Safety Data Sheet

SDS - Proforce Scarlet Trio Advanced Insecticide - 230105

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Applies to Scarlet Trio Advanced Insecticide

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Page 1/7 Safety Data Sheet according to WHS Regulations Printing date 05.01.2023 Revision: 05.01.2023

1 Identification Product Name: ProForce Scarlet Trio Insecticide Other Means of Identification: Mixture APVMA Approval Number: 92166 Recommended Use of the Chemical and Restriction on Use: Agricultural insecticide STOT RE 2 H373 May cause damage to the central nervous system and the peripheral nervous system through prolonged or repeated exposure.

[Image of Environment symbol] Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.

[Image of Exclamation mark symbol] Acute Toxicity (Oral) 4 H302 Harmful if swallowed. Aquatic Acute 2 H401 Toxic to aquatic life.

Signal Word Warning Hazard Statements H302 Harmful if swallowed. H373 May cause damage to the central nervous system and the peripheral nervous system through prolonged or repeated exposure. H401 Toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. (Contd. on page 2)

Page 2/7 Safety Data Sheet according to WHS Regulations Printing date 05.01.2023 Revision: 05.01.2023 Product Name: ProForce Scarlet Trio Insecticide (Contd. of page 1)

P273 Avoid release to the environment. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P330 Rinse mouth. P314 Get medical advice/attention if you feel unwell. P391 Collect spillage. P501 Dispose of contents/container in accordance with local/regional/national regulations.

3 Composition and Information on Ingredients Chemical Characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions.

Hazardous Components:

Component Classification Concentration
CAS: 210880-92-5 Clothianidin Aquatic Chronic 1, H410 (M=10); Acute Toxicity (Oral) 4, H302 10-15%
CAS: 74115-24-5 Clofentezine Acute Toxicity (Inhalation) 3, H331; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Toxicity (Dermal) 4, H312 5-10%
CAS: 71751-41-2 Abamectin Acute Toxicity (Oral) 2, H300; Acute Toxicity (Inhalation) 1, H330; Toxic To Reproduction 2, H361d; STOT RE 1, H372; Aquatic Chronic 1, H410 (M=10000) 1-2%

4 First Aid Measures Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention if breathing problems develop. Skin Contact: In case of skin contact, immediately remove contaminated clothing and wash affected areas with water and soap. Seek medical attention if irritation occurs. Eye Contact: In case of eye contact, rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Seek medical attention if irritation persists. Ingestion: If swallowed, do not induce vomiting. Immediately rinse mouth with water. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Symptoms Caused by Exposure: Inhalation: May cause respiratory irritation. Skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Ingestion: Harmful if swallowed. May cause gastrointestinal irritation, nausea, diarrhoea and vomiting.

5 Fire Fighting Measures Suitable Extinguishing Media: Use fire extinguishing methods suitable to surrounding conditions. Specific Hazards Arising from the Chemical: Hazardous combustion products include oxides of carbon and oxides of nitrogen. Product is not flammable. Containers close to fire should be removed only if safe to do so. Use water spray to cool fire exposed containers. Prevent run-off from fire fighting entering drains or water courses. HAZCHEM Code: •3Z (Contd. on page 3)

Page 3/7 Safety Data Sheet according to WHS Regulations Printing date 05.01.2023 Revision: 05.01.2023 Product Name: ProForce Scarlet Trio Insecticide (Contd. of page 2)

Special Protective Equipment and Precautions for Fire Fighters: When fighting a major fire wear self-contained breathing apparatus and protective equipment.

6 Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures: Wear approved respiratory protection, chemical resistant gloves, protective clothing and safety boots. Evacuate all non-essential personnel from affected area. Do not breathe vapours. Ensure adequate ventilation. Environmental Precautions: In the event of a major spill, prevent spillage from entering drains or water courses. Inform respective authorities in case of seepage into water course or sewage system. Methods and Materials for Containment and Cleaning Up: Wipe up small spills with a paper towel or dry rag. Clean up all spills immediately, since spilled materials, even in small quantities, may present a slip hazard. Absorb large spills with sand, earth, vermiculite or some other absorbent material. Collect the spilled material and place into a suitable container for disposal. Decontaminate spill area with water and detergents.

7 Handling and Storage Precautions for Safe Handling: Use of safe work practices are recommended to avoid eye or skin contact and inhalation of mists. Use only outdoors or in a well-ventilated area. Food, beverages and tobacco products should not be stored or consumed where this material is in use. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use. Provide eyewash fountains and safety showers in close proximity to points of potential exposure. Conditions for Safe Storage: Store in a cool, dry and well ventilated area. Keep container tightly closed when not in use. Protect from heat, sparks, open flames and other sources of ignition.

