--- title: SDS - UPL Penncozeb 750 DF Fungicide - 250611 canonical: https://fernland.com.au/documents/162/ dateModified: 2026-08-03 01:11:58 summary: Safety Data Sheet type: sds --- # SDS - UPL Penncozeb 750 DF Fungicide - 250611 > Safety Data Sheet Safety Data Sheet Hazardous, Dangerous Goods 1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION Product name: Penncozeb 750 DF Fungicide Recommended use: A fungicide used in agricultural situations as per the registered label. Supplier: UPL Australia Pty Ltd Street Address: Level 3, 70 Hindmarsh Square Adelaide, South Australia, 5000 Facsimile: Emergency Telephone number: AUST: (INT: ) 2. HAZARDS IDENTIFICATION This material is hazardous according to health criteria of Safe Work Australia. [Diagram: Exclamation mark symbol] [Diagram: Corrosion symbol] Signal Word Danger Hazard Classifications Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Irritation - Category 1 Sensitisation - Respiratory - Category 1 Sensitisation - Skin - Category 1 Toxic to Reproduction - Category 2 Hazard Statements H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361 Suspected of damaging fertility or the unborn child . Prevention Precautionary Statements P102 Keep out of reach of children. P103 Read label before use. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust, fume, gas, mist, vapours or spray.. P264 Wash hands, face and all exposed skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. Response Precautionary Statements P101 If medical advice is needed, have product container or label at hand. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. P362 Take off contaminated clothing and wash before reuse. Storage Precautionary Statement P405 Store locked up. Disposal Precautionary Statement P501 Dispose of contents/container in accordance with local, regional, national and international regulations. Poison Schedule: S5. Caution DANGEROUS GOOD CLASSIFICATION Classified as Dangerous Goods by the criteria of the "Australian Code for the Transport of Dangerous Goods by Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land". Dangerous Goods Class: 9 Australian Special Provisions; AU01: Environmentally Hazardous Substances meeting the description of UN 3077 or UN 3082 are not subject to this Code (ADG 07) when transported by road or rail in; (a) packagings that do not incorporate a receptacle exceeding 500 Kg (L); or (b) IBCs. 3. COMPOSITION INFORMATION | CHEMICAL ENTITY | CAS NO | PROPORTION | | :--- | :--- | :--- | | Mancozeb | 8018-01-7 | 750 g/Kg | | Hexamine | 100-97-0 | 1 - 10 % (w/w) | | Naphthalenesulfonic acid, sodium salt, isopropylated | 68442-09-1 | 1 - 10 % (w/w) | | Naphthalenesulfonic acid, bis(1-methylethyl)-, sodium salt | -6 | 1 - 10 % (w/w) | | Ingredients determined to be Non-Hazardous | | Balance | | | | 100% | 4. FIRST AID MEASURES If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand 0800 764 766). Inhalation: Effects may be delayed. Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. If breathing laboured and patient cyanotic (blue), ensure airways are clear and have a qualified person give oxygen through a facemask. If breathing has stopped apply artificial respiration at once. In the event of cardiac arrest, apply external cardiac massage. Seek immediate medical advice. Skin Contact: Effects may be delayed. If skin or hair contact occurs, immediately remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre or a Doctor; or for 15 minutes and transport to Doctor or Hospital. Eye contact: Immediately irrigate with copious quantities of water for 15 minutes. Eyelids to be held open. Remove clothing if contaminated and wash skin. Urgently seek medical assistance. Transport to hospital or medical centre. Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to drink. Never give anything by the mouth to an unconscious patient. If vomiting occurs give further water. Seek medical advice. PPE for First Aiders: Wear safety shoes, overalls, gloves, chemical goggles, dust mask. Available information suggests that gloves made from nitrile rubber should be suitable for intermittent contact. However, due to variations in glove construction and local conditions, the user should make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storing or re-using. Notes to physician: Treat symptomatically. Effects may be delayed. Can cause corneal burns. 5. FIRE FIGHTING MEASURES Hazchem Code: 2Z Suitable extinguishing media: If material is involved in a fire use water fog (or if unavailable fine water spray), alcohol resistant foam, standard foam, dry agent (carbon dioxide, dry chemical powder). Specific hazards: Combustible material. Fire fighting further advice: On burning or decomposing may emit toxic fumes. Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion or decomposition. