SDS - ICL Banrot 80G Fungicide - 220824
Applies to Banrot 80G Fungicide
Document contents
Text extracted from the source document for accessibility and reference. Always consult the original safety data sheet above for the authoritative version.
According to EC Regulation 1907/2006 (Reach), Regulation EU No. 2015/830
Safety Data Sheet
Last Revision Date 24-Aug-2022 Version: 2
Section 1: Identification: Product Identifier and Chemical Identity
Product identifier Product Name: Banrot 80G Product ID: E95025
Other means of identification Proper shipping name: Environmentally Hazardous Substance Solid N.O.S.Thiophanate-Methyl UN number or ID number: 3077 Safety data sheet number: P70310
Recommended use of the chemical and restrictions on use Recommended Use: Fungicide.
Section 2: Hazard(s) Identification
GHS Classification Mixture
| Skin Sensitization | Category 1 |
| Germ Cell Mutagenicity | Category 2 |
| Carcinogenicity | Category 2 |
Label elements [Diagram: Exclamation mark, Health hazard, and Environment pictograms]
Signal word Danger
Hazard statements H317 - May cause an allergic skin reaction H341 - Suspected of causing genetic defects H351 - Suspected of causing cancer H410 - Very toxic to aquatic life with long lasting effects H423 - Harmful to the soil environment
Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing Avoid release to the environment Do not handle until all safety precautions have been read and understood
Precautionary Statements - Storage Store locked up
Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
Other hazards which do not result in classification No hazards to be especially mentioned
Section 3: Composition and Information on Ingredients in Accordance with Schedule 8
Substance Not applicable
Mixture
| Chemical name | CAS No | EC No (EU Index No) | Weight-% | Classification according to Regulation (EC) No. 1272/2008 [CLP] | REACH registration number |
|---|---|---|---|---|---|
| Thiophanate-methyl (US) | 23564-05-8 | 245-740-7 | 5 - 10% | Acute Tox. 4 (H332) Skin Sens. 1 (H317) Muta. 2 (H341) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) | 01-2120860136-57 |
| Etridiazole (US) | 2593-15-9 | 219-991-8 | 1 - 5% | Acute Tox. 4 (H302) Skin Sens. 1 (H317) Carc. 2 (H351) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) | Exempt |
| Chemical name | CAS No | Weight-% |
|---|---|---|
| Non-hazardous Ingredients | Proprietary | 92% of the other ingredients are determined not be hazardous. |
Section 4: First Aid Measures
Description of first aid measures General advice: First aid measures should be executed by trained personnel only. Inhalation: Remove to fresh air. In the case of inhalation of aerosol/mist consult a physician if necessary. Possible symptoms are coughing and/or dyspnoea. If breathing is difficult, give oxygen. Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact: Get medical attention if irritation develops and persists. Wash skin with soap and water. Ingestion: Clean mouth with water and drink afterwards plenty of water. Possible symptoms are nausea and/or vomiting. If a person vomits when lying on his back, place him in the recovery position. Do not induce vomiting without medical advice. Consult a physician if necessary.
Most important symptoms and effects, both acute and delayed Symptoms: no data available.
Indication of any immediate medical attention and special treatment needed Note to physicians: Treat symptomatically.
Section 5: Firefighting Measures
Suitable Extinguishing Media Suitable Extinguishing Media: CO2, dry chemical, dry sand, alcohol-resistant foam. Unsuitable extinguishing media: Do not scatter spilled material with high pressure water streams. Dry chemical. Foam. Hazardous Combustion Products: Combustion can produce toxic fumes and irritating gases.
Special protective actions for fire-fighters Special protective equipment for fire-fighters: Coordinate fire extinguishing measures to fire in surrounding area.
Section 6: Accidental Release Measures
Personal precautions, protective equipment and emergency procedures Personal precautions: Avoid generation of dust. Ensure adequate ventilation. For emergency responders: Use personal protection recommended in Section 8.