8 Exposure Controls and Personal Protection Exposure Standards: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Engineering Controls: Natural ventilation should be adequate under normal use conditions. Respiratory Protection: Use an approved mixed particulate / organic vapour (filter type A+P) respirator under conditions where exposure to the substance is apparent (e.g. generation of high concentrations of mist or vapour, inadequate ventilation, development of respiratory tract irritation) and engineering controls are not feasible. See Australian Standards AS/NZS 1715 and 1716 for more information. Skin Protection: Elbow-length chemical resistant gloves. See Australian/New Zealand Standard AS/NZS 2161 for more information. When selecting gloves for use against certain chemicals, the degradation resistance, permeation rate and permeation breakthrough time should be considered. Occupational protective clothing, including cotton overalls buttoned to neck and wrist (depending on conditions in which it has to be used, in particular as regards the period for which it is worn, which shall be determined on the basis of the seriousness of the risk, the frequency of exposure to the risk, the characteristics of the workstation of each worker and the performance of the protective clothing). See Australian/New Zealand Standard AS/NZS 4501 for more information. (Contd. on page 4)

Page 4/7 Safety Data Sheet according to WHS Regulations Printing date 05.01.2023 Revision: 05.01.2023 Product Name: ProForce Scarlet Trio Insecticide (Contd. of page 3)

Eye and Face Protection: Safety glasses with top and side shields or goggles. See Australian/New Zealand Standards AS/NZS 1336 and 1337 for more information.

9 Physical and Chemical Properties Appearance: Form: Liquid Colour: Pink, opaque Odour: No information available Odour Threshold: No information available pH-Value: 7 - 8 (1%) Melting point/freezing point: No information available Initial Boiling Point/Boiling Range: No information available Flash Point: No information available Flammability: Not applicable. Auto-ignition Temperature: No information available Decomposition Temperature: No information available Explosion Limits: Lower: No information available Upper: No information available Vapour Pressure: No information available Relative Density: 1.07 - 1.13 Vapour Density: No information available Evaporation Rate: No information available Solubility in Water: Miscible Partition Coefficient (n-octanol/water): No information available

10 Stability and Reactivity Possibility of Hazardous Reactions: No dangerous reactions known under conditions of normal use. Chemical Stability: Stable at ambient temperature and under normal conditions of storage and use. Conditions to Avoid: No further relevant information available. Incompatible Materials: No further relevant information available. Hazardous Decomposition Products: Oxides of carbon and oxides of nitrogen.

11 Toxicological Information Toxicity: LD50/LC50 Values:

Component Type Value
CAS: 210880-92-5 Clothianidin Oral LD50 >500 mg/kg (rat)
LD50 >2,000 mg/kg (rat)
Dermal LD50 >2,000 mg/kg (rabbit)
Inhalation LC50 >5.54 mg/l (rat)
CAS: 74115-24-5 Clofentezine Oral LD50 >5,200 mg/kg (rat)
Dermal LD50 2,100 mg/kg (rat)
Inhalation LC50/4 h >5.2 mg/l (rat)
CAS: 71751-41-2 Abamectin Oral LD50 1,230 mg/kg (rat)
(Contd. on page 5)

Page 5/7 Safety Data Sheet according to WHS Regulations Printing date 05.01.2023 Revision: 05.01.2023 Product Name: ProForce Scarlet Trio Insecticide (Contd. of page 4)

Component Type Value
LD50 >330 mg/kg (rat)
Inhalation LC50/4 h >4.178 mg/l (rat)

Acute Health Effects Inhalation: May cause respiratory irritation. Skin: May cause skin irritation. Eye: May cause eye irritation. Ingestion: Harmful if swallowed. May cause gastrointestinal irritation, nausea, diarrhoea and vomiting. Skin Corrosion / Irritation: Based on classification principles, the classification criteria are not met. Serious Eye Damage / Irritation: Based on classification principles, the classification criteria are not met. Respiratory or Skin Sensitisation: Based on classification principles, the classification criteria are not met. Germ Cell Mutagenicity: Based on classification principles, the classification criteria are not met. Carcinogenicity: Based on classification principles, the classification criteria are not met. This product does NOT contain any IARC listed chemicals. Reproductive Toxicity: Based on classification principles, the classification criteria are not met. Specific Target Organ Toxicity (STOT) - Single Exposure: Based on classification principles, the classification criteria are not met. Specific Target Organ Toxicity (STOT) - Repeated Exposure: May cause damage to the central nervous system and the peripheral nervous system through prolonged or repeated exposure. Aspiration Hazard: Based on classification principles, the classification criteria are not met. Chronic Health Effects: No information available Existing Conditions Aggravated by Exposure: No information available Additional toxicological information: The Australian Acceptable Daily Intake (ADI) for clothianidin for a human is 0.05 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the LOAEL of 9.7 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. The Australian Acceptable Daily Intake (ADI) for clofentezine for a human is 0.02 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the NOAEL of 2 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. The Australian Acceptable Daily Intake (ADI) for abamectin for a human is 0.001 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the NOAEL of 0.12 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. (Ref: Australian Pesticides and Veterinary Medicines Authority, 'Acceptable Daily Intakes for Agricultural and Veterinary Chemicals', 2022).

