SDS - Envu Dedicate Turf and Ornamental - 230925

SAFETY DATA SHEET

DEDICATE TURF AND ORNAMENTAL FUNGICIDE

Version 1.1

Revision Date: 06.11.2024

SDS Number: 11272708-00002

Date of last issue: 25.09.2023 Date of first issue: 25.09.2023

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SECTION 1: IDENTIFICATION

Product name : DEDICATE TURF AND ORNAMENTAL FUNGICIDE

Product code : Article/SKU: 84062766 UVP: 86300524 Specification: 102000011306

Manufacturer or supplier's details

Company : 2022 Environmental Science AU Pty Ltd

Address : Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123

Emergency telephone number :

Recommended use of the chemical and restrictions on use

Recommended use : Fungicide

Restrictions on use : See product label for restrictions.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Reproductive toxicity : Category 2 Effects on or via lactation

GHS label elements

Hazard pictograms : [Exclamation mark pictogram]

Signal word : Warning

Hazard statements : H361d Suspected of damaging the unborn child. H362 May cause harm to breast-fed children.

Precautionary statements :

Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood.

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P263 Avoid contact during pregnancy and while nursing. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response: P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Storage: P405 Store locked up.

Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Suspension concentrate (=flowable concentrate)(SC)

Components

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.

If inhaled : If inhaled, remove to fresh air. Get medical attention.

In case of skin contact : In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

In case of eye contact : Flush eyes with water as a precaution.

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Get medical attention if irritation develops and persists.

If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention. Rinse mouth thoroughly with water.

Most important symptoms and effects, both acute and delayed : No symptoms known or expected. Suspected of damaging the unborn child. May cause harm to breast-fed children.

Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8).

Notes to physician : There is no specific antidote available. Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing media : High volume water jet

Specific hazards during fire fighting : Exposure to combustion products may be a hazard to health.

Hazardous combustion products : Nitrogen oxides (NOx) Chlorine compounds Carbon oxides Fluorine compounds Metal oxides Oxides of phosphorus

Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so.

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Evacuate area.

Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Hazchem Code : •3Z

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Follow safe handling advice (see section 7) and personal protective equipment recommendations (see section 8).

Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up : Soak up with inert absorbent material. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation : Use only with adequate ventilation.

Advice on safe handling : Avoid contact during pregnancy and while nursing. Avoid inhalation of vapour or mist. Do not swallow. Avoid contact with eyes.

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Avoid prolonged or repeated contact with skin. Wash skin thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment Do not eat, drink or smoke when using this product. Take care to prevent spills, waste and minimize release to the environment.

Hygiene measures : If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.

Conditions for safe storage : Keep in properly labelled containers. Store locked up. Store in accordance with the particular national regulations.

Materials to avoid : Do not store with the following product types: Strong oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.

Personal protective equipment

Respiratory protection : If adequate local exhaust ventilation is not available or exposure assessment demonstrates exposures outside the recommended guidelines, use respiratory protection.

Filter type : Particulates type

Hand protection

Material : Nitrile rubber Break through time : > 480 min Glove thickness : > 0.4 mm

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Protective index : Class 6

Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.

Eye protection : Wear the following personal protective equipment: Safety glasses

Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : suspension

Colour : light beige, white

Odour : characteristic, very faint

Odour Threshold : No data available

pH : 6 - 8 (23 °C) Concentration: 100 %

Melting point/freezing point : No data available

Initial boiling point and boiling range : No data available

Flash point : > 100 °C

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Flammability (liquids) : Ignitable (see flash point)

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Upper explosion limit / Upper flammability limit : No data available

Lower explosion limit / Lower flammability limit : No data available

Vapour pressure : No data available

Relative vapour density : No data available

Density : ca. 1.1 g/cm³ (20 °C)

Solubility(ies) Water solubility : completely miscible

Partition coefficient: n octanol/water : Not applicable

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity Viscosity, dynamic : 200 - 500 mPa.s ( 20 °C) Shear rate of 20/sec

Viscosity, kinematic : No data available

Flow time : 40 - 60 s (20 °C)

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Minimum ignition energy : Not applicable

Particle characteristics Particle size : 3 - 5 µm

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reactions : Can react with strong oxidizing agents.