Environmental precautions Environmental precautions: Do not flush into surface water or sanitary sewer system. Prevent product from entering drains. See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for containment: Prevent further leakage or spillage if safe to do so. Methods for cleaning up: Pick up and transfer to properly labeled containers.
Section 7: Handling and Storage, Including How the Chemical May Be Safely Used
Precautions for safe handling Advice on safe handling: Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice. Use personal protection equipment.
Conditions for safe storage, including any incompatibilities Storage Conditions: Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep container closed when not in use. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in a dry, cool and well-ventilated place. Protect from sunlight. Incompatible materials: None known based on information supplied.
Section 8: Exposure Controls and Personal Protection
Control parameters
Appropriate engineering controls Engineering Controls: Showers, Eyewash stations, Ventilation systems
Individual protection measures, such as personal protective equipment Eye/face Protection: Wear safety glasses with side shields (or goggles). Skin and body protection: Lightweight protective clothing. Hand Protection: Nitrile rubber. Break though time >8h. Environmental exposure controls: no data available.
Section 9: Physical and Chemical Properties
Information on basic physical and chemical properties Physical state: Solid Appearance: Granules Color: grey Odor: No information available.
pH: No data available Melting Point/Freezing Point: No data available Boiling Point/Range: No data available Flash Point: No data available Evaporation Rate: no data available Flammability (solid, gas): Non-flammable Vapor Pressure: No data available Vapour density: No data available Water Solubility: no data available Partition Coefficient: no data available Autoignition Temperature: No data available Hyphen: no data available Kinematic Viscosity: No data available Dynamic Viscosity: no data available
Other information Softening Point: no data available Molecular Weight: no data available VOC content: No data available Particle Size: No data available Particle Size Distribution: No data available
Section 10: Stability and Reactivity
Reactivity: Not reactive. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: None under normal processing. Hazardous Decomposition Products: Contact with acids liberates very toxic gas. Metal oxides possible. Oxides of sulfur. None under normal processing. Conditions to Avoid: For quality reasons: Keep out of reach of direct sunlight, store under dry conditions, partly used bags should be closed well. Incompatible materials: None known based on information supplied. Hazardous decomposition products: None known based on information supplied.
Section 11: Toxicological Information
Acute toxicity Information on likely routes of exposure Inhalation: May cause irritation of respiratory tract. Eye contact: May cause redness, itching, and pain. Skin Contact: May cause irritation. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea
Numerical measures of toxicity - Product Information ATEmix (oral): 12,322.70 mg/kg ATEmix (dermal): 15,943.30 mg/kg ATEmix (inhalation-dust/mist): 8.936 mg/l Unknown acute toxicity: 0 % of the mixture consists of ingredient(s) of unknown toxicity LD50/oral: > 5.0 (rat) g/kg LD50/dermal: > 5.0 g/kg (rabbit) LC50/inhalation: no data available
Component Information
| Chemical name | Oral LD50 | Dermal LD50 | Inhalation LC50 |
|---|---|---|---|
| Thiophanate-methyl (US) | = 6640 mg/kg ( Rat ) | > 2000 mg/kg ( Rabbit ) | = 1700 mg/m3 ( Rat ) 4 h |
| Etridiazole (US) | = 1077 mg/kg ( Rat ) | > 5000 mg/kg ( Rabbit ) | > 5.7 mg/L ( Rat ) 4 h |
Delayed and Immediate Effects as well as Chronic Effects from Short and Long-Term Exposure: skin corrosion/irritation: Classification based on individual ingredients of the mixture. Serious eye damage/eye irritation: Classification based on individual ingredients of the mixture. Respiratory or skin sensitization: Classification based on individual ingredients of the mixture. Germ Cell Mutagenicity: Classification based on individual ingredients of the mixture. Carcinogenicity: Classification based on individual ingredients of the mixture. Reproductive Toxicity: Classification based on individual ingredients of the mixture. STOT - Single Exposure: Classification based on individual ingredients of the mixture. STOT - Repeated Exposure: Classification based on individual ingredients of the mixture. Aspiration Hazard: Classification based on individual ingredients of the mixture.
