SDS - Proforce Clean Sweep Trio Fungicide - 220414

Page 1/7 Safety Data Sheet according to WHS Regulations Printing date 14.04.2022 Revision: 14.04.2022

1 Identification Product Name: ProForce Clean Sweep Trio Fungicide Other Means of Identification: Mixture APVMA Approval Number: 90578 Recommended Use of the Chemical and Restriction on Use: Agricultural fungicide Not subject to the ADG Code when transported in Australia by Road or Rail in packagings that do not incorporate a receptacle exceeding 500 kg(L); or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply.

[Image of Health hazard symbol] Germ Cell Mutagenicity 2 H341 Suspected of causing genetic defects.

[Image of Environment symbol] Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.

[Image of Exclamation mark symbol] Acute Toxicity (Inhalation) 4 H332 Harmful if inhaled. Skin Sensitisation 1 H317 May cause an allergic skin reaction. Aquatic Acute 2 H401 Toxic to aquatic life.

Signal Word Warning Hazard Statements H332 Harmful if inhaled. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. (Contd. on page 2)

Page 2/7 Safety Data Sheet according to WHS Regulations Printing date 14.04.2022 Revision: 14.04.2022 Product Name: ProForce Clean Sweep Trio Fungicide (Contd. of page 1)

P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a POISON CENTER/doctor if you feel unwell. P321 Specific treatment (see on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national regulations.

3 Composition and Information on Ingredients Chemical Characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions.

4 First Aid Measures Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention if breathing problems develop. Skin Contact: In case of skin contact, immediately remove contaminated clothing and wash affected areas with water and soap. Seek medical attention if symptoms occur. Eye Contact: In case of eye contact, rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Seek medical attention. Ingestion: If swallowed, do not induce vomiting. Immediately rinse mouth with water. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Symptoms Caused by Exposure: Inhalation: Harmful if inhaled. May cause respiratory irritation. Skin Contact: May cause skin irritation. May cause an allergic skin reaction. Eye Contact: Causes eye irritation. Ingestion: May cause gastrointestinal irritation, nausea, diarrhoea and vomiting. (Contd. on page 3)

Page 3/7 Safety Data Sheet according to WHS Regulations Printing date 14.04.2022 Revision: 14.04.2022 Product Name: ProForce Clean Sweep Trio Fungicide (Contd. of page 2)

5 Fire Fighting Measures Suitable Extinguishing Media: Use fire extinguishing methods suitable to surrounding conditions. Specific Hazards Arising from the Chemical: Hazardous combustion products include oxides of carbon and toxic smoke. Product is not flammable. Containers close to fire should be removed only if safe to do so. Use water spray to cool fire exposed containers. Prevent run-off from fire fighting entering drains or water courses. HAZCHEM Code: •3Z Special Protective Equipment and Precautions for Fire Fighters: When fighting a major fire wear self-contained breathing apparatus and protective equipment.

6 Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures: Wear approved respiratory protection, chemical resistant gloves, protective clothing and safety boots. Evacuate all non-essential personnel from affected area. Do not breathe vapours. Ensure adequate ventilation. Environmental Precautions: In the event of a major spill, prevent spillage from entering drains or water courses. Methods and Materials for Containment and Cleaning Up: Stop leak if safe to do so and absorb spill with sand, earth, vermiculite or some other absorbent material. Collect the spilled material and place into a suitable container for disposal.

7 Handling and Storage Precautions for Safe Handling: Use of safe work practices are recommended to avoid eye or skin contact and inhalation of vapours or mist. Use only outdoors or in a well-ventilated area. When opening the container and preparing the spray wear cotton overalls buttoned to neck and wrist (or equivalent clothing), elbow-length chemical resistant gloves and faceshield. If applying by low (manual) pressure hand wand wear cotton overalls buttoned to neck and wrist (or equivalent clothing) and elbow-length chemical resistant gloves. ProForce Clean Sweep Trio contains fluazinam, which may cause asthma and/or respiratory sensitisation. Sensitive individuals should avoid contact with this substance. Food, beverages and tobacco products should not be stored or consumed where this material is in use. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use. Provide eyewash fountains and safety showers in close proximity to points of potential exposure. Conditions for Safe Storage: Store in a cool, dry and well ventilated area. Keep container tightly closed when not in use. Protect from heat, sparks, open flames and other sources of ignition. Keep away from strong oxidising agents.

