SDS - Envu Interface Stressgard Turf Fungicide - 240702

Safety Data Sheet

Interface® Stressgard® Turf Fungicide 1/12 Version 2.1 / AUS Revision Date: 02.07.2024 102000021104 Print Date: 02.07.2024

SECTION 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER

1.1 Product identifier Trade name Interface® Stressgard® Turf Fungicide Product code (UVP) 79653646, 81777721

1.2 Relevant identified uses of the substance or mixture and uses advised against Use Fungicide

H351 Suspected of causing cancer. Effects on or via lactation H362 May cause harm to breast-fed children. Acute aquatic toxicity: Category 1 H400 Very toxic to aquatic life. Chronic aquatic toxicity: Category 1 H410 Very toxic to aquatic life with long lasting effects.

2.2 Label elements Labelling according to specific Australian legislation Hazard label for supply/use required.

Hazardous components which must be listed on the label: Iprodione Trifloxystrobin Signal word: Warning Hazard statements H351 Suspected of causing cancer. H362 May cause harm to breast-fed children. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P263 Avoid contact during pregnancy and while nursing. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulation.

2.3 Other hazards No additional hazards known beside those mentioned.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature Iprodione/Trifloxystrobin 256.40 : 16.00 g/l Suspension concentrate (=flowable concentrate)(SC)

SECTION 4. FIRST AID MEASURES

If poisoning occurs, immediately contact a doctor or Poisons Information Centre (telephone 13 11 26), and follow the advice given. Show this Safety Data Sheet to the doctor.

4.1 Description of first aid measures General advice Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely. Inhalation Move to fresh air. In case of respiratory arrest induce breathing with a respiratory device. Seek medical advice. Call a physician or poison control center immediately. Skin contact Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

4.2 Most important symptoms and effects, both acute and delayed Symptoms To date no symptoms are known.

4.3 Indication of any immediate medical attention and special treatment needed Treatment Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote.

SECTION 5. FIRE FIGHTING MEASURES

5.1 Extinguishing media Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable High volume water jet

5.2 Special hazards arising from the substance or mixture In the event of fire the following may be released:, Hydrogen cyanide (hydrocyanic acid), Hydrogen fluoride, Hydrogen chloride (HCl), Carbon monoxide (CO), Carbon dioxide (CO2), Nitrogen oxides (NOx)

5.3 Advice for firefighters Special protective equipment for firefighters In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. Further information Keep out of smoke. Fight fire from upwind position. Remove product from areas of fire, or otherwise cool containers with water in order to avoid pressure being built up due to heat. Whenever possible, contain fire-fighting water by diking area with sand or earth. Do not allow run-off from fire fighting to enter drains or water courses. Avoid contact with spilled product or contaminated surfaces. Hazchem Code •3Z

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures Precautions Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment.

6.2 Environmental precautions Do not allow to get into surface water, drains and ground water. Retain and dispose of contaminated wash water. If the product contaminates rivers and lakes or drains inform respective authorities.

6.3 Methods and materials for containment and cleaning up Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations. Additional advice Use personal protective equipment. If the product is accidentally spilled, do not allow to enter soil, waterways or waste water canal.

6.4 Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13.

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling Advice on safe handling Use only in area provided with appropriate exhaust ventilation. Advice on protection against fire and explosion No special precautions required. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove and wash contaminated gloves, including the inside, before re-use. Keep working clothes separately. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).

7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Keep containers tightly closed in a dry, cool and well-ventilated place. Store in original container. Store in a place accessible by authorized persons only. Keep away from direct sunlight. Protect from freezing. Advice on common storage Keep away from food, drink and animal feedingstuffs.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

*OES BCS:Bayer AG, Crop Science Division "Occupational Exposure Standard"

8.2 Exposure controls Respiratory protection Respiratory protection is not required under anticipated circumstances of exposure. Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance. Hand protection Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Wash gloves when contaminated. Dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet. Material Nitrile rubber Rate of permeability > 480 min Glove thickness > 0.4 mm Protective index Class 6 Directive Protective gloves complying with EN 374. Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent). Skin and body protection Wear standard coveralls and Category 3 Type 6 suit. If there is a risk of significant exposure, consider a higher protective type suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently. General protective measures In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the above mentioned recommendations would apply.

