SDS - Verde K Mag Plus Granular - 240701
Applies to Verde K Mag Plus
Document contents
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Safety Data Sheet
Verde K Mag Plus
Section 1. Identification
GHS product identifier : Verde K Mag Plus Other means of identification : AAVKMP85.2268 Product use : Professional use. Supplier's details : Fernland Agencies Pty Ltd. AUSTRALIA e-mail address of person responsible for this SDS : Emergency telephone number (with hours of operation) : (M-F 7:30-4:30 AEST)
Section 2. Hazards Identification
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture : EYE IRRITATION - Category 2A SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 4%
GHS label elements Hazard pictograms : [Exclamation mark pictogram] Signal word : Warning Hazard statements : H319 Causes serious eye irritation. H335 May cause respiratory irritation.
Precautionary statements Prevention : P261 Avoid breathing dust. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/ face protection. Response : P304 + P340 IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P337 + P313 If eye irritation persists: Get medical advice/attention. Storage : Not applicable. Disposal : Not applicable. Hazards not otherwise classified : None known.
Section 3. Composition/information on Ingredients
Substance/mixture : Mixture Other means of identification : VKMP
CAS number/other identifiers CAS number : Not applicable. Product code : Not available.
| Ingredient name | % | CAS number |
|---|---|---|
| Sulfuric acid, calcium salt, hydrate (1:1:2) | ≥25 - <50 | 10101-41-4 |
| iron (II) sulfate (1:1) heptahydrate | ≥10 - <18 | 7782-63-0 |
| Lignosulfonic acid, calcium | ≥1 - <2.7 | 8061-52-7 |
| Sulfuric acid, manganese(2+) salt, hydrate (1:1:4) | ≥1 - <2 | 10101-68-5 |
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First Aid Measures
Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Give plenty of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : May cause respiratory irritation. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing Skin contact : No specific data. Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first aiders : No action shall be taken involving any personal risk or without suitable training.
Section 5. Fire-fighting Measures
Extinguishing media Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media : None.
Special protective actions for fire-fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA).
Section 6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Absorb spillage to prevent material damage. Avoid dust generation. Vacuum dust with equipment fitted with a HEPA filter. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill : Move containers from spill area. Absorb spillage to prevent material damage. Prevent entry into sewers and water courses. Avoid dust generation. Vacuum dust with equipment fitted with a HEPA filter. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Section 7. Handling and Storage
Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Section 8. Exposure Controls/personal Protection
Control parameters Occupational exposure limits
- Sulfuric acid, calcium salt, hydrate (1:1:2):
- ACGIH TLV (United States, 3/2015). TWA: 10 mg/m³ 8 hours.
- OSHA PEL 1989 (United States, 3/1989). TWA: 15 mg/m³
- NIOSH REL (United States, 10/2013). TWA: 10 mg/m³
- OSHA PEL (United States, 2/2013). TWA: 15 mg/m³
- Sulfuric acid, manganese(2+) salt, hydrate (1:1:4):
- ACGIH TLV (United States, 3/2015). TWA: 1 mg/m³ 8 hours.
- OSHA PEL 1989 (United States, 3/1989). TWA: 1 mg/m³
- NIOSH REL (United States, 10/2013). TWA: 1 mg/m³
- OSHA PEL (United States, 2/2013). TWA: 1 mg/m³
- iron (II) sulfate (1:1) heptahydrate: None.
- Lignosulfonic acid, calcium: None.
- glycollic acid: None.
- glycollic acid: None.
Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and Chemical Properties
Appearance Physical state : Solid. [Granular solid.] Color : Tan. Grey. Odor : Mild. Odor threshold : Not available. pH : 6 to 8 Melting point : Not available. Boiling point : Not available. Flash point : Not available. Evaporation rate : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Vapor pressure : Not available. Vapor density : Not available. Relative density : 1.153 g/cm³ [25°C] (72.0 lb/ft³ [ 75°F]) Solubility : Soluble in the following materials: cold water and hot water. Partition coefficient: n-octanol/water : Not available. Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available.
Section 10. Stability and Reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Section 11. Toxicological Information
Information on toxicological effects Acute toxicity
| Product/ingredient name | Result | Species | Score | Exposure |
|---|---|---|---|---|
| Sulfuric acid, manganese (2+) salt, hydrate (1:1:4) | LD50 Oral | Rat - Male, Female | 2150 mg/kg | - |
Conclusion/Summary : Based on available data, the classification criteria are not met.