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Conditions to avoid : None known.

Incompatible materials : Oxidizing agents

Hazardous decomposition products : No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Exposure routes : Inhalation Skin contact Ingestion Eye contact

Acute toxicity

Not classified based on available information.

Product: Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method

Components:

Tebuconazole: Acute oral toxicity : LD50 (Rat, female): 1,700 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 2.118 mg/l Exposure time: 4 h Test atmosphere: dust/mist

Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg

Trifloxystrobin: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg

Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg

Propylene glycol: Acute oral toxicity : LD50 (Rat): 22,000 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 44.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist

Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity

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Skin corrosion/irritation

Not classified based on available information.

Components:

Tebuconazole: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation

Propylene glycol: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation

Serious eye damage/eye irritation

Not classified based on available information.

Components:

Tebuconazole: Species : Rabbit Result : No eye irritation

Propylene glycol: Species : Rabbit Result : No eye irritation Method : OECD Test Guideline 405

Respiratory or skin sensitisation

Skin sensitisation

Not classified based on available information.

Respiratory sensitisation

Not classified based on available information.

Product: Species : Guinea pig Method : OECD Test Guideline 406 Result : Does not cause skin sensitisation.

Components:

Tebuconazole: Test Type : Maximisation Test Exposure routes : Skin contact Species : Guinea pig Method : OECD Test Guideline 406

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Result : negative

Trifloxystrobin: Assessment : Probability or evidence of skin sensitisation in humans Remarks : Based on national or regional regulation.

Propylene glycol: Test Type : Maximisation Test Exposure routes : Skin contact Species : Guinea pig Result : negative

Chronic toxicity

Germ cell mutagenicity

Not classified based on available information.

Components:

Tebuconazole: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative

Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative

Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative

Trifloxystrobin: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative

Test Type: Chromosome aberration test in vitro Result: negative

Test Type: DNA damage and repair, unscheduled DNA synthesis in mammalian cells (in vitro) Result: negative

Propylene glycol: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative

Test Type: Chromosome aberration test in vitro

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Method: OECD Test Guideline 473 Result: negative

Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative

Carcinogenicity

Not classified based on available information.

Components:

Tebuconazole: Species : Rat Application Route : Ingestion Exposure time : 2 y Result : negative

Trifloxystrobin: Species : Rat Application Route : Ingestion Exposure time : 24 Months Result : negative

Propylene glycol: Species : Rat Application Route : Ingestion Exposure time : 2 Years Result : negative

Reproductive toxicity

Suspected of damaging the unborn child. May cause harm to breast-fed children.

Components:

Tebuconazole: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative

Effects on foetal development : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: positive

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Reproductive toxicity - Assessment : Some evidence of adverse effects on development, based on animal experiments.

Trifloxystrobin: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative

Effects on foetal development : Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative

Reproductive toxicity - Assessment : Studies indicating a hazard to babies during the lactation period

Propylene glycol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Result: negative

Effects on foetal development : Test Type: Embryo-foetal development Species: Mouse Application Route: Ingestion Result: negative

STOT - single exposure

Not classified based on available information.

STOT - repeated exposure

Not classified based on available information.

Components:

Tebuconazole: Assessment : No significant health effects observed in animals at concentrations of 100 mg/kg bw or less.

Trifloxystrobin: Assessment : No significant health effects observed in animals at concentrations of 100 mg/kg bw or less.