Engineering Controls Advice on safe handling Use only in area provided with appropriate exhaust ventilation.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties Form suspension Colour green Odour musty Odour Threshold No data available pH 4.0 - 7.0 (100 %) (23 °C) Melting point/range No data available Boiling Point No data available Flash point No flash point - Determination conducted up to the boiling point. Flammability No data available Auto-ignition temperature No data available Thermal decomposition No data available Minimum ignition energy Not applicable Self-accelarating decomposition temperature (SADT) No data available Upper explosion limit No data available Lower explosion limit No data available Vapour pressure No data available Evaporation rate No data available Relative vapour density No data available Relative density No data available Density 1.11 g/cm³ (20 °C) Water solubility dispersible Partition coefficient: n-octanol/water Trifloxystrobin: log Pow: 4.5 (25 °C) Viscosity, dynamic 550 - 1,000 cps (25 °C) Viscosity, kinematic No data available Oxidizing properties No data available Explosivity Not explosive 9.2 Other information Further safety related physical-chemical data are not known.

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity Stable under normal conditions. 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No hazardous reactions when stored and handled according to prescribed instructions. 10.4 Conditions to avoid Extremes of temperature and direct sunlight. 10.5 Incompatible materials Store only in the original container. 10.6 Hazardous decomposition products No decomposition products expected under normal conditions of use.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects Acute oral toxicity LD50 (Rat) 5,000 mg/kg Acute inhalation toxicity LC50 (Rat) > 2.56 mg/l Exposure time: 4 h Determined in the form of liquid aerosol. highest concentration tested Acute dermal toxicity LD50 (Rat) > 5,000 mg/kg Skin corrosion/irritation No skin irritation (Rabbit) Serious eye damage/eye irritation slight irritation (Rabbit) Respiratory or skin sensitisation Skin: Non-sensitizing. (Guinea pig) OECD Test Guideline 406, Buehler test Skin: Non-sensitizing. (Mouse) OECD Test Guideline 429, local lymph node assay (LLNA)

Assessment mutagenicity Iprodione was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests. Trifloxystrobin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment carcinogenicity Iprodione caused at high dose levels an increased incidence of tumours in the following organ(s): Liver, Testes. The mechanism that triggers tumours in rodents and the type of tumours observed are not relevant to humans. Trifloxystrobin was not carcinogenic in lifetime feeding studies in rats and mice.

Assessment toxicity to reproduction Iprodione did not cause reproductive toxicity in a two-generation study in rats. Trifloxystrobin caused reduced body weight development in offspring during lactation only at doses also producing systemic toxicity in adult rats.

Assessment developmental toxicity Iprodione caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Iprodione are related to maternal toxicity. Trifloxystrobin caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Trifloxystrobin are related to maternal toxicity.

Assessment STOT Specific target organ toxicity – single exposure Iprodione: Based on available data, the classification criteria are not met. Trifloxystrobin: Based on available data, the classification criteria are not met.

Assessment STOT Specific target organ toxicity – repeated exposure Iprodione caused specific target organ toxicity in experimental animal studies in rats in the following organ(s): Adrenal gland. Trifloxystrobin did not cause specific target organ toxicity in experimental animal studies.

Aspiration hazard Based on available data, the classification criteria are not met.

Information on likely routes of exposure Caution! Harmful if swallowed., Avoid contact with skin, eyes and clothing., Wash thoroughly with soap and water after handling. Avoid contact or inhalation of spray mist. Harmful if swallowed., Do not take internally. This product or its components may have target organ effects., This product or its components may have long term (chronic) health effects. Toxic to fish and aquatic invertebrates.

Early onset symptoms related to exposure Refer to Section 4

Delayed health effects from exposure Refer to Section 11

Exposure levels and health effects Refer to Section 4

Interactive effects Not known

When specific chemical data is not available Not applicable

Mixture of chemicals Refer to Section 2.1

Further information Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s). No further toxicological information is available.

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 1.47 mg/l Exposure time: 96 h Toxicity to aquatic invertebrates EC50 (Daphnia magna (Water flea)) 0.6 mg/l Exposure time: 48 h LC50 (Mysidopsis bahia (mysid shrimp)) 0.00862 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient trifloxystrobin. Toxicity to aquatic plants ErC50 (Raphidocelis subcapitata (freshwater green alga)) 5.32 mg/l Growth rate; Exposure time: 72 h EC10 (Desmodesmus subspicatus (green algae)) 0.0025 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient trifloxystrobin. Toxicity to other organisms LD50 (Apis mellifera (bees)) Exposure time: 48 d Non-hazardous for bees.

