--- title: SDS - Envu Signature Xtra Stressgard Systemic Fungcide - 231109 canonical: https://fernland.com.au/documents/316/ dateModified: 2026-08-03 01:14:08 summary: Safety Data Sheet type: sds --- # SDS - Envu Signature Xtra Stressgard Systemic Fungcide - 231109 > Safety Data Sheet SAFETY DATA SHEET SIGNATURE XTRA STRESSGARD SYSTEMIC TURF FUNGICIDE Version 1.0 Revision Date: 09.11.2023 SDS Number: 11292565-00001 Date of last issue: - Date of first issue: 09.11.2023 1 / 18 SECTION 1: IDENTIFICATION Product name : SIGNATURE XTRA STRESSGARD SYSTEMIC TURF FUNGICIDE Product code : Article/SKU: 86802724, 85785265 UVP: 81691088 Specification: 102000029598 Manufacturer or supplier's details Company : 2022 Environmental Science AU Pty Ltd Address : Suite 2.06, Level 2, 737 Burwood Road Hawthorn East, Australia 3123 Emergency telephone number : Recommended use of the chemical and restrictions on use Recommended use : Fungicide Plant protection agent Restrictions on use : Not applicable SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage/eye irritation : Category 2B GHS label elements Hazard pictograms : None Signal word : Warning Hazard statements : H320 Causes eye irritation. Precautionary statements : Prevention: P264 Wash skin thoroughly after handling. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Other hazards which do not result in classification None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Water dispersible granules (WG) Components | Chemical name | CAS-No. | Concentration (% w/w) | | :--- | :--- | :--- | | Fosetyl-aluminium | 39148-24-8 | >= 60 -= 3 -= 1 - 480 min Glove thickness : > 0.4 mm Protective index : Class 6 Remarks : Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Skin should be washed after contact. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : granules Colour : green Odour : acidic, slight Odour Threshold : No data available pH : 3.0 - 5.0 (23 °C) Concentration: 10 % Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : Not applicable Evaporation rate : Not applicable Flammability (solid, gas) : Not classified as a flammability hazard Self-ignition : Method: Regulation (EC) No. 440/2008, Annex, A.16 The substance or mixture is not classified as self heating. Upper explosion limit / Upper flammability limit : Not applicable Lower explosion limit / Lower flammability limit : Not applicable Vapour pressure : Not applicable Relative vapour density : Not applicable Relative density : No data available Bulk density : 705 kg/m³ Solubility(ies) Water solubility : dispersible Partition coefficient: n-octanol/water : Not applicable Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, kinematic : Not applicable Explosive properties : Not explosive Method: Regulation (EC) No. 440/2008, Annex, A.14 Oxidizing properties : The substance or mixture is not classified as oxidizing. Dust explosion class : No data available Particle size : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Can react with strong oxidizing agents. Conditions to avoid : None known. Incompatible materials : Strong oxidizing agents Strong acids and strong bases Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Exposure routes : Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : LD50 (Rat, female): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.22 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Components: Fosetyl-aluminium: Acute oral toxicity : LD50 (Rabbit): 2,680 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.11 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Acute oral toxicity : LD50 (Rat): > 453 - 1,368 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC50 (Rat, male): 1.09 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Acute dermal toxicity : LD50 (Rabbit, male): > 2,000 mg/kg Remarks: Based on data from similar materials Formic acid: Acute oral toxicity : LD50 (Rat): 730 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC50 (Rat): 7.85 mg/l Exposure time: 4 h Test atmosphere: vapour Method: OECD Test Guideline 403 Assessment: Corrosive to the respiratory tract. Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Remarks: Based on data from similar materials Skin corrosion/irritation Not classified based on available information. Product: Species : Rabbit Result : No skin irritation Components: 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Species : Rabbit Result : No skin irritation Formic acid: Result : Corrosive after 3 minutes or less of exposure Remarks : Based on national or regional regulation. Serious eye damage/eye irritation Causes eye irritation. Product: Species : Rabbit Result : Irritation to eyes, reversing within 7 days Components: Fosetyl-aluminium: Result : Irreversible effects on the eye Remarks : Based on national or regional regulation. 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Species : Rabbit Result : Irreversible effects on the eye Formic acid: Result : Irreversible effects on the eye Remarks : Based on skin corrosivity. Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Product: Exposure routes : Skin contact Species : Guinea pig Result : negative Components: Formic acid: Test Type : Buehler Test Exposure routes : Skin contact Species : Guinea pig Method : OECD Test Guideline 406 Result : negative Chronic toxicity Germ cell mutagenicity Not classified based on available information. Components: 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative Formic acid: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Genotoxicity in vivo : Test Type: Sex-linked recessive lethal test in Drosophila melanogaster (in vivo) Application Route: Ingestion Method: OECD Test Guideline 477 Result: negative Carcinogenicity Not classified based on available information. Components: Fosetyl-aluminium: Species : Dog Application Route : Ingestion Exposure time : 2 Years Result : negative Formic acid: Species : Rat Application Route : Ingestion Exposure time : 104 weeks Result : negative Remarks : Based on data from similar materials