SDS - David Grays Permethrin Ant Dust - 230801

[Logo: DAVID GRAYS] DAVID GRAY & CO. PTY LIMITED 2 Rawlinson Street O'CONNOR WA 6163 SAFETY DATA SHEET

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 1.1 Product identifier Product name DAVID GRAYS PERMETHRIN ANT DUST Synonyms 8101 (10KG) - MANUFACTURER'S CODE ● 8151 (12X500G) - MANUFACTURER'S CODE ● DAVID GRAY PERMETHRIN ANT DUST

1.2 Uses and uses advised against Uses ANT BAIT ● COCKROACH BAIT ● FLEA CONTROL ● SILVERFISH CONTROL

CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA Physical Hazards Not classified as a Physical Hazard Health Hazards Skin Sensitisation: Category 1 Environmental Hazards Aquatic Toxicity (Chronic): Category 1

2.2 GHS Label elements Signal word WARNING Pictograms [Exclamation mark pictogram] [Environment pictogram]

Hazard statements H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects.

Prevention statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection.

SDS Date: 7th Aug 2023 Version No: 4

PRODUCT NAME DAVID GRAYS PERMETHRIN ANT DUST

Response statements P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P321 Specific treatment is advised - see first aid instructions. If skin irritation or rash occurs: Get medical advice/attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage.

Storage statements None allocated.

Disposal statements P501 Dispose of contents/container in accordance with relevant regulations.

2.3 Other hazards No information provided.

3. COMPOSITION/ INFORMATION ON INGREDIENTS 3.1 Substances / Mixtures

   Ingredient	CAS Number	EC Number	Content
   PERMETHRIN	52645-53-1	258-067-9	1%
   NON HAZARDOUS INGREDIENTS	Not Available	Not Available	Remainder

4. FIRST AID MEASURES 4.1 Description of first aid measures Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes. Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor. Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). First aid facilities Eye wash facilities and safety shower should be available.

4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms.

4.3 Immediate medical attention and special treatment needed Treat symptomatically.

5. FIRE FIGHTING MEASURES 5.1 Extinguishing media Dry agent, carbon dioxide or water fog. Prevent contamination of drains and waterways.

5.2 Special hazards arising from the substance or mixture Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, ammonia, hydrocarbons) when heated to decomposition.

5.3 Advice for firefighters Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.

5.4 Hazchem code 2Z 2 Fine Water Spray. Z Wear full fire kit and breathing apparatus. Contain spill and run-off.

6. ACCIDENTAL RELEASE MEASURES

PRODUCT NAME DAVID GRAYS PERMETHRIN ANT DUST

6.1 Personal precautions, protective equipment and emergency procedures Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contact emergency services where appropriate.

6.2 Environmental precautions Prevent product from entering drains and waterways.

6.3 Methods of cleaning up Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.

6.4 Reference to other sections See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE 7.1 Precautions for safe handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

7.2 Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.

7.3 Specific end uses No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters Exposure standards No exposure standards have been entered for this product.

Biological limits No biological limit values have been entered for this product.

8.2 Exposure controls Engineering controls Avoid inhalation. Use in well ventilated areas.

PPE Eye / Face Wear dust-proof goggles. Hands Wear PVC or rubber gloves. Body When using large quantities or where heavy contamination is likely, wear coveralls. Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear a Powered Air Purifying Respirator (PAPR) with Class P3 (Particulate) filter or a Class P3 (Particulate) respirator. [Diagrams of goggles and gloves]

9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance WHITE/TAN POWDER Odour SLIGHT ODOUR Flammability NON FLAMMABLE Flash point NOT RELEVANT Boiling point NOT AVAILABLE Melting point NOT AVAILABLE Evaporation rate NOT AVAILABLE

