SDS - Yates Success Ultra Insect Control - 230904

Safety Data Sheet

NON-Hazardous, Dangerous Goods

1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION

Product name: YATES SUCCESS ULTRA INSECT CONTROL

Recommended use: Controls caterpillars and other insect pests such as thrips, codling moth, pear & cherry slugs and citrus leaf miner on vegetables, herbs, fruit and ornamentals.

Supplier: Yates, a division of DuluxGroup (Australia) Pty Ltd ABN: 67 000 049 427 Street Address: 1956 Dandenong Road Australia Emergency Telephone number: Australia – ; New Zealand – 0800 220 770

2. HAZARDS IDENTIFICATION

Based on available information, this material is not classified as hazardous according to criteria of Safe Work Australia GHS 7.

Poison Schedule: S5. Caution

DANGEROUS GOOD CLASSIFICATION Classified as Dangerous Goods by the criteria of the "Australian Code for the Transport of Dangerous Goods by Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".

Dangerous Goods Class: 9

Australian Special Provisions; AU01: Environmentally Hazardous Substances meeting the description of UN 3077 or UN 3082 are not subject to this Code (ADG 07) when transported by road or rail in; (a) packagings that do not incorporate a receptacle exceeding 500 Kg (L); or (b) IBCs.

3. COMPOSITION INFORMATION

4. FIRST AID MEASURES

If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand 0800 764 766).

Inhalation: Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. Seek medical advice if effects persist.

Skin Contact: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. If swelling, redness, blistering or irritation occurs seek medical assistance.

Eye contact: If in eyes wash out immediately with water. In all cases of eye contamination it is a sensible precaution to seek medical advice.

Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to drink. Never give anything by the mouth to an unconscious patient. If vomiting occurs give further water. Seek medical advice.

PPE for First Aiders: Wear safety shoes, overalls, gloves, safety glasses. Available information suggests that gloves made from nitrile rubber should be suitable for intermittent contact. However, due to variations in glove construction and local conditions, the user should make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storing or re-using.

Notes to physician: Treat symptomatically.

5. FIRE FIGHTING MEASURES

Hazchem Code: •3Z

Suitable extinguishing media: If material is involved in a fire use alcohol resistant foam or dry agent (carbon dioxide, dry chemical powder).

Specific hazards: Non-combustible material.

Fire fighting further advice: Not combustible, however following evaporation of aqueous component residual material can burn if ignited.

6. ACCIDENTAL RELEASE MEASURES

SMALL SPILLS Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours or dust. Wipe up with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal.

LARGE SPILLS Clear area of all unprotected personnel. Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination and the inhalation of vapours. Work up wind or increase ventilation. Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly labelled containers or drums for disposal. If contamination of crops, sewers or waterways has occurred advise local emergency services.

Dangerous Goods - Initial Emergency Response Guide No: 47

7. HANDLING AND STORAGE

Handling: Avoid eye contact and repeated or prolonged skin contact. Avoid inhalation of vapour, mist or aerosols.

Storage: Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from foodstuffs. Store away from incompatible materials described in Section 10. Store away from sources of heat and/or ignition. Keep container standing upright. Keep containers closed when not in use - check regularly for leaks.

This material is classified as a Class 9 Miscellaneous Dangerous Good as per the criteria of the "Australian Code for the Transport of Dangerous Goods by Road & Rail" and/or the "New Zealand NZS5433: Transport of Dangerous Goods on Land" and must be stored in accordance with the relevant regulations.

This material is a Scheduled Poison Schedule 5 (Caution) and must be stored, maintained and used in accordance with the relevant regulations.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

National occupational exposure limits: No value assigned for this specific material by Safe Work Australia.

Biological Limit Values: As per the "National Model Regulations for the Control of Workplace Hazardous Substances (Safe Work Australia)" the ingredients in this material do not have a Biological Limit Allocated.

Engineering Measures: Natural ventilation should be adequate under normal use conditions.

Personal Protection Equipment: SAFETY SHOES, OVERALLS, GLOVES, SAFETY GLASSES.

Wear safety shoes, overalls, gloves, safety glasses. Available information suggests that gloves made from nitrile rubber should be suitable for intermittent contact. However, due to variations in glove construction and local conditions, the user should make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storing or re-using.

RECOMMENDATIONS FOR CONSUMER USE: Wash hands after use.

Hygiene measures: Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or smoke. Wash hands prior to eating, drinking or smoking. Avoid contact with clothing. Avoid eye contact and repeated or prolonged skin contact. Avoid inhalation of vapour, mist or aerosols. Ensure that eyewash stations and safety showers are close to the workstation location.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Liquid Colour: White Odour: Mild characteristic

Solubility: Soluble in water Specific Gravity: 1.03 Relative Vapour Density (air=1): >1 Vapour Pressure: N Av Flash Point (°C): >100 (PMCC) Flammability Limits (%): N App Autoignition Temperature (°C): N Av Melting Point/Range (°C): N Av Boiling Point/Range (°C): N Av pH: N Av Viscosity: N Av Total VOC (g/Litre): N Av

(Typical values only - consult specification sheet) N Av = Not available, N App = Not applicable

10. STABILITY AND REACTIVITY

Chemical stability: This material is thermally stable when stored and used as directed.

Conditions to avoid: Elevated temperatures and sources of ignition.

Incompatible materials: Oxidising agents.

Hazardous decomposition products: Oxides of carbon and nitrogen, smoke and other toxic fumes.