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILLS Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours or dust. Wipe up with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal. LARGE SPILLS Clear area of all unprotected personnel. Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination and the inhalation of dust. Work up wind or increase ventilation. Cover with damp absorbent (inert material, sand or soil). Sweep or vacuum up, but avoid generating dust. Collect and seal in properly labelled containers or drums for disposal. If contamination of crops, sewers or waterways has occurred advise local emergency services. Dangerous Goods - Initial Emergency Response Guide No: 47 7. HANDLING AND STORAGE Handling: Avoid eye contact and skin contact. Avoid inhalation of dust. Storage: Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from foodstuffs. Store away from incompatible materials described in Section 10. Store away from sources of heat and/or ignition. Store locked up. Keep container standing upright. Keep containers closed when not in use - check regularly for spills. This material is classified as a Class 9 Miscellaneous Dangerous Good as per the criteria of the "Australian Code for the Transport of Dangerous Goods by Road & Rail" and/or the "New Zealand NZS5433: Transport of Dangerous Goods on Land" and must be stored in accordance with the relevant regulations. This material is a Scheduled Poison Schedule 5 (Caution) and must be stored, maintained and used in accordance with the relevant regulations. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National occupational exposure limits: No value assigned for this specific material by Safe Work Australia. Biological Limit Values: As per the "National Model Regulations for the Control of Workplace Hazardous Substances (Safe Work Australia)" the ingredients in this material do not have a Biological Limit Allocated. Engineering Measures: Natural ventilation should be adequate under normal use conditions. Personal Protection Equipment: SAFETY SHOES, OVERALLS, GLOVES, CHEMICAL GOGGLES, DUST MASK. Personal protective equipment (PPE) must be suitable for the nature of the work and any hazard associated with the work as identified by the risk assessment conducted. Wear safety shoes, overalls, gloves, chemical goggles, dust mask. Available information suggests that gloves made from nitrile rubber should be suitable for intermittent contact. However, due to variations in glove construction and local conditions, the user should make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storing or re-using. Hygiene measures: Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or smoke. Wash hands prior to eating, drinking or smoking. Avoid contact with clothing. Avoid eye contact and skin contact. Avoid inhalation of dust. Ensure that eyewash stations and safety showers are close to the workstation location. 9. PHYSICAL AND CHEMICAL PROPERTIES Form: Granules Colour: Greyish Odour: Mild characteristic Solubility: Dispersible in water Specific Gravity: N Av Relative Vapour Density (air=1): N App Vapour Pressure (20 °C): N App Flash Point (°C): N App Flammability Limits (%): N App Autoignition Temperature (°C): N Av Melting Point/Range (°C): Sublimes Boiling Point/Range (°C): N App Decomposition Point (°C): 192 pH: N App Viscosity: N App Total VOC (g/Litre): N Av (Typical values only - consult specification sheet) N Av = Not available, N App = Not applicable 10. STABILITY AND REACTIVITY Chemical stability: This material is thermally stable when stored and used as directed. Conditions to avoid: Elevated temperatures and sources of ignition. Incompatible materials: Oxidising agents. Hazardous decomposition products: Oxides of carbon and nitrogen, smoke and other toxic fumes. Hazardous reactions: No known hazardous reactions. 11. TOXICOLOGICAL INFORMATION No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Acute Effects Inhalation: Material may be an irritant to mucous membranes and respiratory tract. A respiratory sensitiser. Can cause possible allergic reactions. Skin contact: Contact with skin will result in irritation. A skin sensitiser. Repeated or prolonged skin contact may lead to allergic contact dermatitis. Ingestion: Swallowing can result in nausea, vomiting and irritation of the gastrointestinal tract. Eye contact: A severe eye irritant. Corrosive to eyes: contact can cause corneal burns. Contamination of eyes can result in permanent injury. Exposure to the dust may cause discomfort due to particulate nature. May cause physical irritation to the eyes. Acute toxicity Inhalation: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): LC50 > 5 mg/L Skin contact: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >2,000 mg/Kg bw Ingestion: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >2,000 mg/Kg bw Corrosion/Irritancy: Eye: this material has been classified as a Category 1 Hazard (irreversible effects to eyes). Skin: this material has been classified as a Category 2 