SDS - Envu Signature Xtra Stressgard Systemic Fungcide - 231109

SAFETY DATA SHEET

SIGNATURE XTRA STRESSGARD SYSTEMIC TURF FUNGICIDE

Version 1.0

Revision Date: 09.11.2023

SDS Number: 11292565-00001

Date of last issue: - Date of first issue: 09.11.2023

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SECTION 1: IDENTIFICATION

Product name : SIGNATURE XTRA STRESSGARD SYSTEMIC TURF FUNGICIDE

Product code : Article/SKU: 86802724, 85785265 UVP: 81691088 Specification: 102000029598

Manufacturer or supplier's details

Company : 2022 Environmental Science AU Pty Ltd

Address : Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123

Emergency telephone number :

Recommended use of the chemical and restrictions on use

Recommended use : Fungicide Plant protection agent

Restrictions on use : Not applicable

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Serious eye damage/eye irritation : Category 2B

GHS label elements

Hazard pictograms : None

Signal word : Warning

Hazard statements : H320 Causes eye irritation.

Precautionary statements :

Prevention: P264 Wash skin thoroughly after handling.

Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention.

Other hazards which do not result in classification

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Water dispersible granules (WG)

Components

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.

If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur.

In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention.

If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.

Most important symptoms and effects, both acute and delayed : The following symptoms may occur: The product causes irritation of eyes, skin and mucous membranes. Causes eye irritation. This product is not a cholinesterase inhibitor.

Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8).

Notes to physician : There is no specific antidote available. Treat symptomatically. Gastric lavage is not normally required. However, if a significant amount (more than a mouthful) has been ingested, administer activated charcoal and sodium sulphate. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing media : High volume water jet

Specific hazards during fire fighting : Exposure to combustion products may be a hazard to health.

Hazardous combustion products : Carbon oxides Oxides of phosphorus Metal oxides Sulphur oxides Chlorine compounds Nitrogen oxides (NOx)

Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.

Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8).

Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up : Sweep up or vacuum up spillage and collect in suitable container for disposal. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Wash skin thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment Take care to prevent spills, waste and minimize release to the environment.

Hygiene measures : If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.

Conditions for safe storage : Keep in properly labelled containers. Store in accordance with the particular national regulations.

Materials to avoid : Do not store with the following product types: Strong oxidizing agents

Recommended storage temperature : 0 - 35 °C

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.

Personal protective equipment

Respiratory protection : If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection.

Filter type : Combined particulates and organic vapour type

Hand protection Material : Nitrile rubber Break through time : > 480 min Glove thickness : > 0.4 mm Protective index : Class 6

Remarks : Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.

Eye protection : Wear the following personal protective equipment: Safety goggles

Skin and body protection : Skin should be washed after contact.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : granules

Colour : green

Odour : acidic, slight

Odour Threshold : No data available

pH : 3.0 - 5.0 (23 °C) Concentration: 10 %

Melting point/freezing point : No data available

Initial boiling point and boiling range : No data available

Flash point : Not applicable

Evaporation rate : Not applicable

Flammability (solid, gas) : Not classified as a flammability hazard

Self-ignition : Method: Regulation (EC) No. 440/2008, Annex, A.16 The substance or mixture is not classified as self heating.

Upper explosion limit / Upper flammability limit : Not applicable

Lower explosion limit / Lower flammability limit : Not applicable

Vapour pressure : Not applicable

Relative vapour density : Not applicable

Relative density : No data available

Bulk density : 705 kg/m³

Solubility(ies) Water solubility : dispersible

Partition coefficient: n-octanol/water : Not applicable

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity Viscosity, kinematic : Not applicable

Explosive properties : Not explosive Method: Regulation (EC) No. 440/2008, Annex, A.14

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Dust explosion class : No data available

Particle size : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reactions : Can react with strong oxidizing agents.

Conditions to avoid : None known.

Incompatible materials : Strong oxidizing agents Strong acids and strong bases Oxidizing agents

Hazardous decomposition products : No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Exposure routes : Skin contact Ingestion Eye contact

Acute toxicity Not classified based on available information.

Product: Acute oral toxicity : LD50 (Rat, female): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.22 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg

Components:

Fosetyl-aluminium: Acute oral toxicity : LD50 (Rabbit): 2,680 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.11 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Acute oral toxicity : LD50 (Rat): > 453 - 1,368 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC50 (Rat, male): 1.09 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Acute dermal toxicity : LD50 (Rabbit, male): > 2,000 mg/kg Remarks: Based on data from similar materials

Formic acid: Acute oral toxicity : LD50 (Rat): 730 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC50 (Rat): 7.85 mg/l Exposure time: 4 h Test atmosphere: vapour Method: OECD Test Guideline 403 Assessment: Corrosive to the respiratory tract. Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Remarks: Based on data from similar materials

Skin corrosion/irritation Not classified based on available information.

Product: Species : Rabbit Result : No skin irritation

Components:

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Species : Rabbit Result : No skin irritation

Formic acid: Result : Corrosive after 3 minutes or less of exposure Remarks : Based on national or regional regulation.

Serious eye damage/eye irritation Causes eye irritation.

Product: Species : Rabbit Result : Irritation to eyes, reversing within 7 days

Components:

Fosetyl-aluminium: Result : Irreversible effects on the eye Remarks : Based on national or regional regulation.

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Species : Rabbit Result : Irreversible effects on the eye

Formic acid: Result : Irreversible effects on the eye Remarks : Based on skin corrosivity.