Hazardous reactions: No known hazardous reactions.

11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Acute Effects Inhalation: Material may be an irritant to mucous membranes and respiratory tract. Skin contact: Contact with skin may result in irritation. Ingestion: Swallowing can result in nausea, vomiting and irritation of the gastrointestinal tract. Eye contact: May be an eye irritant.

Acute toxicity Inhalation: This material has been classified as not hazardous for acute inhalation exposure. Acute toxicity estimate (based on ingredients): LC50 > 20.0 mg/L for vapours or LC50 > 5.0 mg/L for dust and mist. Skin contact: This material has been classified as not hazardous for acute dermal exposure. Acute toxicity estimate (based on ingredients): LD50 > 2,000 mg/Kg bw Ingestion: This material has been classified as not hazardous for acute ingestion exposure. Acute toxicity estimate (based on ingredients): LD50 > 2,000 mg/Kg bw

Corrosion/Irritancy: Eye: this material has been classified as not corrosive or irritating to eyes. Skin: this material has been classified as not corrosive or irritating to skin.

Sensitisation: Inhalation: this material has been classified as not a respiratory sensitiser. Skin: this material has been classified as not a skin sensitiser.

Aspiration hazard: This material has been classified as not an aspiration hazard.

Specific target organ toxicity (single exposure): This material has been classified as not a specific hazard to target organs by a single exposure.

Chronic Toxicity Mutagenicity: This material has been classified as not a mutagen. Carcinogenicity: This material has been classified as not a carcinogen. Reproductive toxicity (including via lactation): This material has been classified as not a reproductive toxicant. Specific target organ toxicity (repeat exposure): This material has been classified as not a specific hazard to target organs by repeat exposure.

12. ECOLOGICAL INFORMATION

Avoid contaminating waterways.

Acute aquatic hazard: This material has been classified as not hazardous for acute aquatic exposure. Acute toxicity estimate (based on ingredients): > 100 mg/L

Long-term aquatic hazard: This material has been classified as not hazardous for chronic aquatic exposure. Non-rapidly or rapidly degradable substance for which there are adequate chronic toxicity data available OR in the absence of chronic toxicity data, Acute toxicity estimate (based on ingredients): >100 mg/L, where the substance is not rapidly degradable and/or BCF < 500 and/or log Kow < 4.

Ecotoxicity: No information available. Persistence and degradability: No information available. Bioaccumulative potential: No information available. Mobility: No information available.

13. DISPOSAL CONSIDERATIONS

Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal protection equipment is used, see "Section 8. Exposure Controls and Personal Protection" of this SDS.

If possible material and its container should be recycled. If material or container cannot be recycled, dispose in accordance with local, regional, national and international Regulations.

14. TRANSPORT INFORMATION

ROAD AND RAIL TRANSPORT Classified as Dangerous Goods by the criteria of the “Australian Code for the Transport of Dangerous Goods by Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".

Australian Special Provisions; AU01: Environmentally Hazardous Substances meeting the description of UN 3077 or UN 3082 are not subject to this Code (ADG 07) when transported by road or rail in; (c) packagings that do not incorporate a receptacle exceeding 500 Kg (L); or (d) IBCs.

[Diagram: Class 9 Miscellaneous Dangerous Goods diamond symbol]

UN No: 3082 Dangerous Goods Class: 9 Packing Group: III Hazchem Code: •3Z Emergency Response Guide No: 47 Limited Quantities: 5 L Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SPINETORAM)

Segregation Dangerous Goods: Not to be loaded with explosives (Class 1). Note 1: Materials that are fire risks are incompatible with oxidising agents (Class 5.1) or organic peroxides (Class 5.2). Exemptions may apply.

MARINE TRANSPORT Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. This material is classified as a Marine Pollutant (P) according to the International Maritime Dangerous Goods Code.

[Diagram: Class 9 Miscellaneous Dangerous Goods diamond symbol]

UN No: 3082 Dangerous Goods Class: 9 Packing Group: III Limited Quantities: 5 L Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SPINETORAM)

AIR TRANSPORT Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air.

[Diagram: Class 9 Miscellaneous Dangerous Goods diamond symbol]

UN No: 3082 Dangerous Goods Class: 9 Packing Group: III Limited Quantities: 30 kg G Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SPINETORAM)

15. REGULATORY INFORMATION

This material is not subject to the following international agreements: Montreal Protocol (Ozone depleting substances) The Stockholm Convention (Persistent Organic Pollutants) The Rotterdam Convention (Prior Informed Consent) Basel Convention (Hazardous Waste) International Convention for the Prevention of Pollution from Ships (MARPOL)

This material/constituent(s) is covered by the following requirements: The Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) established under the Therapeutic Goods Act (Commonwealth): S5. Caution. AICIS Status: All components of this product are listed on or exempt from the Australian Inventory of Industrial Chemicals (AIIC). NZ EPA Status: All components of this product are listed on or exempt from the New Zealand Inventory of Chemical (NZIoC). HSNO Approval Code: HSR100925

16. OTHER INFORMATION

Reason for issue: Revised

This Safety Data Sheet has been prepared by Chemical Data Services Pty Ltd () on behalf of its client.

Safety Data Sheets are updated frequently. Please ensure that you have a current copy.

This SDS summarises at the date of issue our best knowledge of the health and safety hazard information of the product, and in particular how to safely handle and use the product in the workplace. Since the company cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this SDS in the context of how the user intends to handle and use the product in the workplace.

If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.

Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also available upon request.