrictions on use : Not applicable
SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin sensitisation : Category 1 Effects on or via lactation
GHS label elements Hazard pictograms : [Exclamation mark pictogram] Signal word : Warning Hazard statements : H317 May cause an allergic skin reaction. H362 May cause harm to breast-fed children. Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe mist or vapours. P263 Avoid contact during pregnancy and while nursing. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of water. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P321 Specific treatment (see supplemental first aid instructions on this label). P333 + P313 If skin irritation or rash occurs: Get medical ad vice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards which do not result in classification None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Suspension concentrate (=flowable concentrate)(SC)
Components
| Chemical name | CAS-No. | Concentration (% w/w) |
|---|---|---|
| Propylene glycol | 57-55-6 | < 10 |
| Isotridecyl alcohol, ethoxylated, phosphated | 73038-25-2 | >= 3 -< 10 |
| Alcohols, C12-16, ethoxylated | 68551-12-2 | >= 1 -< 3 |
| Trifloxystrobin | 141517-21-7 | >= 1 -< 10 |
| Fluopyram | 658066-35-4 | < 10 |
| Potassium hydroxide | -3 | >= 0.5 -< 1 |
SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical ad vice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : Get medical attention. In case of skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. In case of eye contact : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists. If swallowed : Get medical attention. Most important symptoms and effects, both acute and delayed : No symptoms known or expected. May cause an allergic skin reaction. May cause harm to breast-fed children. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8). Notes to physician : There is no specific antidote available. Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. Appropriate supportive and symptomatic treatment as indicat ed by the patient's condition is recommended.
SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Vapours may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod ucts : Carbon oxides Oxides of phosphorus Chlorine compounds Nitrogen oxides (NOx) Fluorine compounds Specific extinguishing meth ods : Use extinguishing measures that are appropriate to local cir cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Hazchem Code : •3Z
SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec tive equipment and emer gency procedures : Use personal protective equipment. Follow safe handling advice (see section 7) and personal pro tective equipment recommendations (see section 8). Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Soak up with inert absorbent material. For large spills, provide dyking or other appropriate contain ment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absor bent. Local or national regulations may apply to releases and dis posal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter mine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use only with adequate ventilation. Advice on safe handling : Avoid contact during pregnancy and while nursing. Do not get on skin or clothing. Do not breathe mist or vapours. Do not swallow. Avoid contact with eyes. Wash skin thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure as sessment Do not eat, drink or smoke when using this product. Take care to prevent spills, waste and minimize release to the environment. Hygiene measures : If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before re-use. Conditions for safe storage : Keep in properly labelled containers. Store in accordance with the particular national regulations. Materials to avoid : Do not store with the following product types: Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters
| Components | CAS-No. | Value type (Form of exposure) | Control parameters / Permissible concentration | Basis |
|---|---|---|---|---|
| Propylene glycol | 57-55-6 | TWA (particulate) | 10 mg/m3 | AU OEL |
| TWA (Total (vapour and particles)) | 150 ppm 474 mg/m3 | AU OEL | ||
| Potassium hydroxide | -3 | Peak limit | 2 mg/m3 | AU OEL |
| C | 2 mg/m3 | ACGIH |
Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : If adequate local exhaust ventilation is not available or expo sure assessment demonstrates exposures outside the rec ommended guidelines, use respiratory protection. Filter type : Combined particulates and organic vapour type Hand protection Material : Nitrile rubber Break through time : > 480 min Glove thickness : > 0.4 mm Protective index : Class 6 Remarks : Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local condi tions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous sub stance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufactur er. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety glasses Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : suspension Colour : green Odour : characteristic Odour Threshold : No data available pH : 6.00 (23 °C) Concentration: 100 % Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : > 93.30 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available Upper explosion limit / Upper flammability limit : No data available Lower explosion limit / Lower flammability limit : No data available Vapour pressure : No data available Relative vapour density : No data available Density : 1.05 g/cm³ (20.00 °C) Solubility(ies) Water solubility : dispersible Partition coefficient: n octanol/water : Not applicable Auto-ignition temperature : 420 °C Decomposition temperature : No data available Viscosity Viscosity, dynamic : 100 - 300 mPa.s ( 20 °C) Viscosity, kinematic : No data available Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. Surface tension : 33.00 mN/m, 20 °C Particle characteristics Particle size : Not applicable
SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac tions : Vapours may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : None known. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known.