12 Ecological Information Ecotoxicity: Highly toxic to bees. CAS: 71751-41-2 Abamectin LC50/24 h 0.002 μg/bee (bee) LD50 0.009 μg/bee (bee) LD50 >2,000 mg/kg (bobwhite quail) LC50 3,120 ppm (bobwhite quail) Aquatic toxicity: Very toxic to aquatic life with long lasting effects. (Contd. on page 6)

Page 6/7 Safety Data Sheet according to WHS Regulations Printing date 05.01.2023 Revision: 05.01.2023 Product Name: ProForce Scarlet Trio Insecticide (Contd. of page 5)

CAS: 210880-92-5 Clothianidin EC50/48 h >119 mg/l (daphnia magna) LC50/96 h >104.2 mg/l (rainbow trout) CAS: 71751-41-2 Abamectin EC50/96 h 7.3 mg/l (algae) Persistence and Degradability: No data available on finished product. Bioaccumulative Potential: No data available on finished product. Mobility in Soil: No data available on finished product. Other adverse effects: No further relevant information available.

13 Disposal Considerations Disposal Methods and Containers: Must not be disposed together with household garbage. Do not allow product to reach sewage system. Dispose according to applicable local and state government regulations. Special Precautions for Landfill or Incineration: Please consult your state Land Waste Management Authority for more information.

14 Transport Information UN Number ADG, IMDG, IATA UN3082 Proper Shipping Name ADG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Abamectin, Clothianidin) IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Abamectin, Clothianidin), MARINE POLLUTANT Dangerous Goods Class ADG Class: 9 Packing Group: ADG, IMDG, IATA III Marine pollutant: Yes EMS Number: F-A,S-F Hazchem Code: •3Z Special Provisions: 274, 331, 335, 375, AU01 Transport/Additional information: Not subject to the ADG Code when transported by road or rail in packagings that do not incorporate a receptacle exceeding 500 kg(L) or IBCs. (refer to SP AU01) Excepted quantities (EQ): E1 Limited Quantities: 5 L Packagings & IBCs - Packing Instruction: P001, IBC03, LP01 Packagings & IBCs - Special Packing Provisions: PP1 Portable Tanks & Bulk Containers - Instructions: T4 (Contd. on page 7)

Page 7/7 Safety Data Sheet according to WHS Regulations Printing date 05.01.2023 Revision: 05.01.2023 Product Name: ProForce Scarlet Trio Insecticide (Contd. of page 6)

Portable Tanks & Bulk Containers - Special Provisions: TP1, TP29

15 Regulatory Information Australian Inventory of Industrial Chemicals: All components are on the inventory, or in compliance with the inventory. Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Poison Schedule: Poisons Schedule: 6 Australian Pesticides and Veterinary Medicines Authority: This product is registered with the Australian Pesticides and Veterinary Medicines Authority. APVMA approval number 92166.

16 Other Information Date of Preparation or Last Revision: 05.01.2023 Prepared by: Pty Ltd Abbreviations and acronyms: ADG: Australian Dangerous Goods IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent IARC: International Agency for Research on Cancer STEL: Short Term Exposure Limit TWA: Time Weighted Average NES: National Exposure Standard (Safe Work Australia - Workplace Exposure Standards For Airborne Contaminants) Acute Toxicity (Oral) 2: Acute toxicity – Category 2 Acute Toxicity (Oral) 4: Acute toxicity – Category 4 Acute Toxicity (Inhalation) 1: Acute toxicity – Category 1 Acute Toxicity (Inhalation) 3: Acute toxicity – Category 3 Toxic To Reproduction 2: Reproductive toxicity – Category 2 STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 Aquatic Acute 1: Hazardous to the aquatic environment, short-term (Acute). Category 1 Aquatic Acute 2: Hazardous to the aquatic environment, short-term (Acute). Category 2 Aquatic Chronic 1: Hazardous to the aquatic environment, long-term (Chronic). Category 1

Disclaimer This SDS is prepared in accord with the Safe Work Australia document “Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals - July 2020”. The information contained in this safety data sheet is provided in good faith and is believed to be accurate at the date of issuance. Indigo Specialty Products Pty Ltd makes no representation of the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or damage related to the supply or use of the information in this material safety data sheet. Pty Ltd is not in a position to warrant the accuracy of the data herein. The user is cautioned to make their own determinations as to the suitability of the information provided to the particular circumstances in which the product is used.