Reproductive toxicity Not classified based on available information. Components: Fosetyl-aluminium: Effects on fertility : Test Type: Four-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Effects on fertility : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Effects on foetal development : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Formic acid: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Remarks: Based on data from similar materials Effects on foetal development : Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials STOT - single exposure Not classified based on available information. Components: 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Assessment : May cause respiratory irritation. STOT - repeated exposure Not classified based on available information. Components: 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Assessment : No significant health effects observed in animals at concentrations of 0.2 mg/l/6h/d or less. Repeated dose toxicity Components: Fosetyl-aluminium: Species : Rat NOAEL : 500 mg/kg Application Route : Ingestion Exposure time : 13 Weeks Species : Rat NOAEL : 1,050 mg/kg Application Route : Skin contact Exposure time : 28 Days 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Species : Rat NOAEL : 100 mg/kg LOAEL : 300 mg/kg Application Route : Ingestion Exposure time : 36 - 52 Days Method : OECD Test Guideline 422 Species : Rat NOAEL : 0.004 mg/l LOAEL : 0.01 mg/l Application Route : inhalation (dust/mist/fume) Exposure time : 90 Days Method : OECD Test Guideline 413 Formic acid: Species : Rat NOAEL : 400 mg/kg Application Route : Ingestion Exposure time : 52 Weeks Remarks : Based on data from similar materials Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 500 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : ErC50 (Desmodesmus subspicatus (green algae)): 43.50 mg/l Exposure time: 72 h Components: Fosetyl-aluminium: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 122 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 29.6 mg/l Exposure time: 48 h Toxicity to algae/aquatic plants : ErC50 (Selenastrum capricornutum (green algae)): 2.715 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Oncorhynchus mykiss (rainbow trout)): >= 100 mg/l Exposure time: 28 d Method: OECD Test Guideline 215 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 17 mg/l Exposure time: 21 d Ecotoxicology Assessment Chronic aquatic toxicity : No toxicity at the limit of solubility 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : ErC50 (Raphidocelis subcapitata (freshwater green alga)): > 200 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 NOEC (Raphidocelis subcapitata (freshwater green alga)): 12.5 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to microorganisms : NOEC (activated sludge): 0.16 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Formic acid: Toxicity to fish : LC50 (Danio rerio (zebra fish)): 130 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 365 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: Based on data from similar materials Toxicity to algae/aquatic plants : ErC50 (Pseudokirchneriella subcapitata (green algae)): 1,240 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials EC10 (Pseudokirchneriella subcapitata (green algae)): 295 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Toxicity to microorganisms : NOEC: 72 mg/l Exposure time: 13 d Persistence and degradability Components: 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Biodegradability : Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 29 d Method: OECD Test Guideline 301B Formic acid: Biodegradability : Result: Readily biodegradable. Biodegradation: 100 % Exposure time: 28 d Method: OECD Test Guideline 301C Bioaccumulative potential Components: Fosetyl-aluminium: Partition coefficient: n-octanol/water : log Pow: -2.11 2-Propanol, reaction products with naphthalene, sulfonated, sodium salts: Partition coefficient: n-octanol/water : log Pow: -0.27 Formic acid: Partition coefficient: n-octanol/water : log Pow: -2.1 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Do not dispose of waste into sewer. Contaminated packaging : Follow advice on product label and/or leaflet. Empty containers retain residue and can be dangerous. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG UN number : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable IATA-DGR UN/ID No. : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable Packing instruction (cargo aircraft) : Not applicable Packing instruction (passenger aircraft) : Not applicable IMDG-Code UN number : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable EmS Code : Not applicable Marine pollutant : Not applicable Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations ADG UN number : Not applicable Proper shipping name : Not applicable Class : Not applicable Subsidiary risk : Not applicable Packing group : Not applicable Labels : Not applicable Hazchem Code : Not applicable Special precautions for user Not applicable SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform Scheduling of Medicines and Poisons : Schedule 6 Standard for the Uniform Scheduling of Medicines and Poisons : Schedule 5 Prohibition/Licensing Requirements : There is no applicable prohibition, authorisation and restricted use requirements, including for carcinogens referred to in Schedule 10 of the model WHS Act and Regulations. Active substance : 60 % Fosetyl-aluminium SECTION 16: ANY OTHER RELEVANT INFORMATION Further information Revision Date : 09.11.2023 Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency, Date format : dd.mm.yyyy Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) AU OEL : Australia. Workplace Exposure Standards for Airborne Contaminants. ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit AU OEL / TWA : Exposure standard - time weighted average AU OEL / STEL : Exposure standard - short term exposure limit AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. AU / EN