SECTION 11. TOXICOLOGICAL INFORMATION Exposure routes : Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Remarks: Based on data from similar materials Components: Propylene glycol: Acute oral toxicity : LD50 (Rat): 22,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 44.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Alcohols, C12-16, ethoxylated: Acute oral toxicity : LD50 (Rat): > 300 - 2,000 mg/kg Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Trifloxystrobin: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Fluopyram: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 423 Assessment: The substance or mixture has no acute oral tox icity Acute inhalation toxicity : LC50 (Rat): > 5.11 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: The substance or mixture has no acute inhala tion toxicity Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Potassium hydroxide: Acute oral toxicity : LD50 (Rat): 333 mg/kg Acute inhalation toxicity : Assessment: Corrosive to the respiratory tract. Skin corrosion/irritation Not classified based on available information. Product: Species : Rabbit Result : Mild skin irritation Remarks : Based on data from similar materials Components: Propylene glycol: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation Isotridecyl alcohol, ethoxylated, phosphated: Result : Skin irritation Alcohols, C12-16, ethoxylated: Species : Rabbit Result : No skin irritation Remarks : Based on data from similar materials Fluopyram: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation Potassium hydroxide: Species : Rabbit Result : Corrosive after 3 minutes or less of exposure Serious eye damage/eye irritation Not classified based on available information. Product: Result : No eye irritation Components: Propylene glycol: Species : Rabbit Result : No eye irritation Method : OECD Test Guideline 405 Isotridecyl alcohol, ethoxylated, phosphated: Result : Irreversible effects on the eye Alcohols, C12-16, ethoxylated: Species : Rabbit Result : Irreversible effects on the eye Remarks : Based on data from similar materials Fluopyram: Species : Rabbit Result : No eye irritation Method : OECD Test Guideline 405 Potassium hydroxide: Species : Rabbit Result : Irreversible effects on the eye Respiratory or skin sensitisation Skin sensitisation May cause an allergic skin reaction. Respiratory sensitisation Not classified based on available information. Product: Test Type : Local lymph node assay (LLNA) Exposure routes : Skin contact Species : Mouse Method : OECD Test Guideline 429 Result : positive Remarks : Based on data from similar materials Assessment : Probability or evidence of skin sensitisation in humans Components: Propylene glycol: Test Type : Maximisation Test Exposure routes : Skin contact Species : Guinea pig Result : negative Alcohols, C12-16, ethoxylated: Exposure routes : Skin contact Species : Guinea pig Method : OECD Test Guideline 406 Result : negative Remarks : Based on data from similar materials Trifloxystrobin: Assessment : Probability or evidence of skin sensitisation in humans Remarks : Based on national or regional regulation. Fluopyram: Test Type : Local lymph node assay (LLNA) Exposure routes : Skin contact Species : Mouse Method : OECD Test Guideline 429 Result : negative Potassium hydroxide: Test Type : Intracutaneous test Exposure routes : Skin contact Species : Guinea pig Result : negative Chronic toxicity Germ cell mutagenicity Not classified based on available information. Components: Propylene glycol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative Trifloxystrobin: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Test Type: Chromosome aberration test in vitro Result: negative Test Type: DNA damage and repair, unscheduled DNA syn thesis in mammalian cells (in vitro) Result: negative Fluopyram: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative Potassium hydroxide: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Carcinogenicity Not classified based on available information. Components: Propylene glycol: Species : Rat Application Route : Ingestion Exposure time : 2 Years Result : negative Trifloxystrobin: Species : Rat Application Route : Ingestion Exposure time : 24 Months Result : negative Fluopyram: Species : Rat Application Route : Ingestion Exposure time : 104 weeks Method : OECD Test Guideline 453 Result : positive Remarks : The mechanism or mode of action is not relevant in humans. Reproductive toxicity May cause harm to breast-fed children. Components: Propylene glycol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Result: negative Effects on foetal develop ment : Test Type: Embryo-foetal development Species: Mouse Application Route: Ingestion Result: negative Trifloxystrobin: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Effects on foetal develop ment : Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Reproductive toxicity - As sessment : Studies indicating a hazard to babies during the lactation peri od Fluopyram: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Effects on foetal develop ment : Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Components: Trifloxystrobin: Assessment : No significant health effects observed in animals at concentra tions of 100 mg/kg bw or less. Repeated dose toxicity Components: Propylene glycol: Species : Rat, male NOAEL : >= 1,700 mg/kg Application Route : Ingestion Exposure time : 2 yr Trifloxystrobin: Species : Rat NOAEL : 10 mg/kg Application Route : Ingestion Exposure time : 2 yr Fluopyram: Species : Dog, male NOAEL : 13.2 mg/kg LOAEL : 67.6 mg/kg Application Route : Ingestion Exposure time : 1 yr Method : OECD Test Guideline 452 Aspiration toxicity Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 1.42 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.75 mg/l Exposure time: 48 h Remarks: Based on data from similar materials EC50 (Mysidopsis bahia (opossum shrimp)): 0.00862 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to algae/aquatic plants : ErC50 (Raphidocelis subcapitata (freshwater green alga)): 0.0025 mg/l Exposure time: 72 h EC10 (Desmodesmus subspicatus (green algae)): 5.25 mg/l Exposure time: 72 h Remarks: Based