PRODUCT NAME DAVID GRAYS PERMETHRIN ANT DUST

9.1 Information on basic physical and chemical properties (continued) pH NOT AVAILABLE Vapour density NOT AVAILABLE Specific gravity NOT AVAILABLE Solubility (water) INSOLUBLE Vapour pressure NOT AVAILABLE Upper explosion limit NOT RELEVANT Lower explosion limit NOT RELEVANT Partition coefficient NOT AVAILABLE Autoignition temperature NOT AVAILABLE Decomposition temperature NOT AVAILABLE Viscosity NOT AVAILABLE Explosive properties NOT AVAILABLE Oxidising properties NOT AVAILABLE Odour threshold NOT AVAILABLE

10. STABILITY AND REACTIVITY 10.1 Reactivity Carefully review all information provided in sections 10.2 to 10.6.

10.2 Chemical stability Stable under recommended conditions of storage.

10.3 Possibility of hazardous reactions Polymerization will not occur.

10.4 Conditions to avoid Avoid heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).

10.6 Hazardous decomposition products May evolve toxic gases (carbon/ nitrogen oxides, ammonia, hydrocarbons) when heated to decomposition.

11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Information available for the ingredients:

    Ingredient	Oral LD50	Dermal LD50	Inhalation LC50
    PERMETHRIN	383 mg/kg (rat)	1750 mg/kg (rat)	485 mg/m³ (rat)

Skin Contact may result in irritation, stinging sensation, rash and possible numbness. Eye Contact may result in irritation, lacrimation, pain and redness. Sensitisation May cause an allergic skin reaction. This product is not classified as a respiratory sensitiser. Mutagenicity Not classified as a mutagen. Carcinogenicity Not classified as a carcinogen. Reproductive Not classified as a reproductive toxin. STOT - single exposure Over exposure may result in irritation of the nose and throat, nausea and dizziness. High level exposure to pyrethrins may result in breathing difficulties STOT - repeated exposure Not classified as causing organ damage from repeated exposure. Aspiration This product does not present an aspiration hazard.

12. ECOLOGICAL INFORMATION

PRODUCT NAME DAVID GRAYS PERMETHRIN ANT DUST

12.1 Toxicity Very toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability No information provided.

12.3 Bioaccumulative potential No information provided.

12.4 Mobility in soil No information provided.

12.5 Other adverse effects No information provided.

13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Waste disposal For small amounts, cover with moist sand or similar, collect and dispose of to an approved landfill site. Avoid generating dust. Contact the manufacturer/supplier for additional information (if required). Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE [Miscellaneous Dangerous Goods Class 9 pictogram]

14.5 Environmental hazards Marine Pollutant

14.6 Special precautions for user Hazchem code 2Z GTEPG 9C1 EMS F-A, S-F Other information Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to the Australian Dangerous Goods Code when transported by road or rail in; (a) packagings; (b) IBCs; or (c) any other receptacle not exceeding 500 kg(L).

• Australian Special Provisions (SP AU01) - ADG Code 7th Ed. Labels Required: MISCELLANEOUS.

15. REGULATORY INFORMATION

PRODUCT NAME DAVID GRAYS PERMETHRIN ANT DUST

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Classifications (GHS) of Classification and Safework Australia criteria is based on the Globally Harmonised System Labelling of Chemicals. Inventory listings AUSTRALIA: AICS (Australian Inventory of Chemical Substances) All components are listed on AICS, or are exempt.

16. OTHER INFORMATION Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.

EXPOSURE STANDARDS - TIME WEIGHTED AVERAGE (TWA) or WES (WORKPLACE EXPOSURE STANDARD) (NZ): Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: Strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES: The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE: It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

Abbreviations ACGIH American Conference of Governmental Industrial Hygienists CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds CNS Central Nervous System EC No. EC No - European Community Number EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods) GHS Globally Harmonized System GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm Parts Per Million STEL Short-Term Exposure Limit STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure) SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia TLV Threshold Limit Value TWA Time Weighted Average

PRODUCT NAME DAVID GRAYS PERMETHRIN ANT DUST

Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier. While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005

[ End of SDS ]