8 Exposure Controls and Personal Protection Exposure Standards: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Engineering Controls: Ensure adequate ventilation of the working area. Respiratory Protection: Use an approved vapour respirator under conditions where exposure to the substance is apparent (e.g. generation of high concentrations of mist or vapour, inadequate ventilation, development of respiratory tract irritation) and engineering controls are not feasible. See Australian Standards AS/NZS 1715 and 1716 for more information. (Contd. on page 4)

Page 4/7 Safety Data Sheet according to WHS Regulations Printing date 14.04.2022 Revision: 14.04.2022 Product Name: ProForce Clean Sweep Trio Fungicide (Contd. of page 3)

Skin Protection: Elbow-length chemical resistant gloves. See Australian/New Zealand Standard AS/NZS 2161 for more information. When selecting gloves for use against certain chemicals, the degradation resistance, permeation rate and permeation breakthrough time should be considered. Occupational protective clothing, including cotton overalls buttoned to neck and wrist (depending on conditions in which it has to be used, in particular as regards the period for which it is worn, which shall be determined on the basis of the seriousness of the risk, the frequency of exposure to the risk, the characteristics of the workstation of each worker and the performance of the protective clothing). See Australian/New Zealand Standard AS/NZS 4501 for more information. Eye and Face Protection: Eye and face protectors for protection against splashing materials or liquids. See Australian/New Zealand Standard AS/NZS 1337 for more information.

9 Physical and Chemical Properties Appearance: Form: Suspension Colour: Beige to brown Odour: No information available Odour Threshold: No information available pH-Value: 4.5 - 6.0 (undiluted) Melting point/freezing point: No information available Initial Boiling Point/Boiling Range: No information available Flash Point: >93 °C Flammability: Product is not flammable Auto-ignition Temperature: No information available Decomposition Temperature: No information available Explosion Limits: Lower: No information available Upper: No information available Vapour Pressure: No information available Relative Density: 1.1 Vapour Density: No information available Evaporation Rate: No information available Solubility in Water: Dispersible Partition Coefficient (n-octanol/water): No information available

10 Stability and Reactivity Possibility of Hazardous Reactions: No dangerous reactions known under conditions of normal use. Chemical Stability: Stable at ambient temperature and under normal conditions of storage and use. Conditions to Avoid: Heat, sparks, open flames and other sources of ignition. Incompatible Materials: Strong oxidising agents. Hazardous Decomposition Products: Oxides of carbon and toxic smoke. (Contd. on page 5)

Page 5/7 Safety Data Sheet according to WHS Regulations Printing date 14.04.2022 Revision: 14.04.2022 Product Name: ProForce Clean Sweep Trio Fungicide (Contd. of page 4)

11 Toxicological Information Toxicity: LD50/LC50 Values: CAS: 23564-05-8 Thiophanate-methyl Oral LD50 >5,000 mg/kg (rat) Dermal LD50 >2,000 mg/kg (rat) Inhalation LC50/4 h 1.7 mg/l (rat) CAS: 79622-59-6 Fluazinam Oral LD50 >4,100 mg/kg (rat) Dermal LD50 >2,000 mg/kg (rat) Inhalation LC50/4 h >1.1 mg/l (rat) CAS: 107534-96-3 Tebuconazole Oral LD50 1,700 mg/kg (rat) Dermal LD50 >2,000 mg/kg (rat) Inhalation LC50/4 h >5.09 mg/l (rat)

Acute Health Effects Inhalation: Harmful if inhaled. May cause respiratory irritation. Skin: May cause skin irritation. May cause an allergic skin reaction. Eye: Causes eye irritation. Ingestion: May cause gastrointestinal irritation, nausea, diarrhoea and vomiting. Skin Corrosion / Irritation: Based on classification principles, the classification criteria are not met. Serious Eye Damage / Irritation: Based on classification principles, the classification criteria are not met. Respiratory or Skin Sensitisation: May cause an allergic skin reaction. Germ Cell Mutagenicity: Suspected of causing genetic defects. Carcinogenicity: This product does NOT contain any IARC listed chemicals. Reproductive Toxicity: Based on classification principles, the classification criteria are not met. Specific Target Organ Toxicity (STOT) - Single Exposure: Based on classification principles, the classification criteria are not met. Specific Target Organ Toxicity (STOT) - Repeated Exposure: Based on classification principles, the classification criteria are not met. Aspiration Hazard: Based on classification principles, the classification criteria are not met. Chronic Health Effects: No data associated with long term health effects. Existing Conditions Aggravated by Exposure: Pre-exisiting allergies, eye, skin and respiratory disorders. Additional toxicological information: The Australian Acceptable Daily Intake (ADI) for thiophanate-methyl for a human is 0.08 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the NOAEL of 8 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. The Australian Acceptable Daily Intake (ADI) for fluazinam for a human is 0.004 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the NOAEL of 0.4 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. The Australian Acceptable Daily Intake (ADI) for tebuconazole for a human is 0.03 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the NOAEL of 2.96 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. (Contd. on page 6)

Page 6/7 Safety Data Sheet according to WHS Regulations Printing date 14.04.2022 Revision: 14.04.2022 Product Name: ProForce Clean Sweep Trio Fungicide (Contd. of page 5) (Ref: Australian Pesticides and Veterinary Medicines Authority, 'Acceptable Daily Intakes for Agricultural and Veterinary Chemicals', 2022).