Section 12: Ecological Information
Ecotoxicity Ecotoxicity: Do not allow product to enter the environment uncontrolled. Unknown aquatic toxicity: 0 % of the mixture consists of component(s) of unknown hazards to the aquatic environment.
| Chemical name | Algae/aquatic plants | Fish | Toxicity to microorganisms | Crustacea |
|---|---|---|---|---|
| Etridiazole (US) | - | LC50: 0.63 - 0.95mg/L (96h, Oncorhynchus mykiss) | - | - |
Persistence and degradability: no data available. Bioaccumulative potential: No information available. Mobility: no data available.
Other adverse effects: No information available.
| Chemical name | EU - Endocrine Disrupters Candidate List | EU - Endocrine Disrupters - Evaluated Substances |
|---|---|---|
| Etridiazole (US) | Group III Chemical | - |
Section 13: Disposal Considerations
Waste Treatment Methods: Waste from residues/unused products: Dispose of waste in accordance with environmental legislation. Dispose of in accordance with local regulations. Contaminated packaging: Do not reuse empty containers.
Section 14: Transport Information
ADG UN Number: 3077 Proper shipping name: Environmentally Hazardous Substance Solid N.O.S.Thiophanate-Methyl Hazard Class: 9 Packing Group: III Environmental Hazard: Yes Special Provisions: 274, 335, 375, 601
IATA UN number or ID number: 3077 Proper shipping name: Environmentally Hazardous Substance Solid N.O.S.Thiophanate-Methyl Transport hazard class(es): 9 Packing group: III
IMDG UN number or ID number: 3077 Proper shipping name: Environmentally Hazardous Substance Solid N.O.S.Thiophanate-Methyl Transport hazard class(es): 9 Packing group: III EmS: F-A, S-F Special Provisions: 274, 335, 966, 967, 969 Marine Pollutant: This material meets the definition of a marine pollutant
Bulk transport according Annex II of MARPOL and IBC Code: no data available
Section 15: Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations New Zealand: Hazardous Substances Regulations: Not regulated Australia: See section 8 for national exposure control parameters
International Inventories: TSCA: This product complies with USINV ENCS: This product complies with encs: Australian Inventory of Chemical Substances: This product does not comply with AICS
Legend: TSCA: United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS: European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances AICS: Australian Inventory of Chemical Substances
International Regulations The Montreal Protocol on Substances that Deplete the Ozone Layer: Not applied The Stockholm Convention on Persistent Organic Pollutants: Not applicable The Rotterdam Convention: Not applicable
Section 16: Any Other Relevant Information
Prepared by: Regulatory Affairs Department () Last Revision Date: 24-Aug-2022 Revision Note: Not applied
Key or legend to abbreviations and acronyms used in the safety data sheet ADG: Australian Dangerous Goods code RID: Regulations Concerning the International Transport of Dangerous Goods by Rail ICAO: International Civil Aviation Organization ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labeling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) PNEC: Predicted No Effect Concentration DNEL: Derived No-Effect Level REACh: Registration, Evaluation, Authorization of Chemicals CLP: EU-GHS; Classification, Labelling and Packaging OEL: Occupational Exposure Limit TWA: Time Weighted Average ATE: Acute Toxicity Estimate EUH phrase: CLP (EU) specific hazard statement LD50: Lethal dose, 50%. LC50: Lethal concentration, 50%. SVHC: Substance of Very High Concern.
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION TWA: TWA (time-weighted average) STEL: STEL (Short Term Exposure Limit) Ceiling: Maximum limit value *: Skin designation
Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
End of Safety Data Sheet