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Repeated dose toxicity

Components:

Tebuconazole: Species : Dog NOAEL : 3 mg/kg LOAEL : 4.4 mg/kg Application Route : Ingestion Exposure time : 1 yr Method : OECD Test Guideline 452

Trifloxystrobin: Species : Rat NOAEL : 10 mg/kg Application Route : Ingestion Exposure time : 2 yr

Propylene glycol: Species : Rat, male NOAEL : >= 1,700 mg/kg Application Route : Ingestion Exposure time : 2 yr

Aspiration toxicity

Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

Tebuconazole: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 4.4 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 2.79 mg/l Exposure time: 48 h

Toxicity to algae/aquatic plants : ErC50 (Lemna gibba (gibbous duckweed)): 0.237 mg/l Exposure time: 168 h

Toxicity to fish (Chronic toxicity) : NOEC (Oncorhynchus mykiss (rainbow trout)): 0.012 mg/l Exposure time: 83 d

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 0.01 mg/l Exposure time: 21 d

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Toxicity to microorganisms : EC50 (activated sludge): > 32 mg/l Exposure time: 0.5 h

Trifloxystrobin: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.015 mg/l Exposure time: 96 h Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates : EC50 (Mysidopsis bahia (opossum shrimp)): 0.00862 mg/l Exposure time: 96 h

Toxicity to algae/aquatic plants : ErC50 (Desmodesmus subspicatus (green algae)): 0.0174 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

EC10 (Desmodesmus subspicatus (green algae)): 0.0025 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

Toxicity to fish (Chronic toxicity) : EC10 (Oncorhynchus mykiss (rainbow trout)): 0.0075 mg/l Exposure time: 95 d

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : EC10 (Daphnia magna (Water flea)): 0.00328 mg/l Exposure time: 21 d

Propylene glycol: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates : EC50 (Ceriodaphnia dubia (water flea)): 18,340 mg/l Exposure time: 48 h

Toxicity to algae/aquatic plants : ErC50 (Skeletonema costatum (marine diatom)): 19,300 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Ceriodaphnia dubia (water flea)): 13,020 mg/l Exposure time: 7 d

Toxicity to microorganisms : NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h

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Persistence and degradability

Components:

Propylene glycol: Biodegradability : Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F

Bioaccumulative potential

Components:

Tebuconazole: Bioaccumulation : Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): 78

Partition coefficient: n octanol/water : log Pow: 3.7

Trifloxystrobin: Bioaccumulation : Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): 431 Method: OECD Test Guideline 305

Partition coefficient: n octanol/water : log Pow: 4.5 Method: OECD Test Guideline 107

Propylene glycol: Partition coefficient: n octanol/water : log Pow: -1.07 Method: Regulation (EC) No. 440/2008, Annex, A.8

Mobility in soil No data available

Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer.

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Contaminated packaging : Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trifloxystrobin, Tebuconazole) Class : 9 Packing group : III Labels : 9 Environmentally hazardous : yes

IATA-DGR UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (Trifloxystrobin, Tebuconazole) Class : 9 Packing group : III Labels : Miscellaneous Packing instruction (cargo aircraft) : 964 Packing instruction (passenger aircraft) : 964 Environmentally hazardous : yes

IMDG-Code UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trifloxystrobin, Tebuconazole) Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : yes

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.

National Regulations

ADG UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Trifloxystrobin, Tebuconazole)

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Class : 9 Packing group : III Labels : 9 Hazchem Code : •3Z Environmentally hazardous : yes

Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

Therapeutic Goods (Poisons Standard) Instrument : Schedule 5 (Please use the original publication to check for specific uses, specific conditions or threshold limits that might apply for this chemical)

Prohibition/Licensing Requirements : There is no applicable prohibition, authorisation and restricted use requirements, including for carcinogens referred to in Schedule 10 of the model WHS Act and Regulations.

Active substance : 200 g/l Tebuconazole

100 g/l Trifloxystrobin

SECTION 16: ANY OTHER RELEVANT INFORMATION

Further information

Revision Date : 06.11.2024

Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency,

Date format : dd.mm.yyyy

Full text of other abbreviations

AU OEL : Australia. Workplace Exposure Standards for Airborne Contaminants.

AU OEL / TWA : Exposure standard - time weighted average

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AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA

• International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable.

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