Respiratory or skin sensitisation Skin sensitisation Not classified based on available information.

Respiratory sensitisation Not classified based on available information.

Product: Exposure routes : Skin contact Species : Guinea pig Result : negative

Components:

Formic acid: Test Type : Buehler Test Exposure routes : Skin contact Species : Guinea pig Method : OECD Test Guideline 406 Result : negative

Chronic toxicity

Germ cell mutagenicity Not classified based on available information.

Components:

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative

Formic acid: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Genotoxicity in vivo : Test Type: Sex-linked recessive lethal test in Drosophila melanogaster (in vivo) Application Route: Ingestion Method: OECD Test Guideline 477 Result: negative

Carcinogenicity Not classified based on available information.

Components:

Fosetyl-aluminium: Species : Dog Application Route : Ingestion Exposure time : 2 Years Result : negative

Formic acid: Species : Rat Application Route : Ingestion Exposure time : 104 weeks Result : negative Remarks : Based on data from similar materials

Reproductive toxicity Not classified based on available information.

Components:

Fosetyl-aluminium: Effects on fertility : Test Type: Four-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Effects on fertility : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Effects on foetal development : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative

Formic acid: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Remarks: Based on data from similar materials Effects on foetal development : Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials

STOT - single exposure Not classified based on available information.

Components:

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Assessment : May cause respiratory irritation.

STOT - repeated exposure Not classified based on available information.

Components:

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Assessment : No significant health effects observed in animals at concentrations of 0.2 mg/l/6h/d or less.

Repeated dose toxicity

Components:

Fosetyl-aluminium: Species : Rat NOAEL : 500 mg/kg Application Route : Ingestion Exposure time : 13 Weeks Species : Rat NOAEL : 1,050 mg/kg Application Route : Skin contact Exposure time : 28 Days

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Species : Rat NOAEL : 100 mg/kg LOAEL : 300 mg/kg Application Route : Ingestion Exposure time : 36 - 52 Days Method : OECD Test Guideline 422 Species : Rat NOAEL : 0.004 mg/l LOAEL : 0.01 mg/l Application Route : inhalation (dust/mist/fume) Exposure time : 90 Days Method : OECD Test Guideline 413

Formic acid: Species : Rat NOAEL : 400 mg/kg Application Route : Ingestion Exposure time : 52 Weeks Remarks : Based on data from similar materials

Aspiration toxicity Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 500 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : ErC50 (Desmodesmus subspicatus (green algae)): 43.50 mg/l Exposure time: 72 h

Components:

Fosetyl-aluminium: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 122 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 29.6 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : ErC50 (Selenastrum capricornutum (green algae)): 2.715 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Oncorhynchus mykiss (rainbow trout)): >= 100 mg/l Exposure time: 28 d Method: OECD Test Guideline 215 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 17 mg/l Exposure time: 21 d

Ecotoxicology Assessment Chronic aquatic toxicity : No toxicity at the limit of solubility

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : ErC50 (Raphidocelis subcapitata (freshwater green alga)): > 200 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 NOEC (Raphidocelis subcapitata (freshwater green alga)): 12.5 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to microorganisms : NOEC (activated sludge): 0.16 mg/l Exposure time: 3 h Method: OECD Test Guideline 209

Formic acid: Toxicity to fish : LC50 (Danio rerio (zebra fish)): 130 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 365 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: Based on data from similar materials Toxicity to algae/aquatic plants : ErC50 (Pseudokirchneriella subcapitata (green algae)): 1,240 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials EC10 (Pseudokirchneriella subcapitata (green algae)): 295 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Toxicity to microorganisms : NOEC: 72 mg/l Exposure time: 13 d

Persistence and degradability

Components:

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Biodegradability : Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 29 d Method: OECD Test Guideline 301B

Formic acid: Biodegradability : Result: Readily biodegradable. Biodegradation: 100 % Exposure time: 28 d Method: OECD Test Guideline 301C

Bioaccumulative potential

Components:

Fosetyl-aluminium: Partition coefficient: n-octanol/water : log Pow: -2.11

2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Partition coefficient: n-octanol/water : log Pow: -0.27

Formic acid: Partition coefficient: n-octanol/water : log Pow: -2.1

Mobility in soil No data available

Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods Waste from residues : It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer.

Contaminated packaging : Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG UN number : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable

IATA-DGR UN/ID No. : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable Packing instruction (cargo aircraft) : Not applicable Packing instruction (passenger aircraft) : Not applicable

IMDG-Code UN number : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable EmS Code : Not applicable Marine pollutant : Not applicable

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations

ADG UN number : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable Hazchem Code : Not applicable

Special precautions for user Not applicable

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

Standard for the Uniform Scheduling of Medicines and Poisons : Schedule 6

Standard for the Uniform Scheduling of Medicines and Poisons : Schedule 5

Prohibition/Licensing Requirements : There is no applicable prohibition, authorisation and restricted use requirements, including for carcinogens referred to in Schedule 10 of the model WHS Act and Regulations.

Active substance : 60 % Fosetyl-aluminium

SECTION 16: ANY OTHER RELEVANT INFORMATION

Further information Revision Date : 09.11.2023

Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency,

Date format : dd.mm.yyyy

Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) AU OEL : Australia. Workplace Exposure Standards for Airborne Contaminants.

ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit AU OEL / TWA : Exposure standard - time weighted average AU OEL / STEL : Exposure standard - short term exposure limit

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA

• International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.

AU / EN