on data from similar materials Ecotoxicology Assessment Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects. Components: Propylene glycol: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Ceriodaphnia dubia (water flea)): 18,340 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : ErC50 (Skeletonema costatum (marine diatom)): 19,300 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chron ic toxicity) : NOEC (Ceriodaphnia dubia (water flea)): 13,020 mg/l Exposure time: 7 d Toxicity to microorganisms : NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h Isotridecyl alcohol, ethoxylated, phosphated: Toxicity to algae/aquatic plants : EC50: > 0.1 - 1 mg/l Exposure time: 72 h Ecotoxicology Assessment Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects. Alcohols, C12-16, ethoxylated: Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 1 - 10 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chron ic toxicity) : NOEC (Daphnia (water flea)): > 0.1 - 1 mg/l Remarks: Based on data from similar materials Trifloxystrobin: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.015 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Mysidopsis bahia (opossum shrimp)): 0.00862 mg/l Exposure time: 96 h Toxicity to algae/aquatic plants : ErC50 (Desmodesmus subspicatus (green algae)): 0.0174 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 EC10 (Desmodesmus subspicatus (green algae)): 0.0025 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic tox icity) : EC10 (Oncorhynchus mykiss (rainbow trout)): 0.0075 mg/l Exposure time: 95 d Toxicity to daphnia and other aquatic invertebrates (Chron ic toxicity) : EC10 (Daphnia magna (Water flea)): 0.00328 mg/l Exposure time: 21 d Fluopyram: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 2 mg/l Exposure time: 96 h Remarks: No toxicity at the limit of solubility Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 20 mg/l Exposure time: 48 h Remarks: No toxicity at the limit of solubility Toxicity to algae/aquatic plants : ErC50 (Lemna gibba (gibbous duckweed)): 2.51 mg/l Exposure time: 7 d NOEC (Lemna gibba (gibbous duckweed)): 1.6 mg/l Exposure time: 7 d Toxicity to fish (Chronic tox icity) : NOEC (Pimephales promelas (fathead minnow)): 0.135 mg/l Exposure time: 33 d Method: OECD Test Guideline 210 Toxicity to daphnia and other aquatic invertebrates (Chron ic toxicity) : NOEC (Daphnia magna (Water flea)): 1.22 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Persistence and degradability Components: Propylene glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F Isotridecyl alcohol, ethoxylated, phosphated: Biodegradability : Result: Readily biodegradable. Biodegradation: 74.2 % Exposure time: 28 d Method: OECD Test Guideline 301E Alcohols, C12-16, ethoxylated: Biodegradability : Result: Readily biodegradable. Biodegradation: > 70 % Exposure time: 28 d Method: OECD Test Guideline 301E Remarks: Based on data from similar materials Bioaccumulative potential Components: Propylene glycol: Partition coefficient: n octanol/water : log Pow: -1.07 Method: Regulation (EC) No. 440/2008, Annex, A.8 Trifloxystrobin: Bioaccumulation : Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): 431 Method: OECD Test Guideline 305 Partition coefficient: n octanol/water : log Pow: 4.5 Method: OECD Test Guideline 107 Fluopyram: Bioaccumulation : Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): 18 Method: OECD Test Guideline 305 Partition coefficient: n octanol/water : log Pow: 3.3 Method: OECD Test Guideline 107 Mobility in soil No data available Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer. Contaminated packaging : Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trifloxystrobin) Class : 9 Packing group : III Labels : 9 Environmentally hazardous : yes IATA-DGR UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (Trifloxystrobin) Class : 9 Packing group : III Labels : Miscellaneous Packing instruction (cargo aircraft) : 964 Packing instruction (passen ger aircraft) : 964 Environmentally hazardous : yes IMDG-Code UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trifloxystrobin) Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : yes Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations ADG UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trifloxystrobin) Class : 9 Packing group : III Labels : 9 Hazchem Code : •3Z Environmentally hazardous : yes Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var iations in regional or country regulations.
SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mix ture Therapeutic Goods (Poisons Standard) Instrument : Schedule 6 (Please use the original publication to check for specific uses, specific conditions or threshold limits that might apply for this chemical) Therapeutic Goods (Poisons Standard) Instrument : Schedule 5 Prohibition/Licensing Requirements : There is no applicable prohibition, authorisation and restricted use requirements, including for carcino gens referred to in Schedule 10 of the model WHS Act and Regula tions. Active substance : 12.5 g/l Fluopyram 12.5 g/l Trifloxystrobin
SECTION 16: ANY OTHER RELEVANT INFORMATION Further information Revision Date : 12.11.2024 Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen cy, Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines. Date format : dd.mm.yyyy Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) AU OEL : Australia. Workplace Exposure Standards for Airborne Con taminants. ACGIH / C : Ceiling limit AU OEL / TWA : Exposure standard - time weighted average AU OEL / Peak limit : Exposure standard - peak AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans portation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Sub stances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recom mendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumu lative; WHMIS - Workplace Hazardous Materials Information System
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor mation and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS mate rial is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the ap propriateness of the SDS material in the user’s end product, if applicable. AU / EN