Irritation/Corrosion
| Product/ingredient name | Result | Species | Score | Exposure | Observation |
|---|---|---|---|---|---|
| Sulfuric acid, manganese (2+) salt, hydrate (1:1:4) | Skin - Non-irritating to the skin. [OECD 404] | Rabbit | 0 | - | - |
| Eyes - Cornea opacity [OECD 405] | Rabbit | - | 72 hours | - |
Conclusion/Summary Skin : Based on available data, the classification criteria are not met. Eyes : Causes serious eye irritation.
Sensitization : Not available. Mutagenicity : Not available. Carcinogenicity : Not available. Reproductive toxicity : Not available. Teratogenicity : Not available. Specific target organ toxicity (single exposure) : Not available. Specific target organ toxicity (repeated exposure)
| Product/ingredient name | Category | Route of | Target organs |
|---|---|---|---|
| Sulfuric acid, manganese(2+) salt, hydrate (1:1:4) | Category 2 | Not determined | Not determined |
Aspiration hazard : Not available. Information on the likely routes of exposure : Not available.
Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : May cause respiratory irritation. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain or irritation, watering, redness Inhalation : Adverse symptoms may include the following: respiratory tract irritation, coughing Skin contact : No specific data. Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : Not available. Potential delayed effects : Not available. Long term exposure Potential immediate effects : Not available. Potential delayed effects : Not available.
Potential chronic health effects : Not available. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity estimates : Not available.
Section 12. Ecological Information
Toxicity
| Product/ingredient name | Result | Species | Exposure |
|---|---|---|---|
| Sulfuric acid, manganese (2+) salt, hydrate (1:1:4) | Acute LC50 49.9 mg/l Fresh water | Fish | 96 hours |
Conclusion/Summary : Based on available data, the classification criteria are not met.
Persistence and degradability Conclusion/Summary : There are no data available on the mixture itself.
Bioaccumulative potential : Not available. Mobility in soil Soil/water partition coefficient (KOC) : Not available. Other adverse effects : No known significant effects or critical hazards.
Section 13. Disposal Considerations
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Section 14. Transport Information
| DOT Classification | TDG Classification | Mexico Classification | ADR/RID | IMDG | IATA | |
|---|---|---|---|---|---|---|
| UN number | Not regulated. | Not regulated. | Not regulated. | Not regulated. | Not regulated. | Not regulated. |
| UN proper shipping name | - | - | - | - | - | - |
| Transport hazard class(es) | - | - | - | - | - | - |
| Label | ||||||
| Packing group | - | - | - | - | - | - |
| Environmental hazards | No. | No. | No. | No. | Marine Pollutant: No | No. |
| Additional information | - | - | - | - | - | - |
Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according to Annex II of MARPOL and the IBC Code : Not available.
Section 15. Regulatory Information
U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted.
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Not listed Clean Air Act Section 602 Class I Substances : Not listed Clean Air Act Section 602 Class II Substances : Not listed DEA List I Chemicals (Precursor Chemicals) : Not listed DEA List II Chemicals (Essential Chemicals) : Not listed
SARA 302/304 Composition/information on ingredients : No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Not applicable
State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : None of the components are listed. Pennsylvania : None of the components are listed.
International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals : Not listed. Montreal Protocol (Annexes A, B, C, E) : Not listed. Stockholm Convention on Persistent Organic Pollutants : Not listed. Rotterdam Convention on Prior Inform Consent (PIC) : Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals : Not listed.
International lists National inventory Australia : All components are listed or exempted. Canada : All components are listed or exempted. China : All components are listed or exempted. Europe : At least one component is not listed. Japan : Japan inventory (ENCS): All components are listed or exempted. Japan inventory (ISHL): Not determined. Malaysia : Not determined. New Zealand : All components are listed or exempted. Philippines : All components are listed or exempted. Republic of Korea : All components are listed or exempted. Taiwan : All components are listed or exempted. Turkey : Not determined.
Section 16. Other Information
Procedure used to derive the classification
| Classification | Justification |
|---|---|
| EYE IRRITATION - Category 2A | Calculation method |
| SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 | Expert judgment |
History Date of printing : 02/08/2024 Date of issue/Date of revision : 01/07/2024 Date of previous issue : 15/06/2019 Version : 1.1
Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.