12 Ecological Information Ecotoxicity: Aquatic toxicity: Toxic to aquatic life with long lasting effects. CAS: 107534-96-3 Tebuconazole EC50/72 h 4.01 mg/l (green algae) LC50/96 h 8.7 mg/l (golden orfe) 6.4 mg/l (rainbow trout) LC50/48 h 4.2 mg/l (daphnia) Persistence and Degradability: No data available on finished product. Bioaccumulative Potential: No data available on finished product. Mobility in Soil: No data available on finished product. Other adverse effects: No further relevant information available.

13 Disposal Considerations Disposal Methods and Containers: Dispose according to applicable local and state government regulations. Special Precautions for Landfill or Incineration: Please consult your state Land Waste Management Authority for more information.

14 Transport Information UN Number ADG, IMDG, IATA UN3082 Proper Shipping Name ADG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Thiophanate-methyl) IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Thiophanate-methyl, Fluazinam), MARINE POLLUTANT Dangerous Goods Class ADG Class: 9 Packing Group: ADG, IMDG, IATA III Marine pollutant: Symbol (fish and tree) EMS Number: F-A,S-F Hazchem Code: •3Z Special Provisions: 274, 331, 335, 375, AU01 Transport/Additional information: Not subject to the ADG Code when transported by road or rail in packagings that do not incorporate a receptacle exceeding 500 kg(L) or IBCs. (refer to SP AU01) Excepted quantities (EQ): E1 (Contd. on page 7)

Page 7/7 Safety Data Sheet according to WHS Regulations Printing date 14.04.2022 Revision: 14.04.2022 Product Name: ProForce Clean Sweep Trio Fungicide (Contd. of page 6)

Limited Quantities: 5L Packagings & IBCs - Packing Instruction: P001, IBC03, LP01 Packagings & IBCs - Special Packing Provisions: PP1 Portable Tanks & Bulk Containers - Instructions: T4 Portable Tanks & Bulk Containers - Special Provisions: TP1, TP29

15 Regulatory Information Australian Inventory of Industrial Chemicals: None of the ingredients are listed. Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Poison Schedule: Poisons Schedule: 6 Australian Pesticides and Veterinary Medicines Authority: This product is registered with the Australian Pesticides and Veterinary Medicines Authority. APVMA number 90578.

16 Other Information Date of Preparation or Last Revision: 14.04.2022 Prepared by: Pty Ltd Abbreviations and acronyms: ADG: Australian Dangerous Goods IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent IARC: International Agency for Research on Cancer STEL: Short Term Exposure Limit TWA: Time Weighted Average NES: National Exposure Standard (Safe Work Australia - Workplace Exposure Standards For Airborne Contaminants) Acute Toxicity (Inhalation) 4: Acute toxicity – Category 4 Serious Eye Damage/Irritation 1: Serious eye damage/eye irritation – Category 1 Skin Sensitisation 1: Skin sensitisation, Hazard Category 1 Skin Sensitisation 1A: Skin sensitisation, Hazard Category 1A Germ Cell Mutagenicity 2: Germ cell mutagenicity – Category 2 Toxic To Reproduction 2: Reproductive toxicity – Category 2 Aquatic Acute 1: Hazardous to the aquatic environment, short-term (Acute). Category 1 Aquatic Acute 2: Hazardous to the aquatic environment, short-term (Acute). Category 2 Aquatic Chronic 1: Hazardous to the aquatic environment, long-term (Chronic). Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment, long-term (Chronic). Category 2

Disclaimer This SDS is prepared in accord with the Safe Work Australia document “Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals - July 2020” The information contained in this safety data sheet is provided in good faith and is believed to be accurate at the date of issuance. Indigo Specialty Products Pty Ltd makes no representation of the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or damage related to the supply or use of the information in this material safety data sheet. Pty Ltd is not in a position to warrant the accuracy of the data herein. The user is cautioned to make their own determinations as to the suitability of the information provided to the particular circumstances in which the product is used.