12.2 Persistence and degradability Biodegradability Iprodione: Not rapidly biodegradable Trifloxystrobin: Not rapidly biodegradable Koc Iprodione: Koc: 202 - 543 Trifloxystrobin: Koc: 2377

12.3 Bioaccumulative potential Bioaccumulation Iprodione: Bioconcentration factor (BCF) 70 Does not bioaccumulate. Trifloxystrobin: Bioconcentration factor (BCF) 431 Does not bioaccumulate.

12.4 Mobility in soil Mobility in soil Iprodione: Moderately mobile in soils Trifloxystrobin: Slightly mobile in soils

12.5 Other adverse effects Additional ecological information No other effects to be mentioned.

SECTION 13. DISPOSAL CONSIDERATIONS

Triple or preferably pressure rinse containers before disposal. Dispose of rinsings in a disposal pit specifically marked and set up for this purpose, clear of waterways, desirable vegetation and tree roots. If recycling, replace cap and return clean containers to recycler or designated collection point. If not recycling, break, crush or puncture and deliver empty packaging for appropriate disposal to an approved waste management facility. If an approved waste management facility is not available bury the empty packaging 500 mm below the surface in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots, in compliance with relevant Local, State or Territory Government Regulations. DO NOT burn empty containers or product.

SECTION 14. TRANSPORT INFORMATION

ADG UN number 3082 Transport hazard class(es) 9 Subsidiary Risk None Packaging group III Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (IPRODIONE SOLUTION) Hazchem Code •3Z AU01: Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to this Code when transported by road or rail in; a) packagings that do not incorporate a receptacle exceeding 500 kg(L); or b) IBCs

IMDG UN number 3082 Transport hazard class(es) 9 Subsidiary Risk None Packaging group III Marine pollutant YES Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (IPRODIONE SOLUTION)

IATA UN number 3082 Transport hazard class(es) 9 Subsidiary Risk None Packaging group III Environm. Hazardous Mark YES Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (IPRODIONE SOLUTION )

SECTION 15. REGULATORY INFORMATION

Australian Pesticides and Veterinary Medicines Authority approval number: 68029 SUSMP classification (Poison Schedule) Schedule 5 (Standard for the Uniform Scheduling of Medicines and Poisons)

SECTION 16. OTHER INFORMATION

Trademark information Interface® and Stressgard® are Registered Trademarks.

Abbreviations and acronyms ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR European Agreement concerning the International Carriage of Dangerous Goods by Road ATE Acute toxicity estimate AU OEL Australia. OELs. (Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment) CAS-Nr. Chemical Abstracts Service number CEILING Ceiling Limit Value Conc. Concentration EC-No. European community number ECx Effective concentration to x % EINECS European inventory of existing commercial substances ELINCS European list of notified chemical substances EN European Standard EU European Union IATA International Air Transport Association IBC International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk (IBC Code) ICx Inhibition concentration to x % IMDG International Maritime Dangerous Goods LCx Lethal concentration to x % LDx Lethal dose to x % LOEC/LOEL Lowest observed effect concentration/level MARPOL MARPOL: International Convention for the prevention of marine pollution from ships N.O.S. Not otherwise specified NOEC/NOEL No observed effect concentration/level OECD Organization for Economic Co-operation and Development OES BCS OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard" PEAK PEAK: Exposure Standard - Peak means a maximum or peak airborne concentration of a particular substance determined over the shortest analytically practicable period of time which does not exceed 15 minutes. RID Regulations concerning the International Carriage of Dangerous Goods by Rail SK-SEN Skin sensitiser SKIN_DES SKIN_DES: Skin notation: Absorption through the skin may be a significant source of exposure. STEL STEL: Exposure standard - short term exposure limit (STEL): A 15 minute TWA exposure which should not be exceeded at any time during a working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There should be at least 60 minutes between successive exposures at the STEL. TWA TWA: Exposure standard - time-weighted average (TWA): The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day working week. TWA Time weighted average UN United Nations WHO World health organisation

This SDS summarises our best knowledge of the health and safety hazard information of the product and how to safely handle and use the product in the workplace. Each user should read this SDS and consider the information in the context of how the product will be handled and used in the workplace including in conjunction with other products.

Changes since the last version are highlighted in the margin. This version replaces all previous versions.