Hazard (reversible effects to skin). Sensitisation: Inhalation: this material has been classified as a Category 1 Hazard (respiratory sensitiser). Skin: this material has been classified as a Category 1 Hazard (skin sensitiser). Aspiration hazard: This material has been classified as non-hazardous. Specific target organ toxicity (single exposure): This material has been classified as non-hazardous. Chronic Toxicity Mutagenicity: This material has been classified as non-hazardous. Carcinogenicity: This material has been classified as non-hazardous. Reproductive toxicity (including via lactation): This material has been classified as a Category 2 Hazard. Specific target organ toxicity (repeat exposure): This material has been classified as non-hazardous. 12. ECOLOGICAL INFORMATION Avoid contaminating waterways. Acute aquatic hazard: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >100 mg/L Long-term aquatic hazard: This material has been classified as non-hazardous. Non-rapidly or rapidly degradable substance for which there are adequate chronic toxicity data available OR in the absence of chronic toxicity data, Acute toxicity estimate (based on ingredients): >100 mg/L, where the substance is not rapidly degradable and/or BCF < 500 and/or log Kow < 4. Ecotoxicity: No information available. Persistence and degradability: No information available. Bioaccumulative potential: No information available. Mobility: No information available. 13. DISPOSAL CONSIDERATIONS Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal protection equipment is used, see "Section 8. Exposure Controls and Personal Protection" of this SDS. If possible material and its container should be recycled. If material or container cannot be recycled, dispose in accordance with local, regional, national and international Regulations. 14. TRANSPORT INFORMATION ROAD AND RAIL TRANSPORT Classified as Dangerous Goods by the criteria of the “Australian Code for the Transport of Dangerous Goods by Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land". Australian Special Provisions; AU01: Environmentally Hazardous Substances meeting the description of UN 3077 or UN 3082 are not subject to this Code (ADG 07) when transported by road or rail in; (c) packagings that do not incorporate a receptacle exceeding 500 Kg (L); or (d) IBCs. [Diagram: Class 9 Miscellaneous Dangerous Goods symbol] UN No: 3077 Dangerous Goods Class: 9 Packing Group: III Hazchem Code: 2Z Emergency Response Guide No: 47 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (MANCOZEB) Segregation Dangerous Goods: Not to be loaded with explosives (Class 1). Note 1: Materials that are fire risks are incompatible with oxidising agents (Class 5.1) or organic peroxides (Class 5.2). Exemptions may apply. MARINE TRANSPORT Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. This material is classified as a Marine Pollutant (P) according to the International Maritime Dangerous Goods Code. [Diagram: Class 9 Miscellaneous Dangerous Goods symbol] UN No: 3077 Dangerous Goods Class: 9 Packing Group: III Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (MANCOZEB) AIR TRANSPORT Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. [Diagram: Class 9 Miscellaneous Dangerous Goods symbol] UN No: 3077 Dangerous Goods Class: 9 Packing Group: III Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (MANCOZEB) 15. REGULATORY INFORMATION This material is not subject to the following international agreements: Montreal Protocol (Ozone depleting substances) The Stockholm Convention (Persistent Organic Pollutants) The Rotterdam Convention (Prior Informed Consent) Basel Convention (Hazardous Waste) International Convention for the Prevention of Pollution from Ships (MARPOL) This material/constituent(s) is covered by the following requirements: • The Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) established under the Therapeutic Goods Act (Commonwealth). • All components of this product are listed on or exempt from the Australian Inventory of Chemical Substances (AICS). 16. OTHER INFORMATION Reason for issue: First Issue This Safety Data Sheet has been prepared by Chemical Data Services Pty Ltd on behalf of its client. Safety Data Sheets are updated frequently. Please ensure that you have a current copy. This information was prepared in good faith from the best information available at the time of issue. It is based on the present level of research and to this extent we believe it is accurate. However, no guarantee of accuracy is made or implied and since conditions of use are beyond our control, all information relevant to usage is offered without warranty. The manufacturer will not be held responsible for any unauthorised use of this information or for any modified or altered versions. If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company. Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also available upon request.